Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
Peak | Intensity |
---|---|
135.11 | 0.2 |
135.94 | 0.8 |
137.05 | 0.2 |
138.02 | 77.1 |
139.16 | 1.4 |
142.11 | 0.5 |
Annotations: ^{0,2}A_{Man}Y |
|
143.05 | 0.4 |
144.05 | 6.6 |
148.98 | 0.5 |
Annotations: ^{1,5}A_{Man}Y |
|
149.97 | 0.2 |
151.08 | 0.3 |
152.98 | 0.3 |
154.07 | 0.2 |
Annotations: BZ |
|
161.95 | 0.2 |
163.06 | 1.0 |
Annotations: CZ BY BY BY CZ CZ |
|
165.93 | 0.8 |
167.05 | 0.5 |
168.04 | 54.1 |
169.19 | 0.3 |
Annotations: ^{1,5}A_{Man} |
|
170.09 | 0.5 |
171.92 | 0.3 |
Annotations: CY |
|
173.15 | 0.2 |
174.03 | 0.4 |
176.93 | 0.5 |
179.31 | 0.7 |
181.16 | 0.3 |
Annotations: CY CY |
|
182.51 | 0.2 |
184.2 | 0.3 |
186.08 | 69.3 |
Annotations: BZ |
|
187.13 | 3.8 |
193.22 | 0.3 |
196.07 | 0.2 |
197.11 | 0.2 |
201.08 | 0.7 |
202.14 | 3.3 |
202.94 | 0.9 |
204.02 | 1295.3 |
Annotations: Z Z B |
|
205.08 | 68.1 |
Annotations: ^{2,4}A_{Man}Z ^{1,3}A_{Man}Z |
|
206.12 | 1.9 |
207.15 | 0.3 |
209.11 | 0.3 |
213.01 | 0.2 |
Annotations: Y |
|
215.21 | 0.7 |
217.99 | 0.2 |
219.3 | 0.6 |
220.1 | 3.2 |
221.09 | 14.1 |
222.09 | 36.4 |
Annotations: C Y |
|
223.22 | 1.4 |
Annotations: ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y |
|
224.11 | 1.2 |
225.04 | 0.3 |
226.04 | 2.4 |
227.24 | 0.3 |
227.97 | 0.9 |
229.23 | 0.3 |
230.27 | 0.2 |
231.17 | 0.8 |
233.13 | 0.6 |
234.09 | 1.1 |
235.25 | 0.2 |
Annotations: ^{1,4}A_{Man}Z ^{2,5}A_{Man} |
|
238.11 | 0.9 |
239.12 | 0.7 |
239.96 | 0.4 |
244.14 | 0.4 |
247.12 | 0.7 |
248.27 | 0.9 |
249.3 | 0.2 |
Annotations: ^{2,5}A_{Man}Z |
|
250.0 | 0.2 |
251.14 | 0.4 |
252.08 | 0.3 |
255.05 | 0.1 |
256.14 | 0.2 |
258.09 | 1.1 |
259.11 | 0.3 |
260.22 | 0.7 |
261.2 | 0.9 |
262.14 | 0.6 |
263.1 | 0.6 |
263.93 | 0.8 |
Annotations: ^{1,3}A_{Man} |
|
265.25 | 0.7 |
Annotations: ^{0,2}A_{Man}Z |
|
266.44 | 0.2 |
267.29 | 0.4 |
Annotations: ^{2,5}A_{Man}Y |
|
268.89 | 1.3 |
271.25 | 0.3 |
273.18 | 0.2 |
Annotations: C |
|
274.09 | 0.4 |
Annotations: C |
|
278.07 | 0.4 |
279.13 | 0.4 |
Annotations: ^{1,5}A_{Man}Z |
|
280.03 | 0.5 |
281.25 | 2.0 |
282.12 | 0.6 |
283.32 | 1.3 |
Annotations: ^{0,2}A_{Man}Y |
|
283.98 | 0.2 |
284.49 | 0.2 |
285.32 | 1.2 |
Annotations: Z |
|
286.94 | 0.3 |
287.93 | 0.9 |
288.95 | 0.6 |
290.07 | 0.4 |
