Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library

PubMed Entry

Peak Intensity
135.11 0.2
135.94 0.8
137.05 0.2
138.02 77.1
139.16 1.4
142.11 0.5

Annotations:

^{0,2}A_{Man}Y
143.05 0.4
144.05 6.6
148.98 0.5

Annotations:

^{1,5}A_{Man}Y
149.97 0.2
151.08 0.3
152.98 0.3
154.07 0.2

Annotations:

BZ
161.95 0.2
163.06 1.0

Annotations:

BY CZ BY BY CZ CZ
165.93 0.8
167.05 0.5
168.04 54.1
169.19 0.3

Annotations:

^{1,5}A_{Man}
170.09 0.5
171.92 0.3

Annotations:

CY
173.15 0.2
174.03 0.4
176.93 0.5
179.31 0.7
181.16 0.3

Annotations:

CY CY
182.51 0.2
184.2 0.3
186.08 69.3

Annotations:

BZ
187.13 3.8
193.22 0.3
196.07 0.2
197.11 0.2
201.08 0.7
202.14 3.3
202.94 0.9
204.02 1295.3

Annotations:

B Z Z
205.08 68.1

Annotations:

^{1,3}A_{Man}Z ^{2,4}A_{Man}Z
206.12 1.9
207.15 0.3
209.11 0.3
213.01 0.2

Annotations:

Y
215.21 0.7
217.99 0.2
219.3 0.6
220.1 3.2
221.09 14.1
222.09 36.4

Annotations:

C Y
223.22 1.4

Annotations:

^{2,4}A_{Man}Y ^{1,3}A_{Man}Y
224.11 1.2
225.04 0.3
226.04 2.4
227.24 0.3
227.97 0.9
229.23 0.3
230.27 0.2
231.17 0.8
233.13 0.6
234.09 1.1
235.25 0.2

Annotations:

^{1,4}A_{Man}Z ^{2,5}A_{Man}
238.11 0.9
239.12 0.7
239.96 0.4
244.14 0.4
247.12 0.7
248.27 0.9
249.3 0.2

Annotations:

^{2,5}A_{Man}Z
250.0 0.2
251.14 0.4
252.08 0.3
255.05 0.1
256.14 0.2
258.09 1.1
259.11 0.3
260.22 0.7
261.2 0.9
262.14 0.6
263.1 0.6
263.93 0.8

Annotations:

^{1,3}A_{Man}
265.25 0.7

Annotations:

^{0,2}A_{Man}Z
266.44 0.2
267.29 0.4

Annotations:

^{2,5}A_{Man}Y
268.89 1.3
271.25 0.3
273.18 0.2

Annotations:

C
274.09 0.4

Annotations:

C
278.07 0.4
279.13 0.4

Annotations:

^{1,5}A_{Man}Z
280.03 0.5
281.25 2.0
282.12 0.6
283.32 1.3

Annotations:

^{0,2}A_{Man}Y
283.98 0.2
284.49 0.2
285.32 1.2

Annotations:

Z
286.94 0.3
287.93 0.9
288.95 0.6
290.07 0.4
291.34 0.3
291.89 0.2
293.3 1.1
295.17 6.7
296.11 3.2
297.12 0.2

Annotations:

^{1,5}A_{Man}Y
299.36 0.3
300.02 0.2
301.26 0.9
303.15 2.0
304.15 1.1
305.38 1.4
307.26 0.8

Annotations:

BZ
308.07 0.8
309.25 0.3
310.19 0.3
312.99 0.9
314.08 0.5
315.04 1.8
315.89 3.3
317.2 2.5
318.18 1.7
319.06 