291.34 | 0.3 |
291.89 | 0.2 |
293.3 | 1.1 |
295.17 | 6.7 |
296.11 | 3.2 |
297.12 | 0.2 |
Annotations: ^{1,5}A_{Man}Y |
|
299.36 | 0.3 |
300.02 | 0.2 |
301.26 | 0.9 |
303.15 | 2.0 |
304.15 | 1.1 |
305.38 | 1.4 |
307.26 | 0.8 |
Annotations: BZ |
|
308.07 | 0.8 |
309.25 | 0.3 |
310.19 | 0.3 |
312.99 | 0.9 |
314.08 | 0.5 |
315.04 | 1.8 |
315.89 | 3.3 |
317.2 | 2.5 |
318.18 | 1.7 |
319.06 | 0.4 |
319.83 | 0.3 |
321.14 | 1.1 |
322.06 | 0.6 |
323.24 | 1.4 |
324.14 | 0.6 |
326.01 | 1.0 |
327.05 | 2.6 |
327.78 | 0.3 |
329.21 | 0.9 |
330.18 | 0.6 |
331.06 | 1.1 |
331.93 | 0.2 |
333.16 | 1.4 |
334.13 | 0.7 |
335.25 | 1.9 |
335.99 | 0.3 |
337.41 | 1.6 |
338.1 | 2.3 |
Annotations: ^{1,5}A_{Man} |
|
339.18 | 0.7 |
339.75 | 0.2 |
340.96 | 0.2 |
342.07 | 1.0 |
343.06 | 0.8 |
Annotations: CY |
|
344.11 | 0.7 |
344.74 | 1.2 |
345.94 | 2.6 |
347.14 | 2.6 |
348.24 | 1.5 |
Annotations: BZ |
|
349.05 | 1.7 |
350.08 | 0.6 |
351.42 | 1.5 |
352.22 | 1.3 |
353.08 | 0.6 |
354.42 | 0.5 |
355.14 | 1.5 |
356.11 | 4.2 |
356.87 | 0.5 |
357.44 | 1.2 |
358.13 | 1.2 |
359.29 | 0.8 |
360.13 | 1.8 |
361.17 | 0.4 |
362.07 | 0.4 |
363.03 | 2.9 |
364.13 | 4.1 |
364.94 | 2.1 |
366.17 | 193.8 |
Annotations: B B Z |
|
367.15 | 20.9 |
368.09 | 1.6 |
369.19 | 28.9 |
370.16 | 11.3 |
371.27 | 2.7 |
372.1 | 1.3 |
372.8 | 0.6 |
374.1 | 3.1 |
375.32 | 4.4 |
Annotations: C Y |
|
376.18 | 0.7 |
377.4 | 1.6 |
378.13 | 2.1 |
379.07 | 3.5 |
380.11 | 2.3 |
381.06 | 0.9 |
382.3 | 0.8 |
382.99 | 0.7 |
384.09 | 4.5 |
Annotations: C |
|
385.07 | 3.0 |
386.08 | 4.5 |
386.79 | 5.7 |
388.12 | 2.4 |
389.11 | 3.7 |
390.52 | 1.5 |
391.86 | 0.3 |
393.11 | 1.1 |
394.33 | 1.5 |
395.42 | 1.1 |
396.12 | 1.7 |
396.89 | 2.1 |
398.4 | 0.8 |
399.1 | 0.5 |
400.17 | 0.9 |
401.2 | 3.6 |
402.24 | 3.5 |
403.18 | 3.0 |
404.02 | 1.0 |
405.32 | 2.1 |
406.45 | 1.4 |
407.24 | 7.0 |
Annotations: Z |
|
408.24 | 1.0 |
408.87 | 0.3 |
409.57 | 0.5 |
410.41 | 0.3 |
412.38 | 3.8 |
413.46 | 1.6 |
414.2 | 2.9 |
415.23 | 1.0 |
416.03 | 1.5 |
417.08 | 2.8 |
417.96 | 1.9 |
419.23 | 0.9 |
420.08 | 0.4 |
421.4 | 1.5 |
422.37 | 2.1 |
423.24 | 2.0 |
424.27 | 3.9 |
425.23 | 42.5 |
Annotations: Y |
|
426.2 | 6.8 |
Annotations: ^{1,3}A_{Man} ^{2,4}A_{Man} |
|
427.01 | 0.5 |
427.95 | 0.7 |
429.2 | 1.8 |
430.22 | 4.6 |
431.07 | 5.4 |
432.18 | 5.6 |
433.17 | 5.9 |
434.04 | 1.5 |
435.23 | 0.4 |
436.74 | 0.5 |
437.88 | 4.3 |
439.21 | 3.2 |
440.09 | 14.8 |
441.19 | 10.0 |
441.9 | 2.6 |
442.64 | 0.4 |
443.18 | 8.8 |
444.14 | 8.2 |
445.81 | 3.9 |
446.36 | 1.5 |
447.0 | 1.0 |
448.2 | 3.8 |
449.02 | 6.4 |
449.99 | 2.0 |
451.0 | 1.2 |
454.6 | 1.3 |
455.34 | 1.5 |
456.73 | 2.4 |
458.05 | 56.2 |
459.17 | 95.1 |
460.12 | 25.5 |
461.06 | 5.7 |
462.17 | 1.0 |
462.98 | 0.9 |
464.08 | 0.6 |
464.87 | 1.3 |
465.99 | 0.6 |
466.89 | 22.2 |
467.75 | 250.8 |
468.42 | 22.4 |
469.69 | 0.7 |
Annotations: ^{2,5}A_{Man} |
|
470.38 | 0.8 |
Annotations: ^{2,5}A_{Man} |
|
471.96 | 0.2 |
474.47 | 1.1 |
475.84 | 7.4 |
476.95 | 2.7 |
478.19 | 1.0 |
478.9 | 0.5 |
480.53 | 0.2 |
482.11 | 0.6 |
488.01 | 0.3 |
489.14 | 0.4 |
490.22 | 0.4 |
492.26 | 1.4 |
493.3 | 0.4 |
497.34 | 0.2 |
502.12 | 0.2 |
503.37 | 0.2 |
509.21 | 0.4 |
510.22 | 2.4 |
Annotations: BZ |
|
512.31 | 0.6 |
513.35 | 0.3 |
526.32 | 2.8 |
527.42 | 3.9 |
528.19 | 487.9 |
Annotations: B |
|
529.22 | 73.0 |
530.12 | 2.4 |
544.2 | 0.2 |
544.95 | 0.4 |
546.2 | 6.5 |
Annotations: C |
|
547.31 | 2.5 |
548.99 | 0.2 |
551.29 | 0.7 |
552.49 | 0.8 |
555.6 | 0.2 |
558.38 | 0.6 |
560.87 | 0.6 |
564.71 | 0.3 |
566.15 | 0.9 |
567.29 | 0.4 |
567.88 | 0.8 |
569.29 | 90.5 |
Annotations: Z |
|
570.26 | 17.2 |
571.08 | 2.3 |
578.72 | 0.7 |
581.44 | 0.9 |
582.05 | 0.3 |
585.22 | 6.9 |
586.1 | 3.0 |
587.23 | 473.6 |
Annotations: Y |
|
588.28 | 66.5 |
589.27 | 6.5 |
590.05 | 1.9 |
591.14 | 1.0 |
592.34 | 0.3 |
606.38 | 0.4 |
617.47 | 0.2 |
618.05 | 0.5 |
621.32 | 0.1 |
621.92 | 0.4 |
626.41 | 0.4 |
628.33 | 0.6 |
632.27 | 0.2 |
634.33 | 0.2 |
635.32 | 0.6 |
636.92 | 0.2 |
637.67 | 1.9 |
645.84 | 1.4 |
663.5 | 0.2 |
669.25 | 0.2 |
682.57 | 0.5 |
688.63 | 0.9 |
689.34 | 0.3 |
690.44 | 1.1 |
693.42 | 1.0 |
695.26 | 1.8 |
696.54 | 0.3 |
713.31 | 8.0 |
714.35 | 2.1 |
720.59 | 0.3 |
729.55 | 14.1 |
730.45 | 9.3 |
731.29 | 532.3 |
Annotations: B Z |
|
732.33 | 124.6 |
733.34 | 3.8 |
745.84 | 0.3 |
747.0 | 0.5 |
747.59 | 31.5 |
748.51 | 54.3 |
749.28 | 2104.6 |
Annotations: Y C |
|
750.29 | 405.8 |
751.25 | 17.3 |
754.44 | 0.2 |
755.43 | 0.5 |
765.46 | 0.3 |
769.27 | 3.2 |
787.45 | 0.6 |
788.31 | 0.3 |
828.18 | 0.2 |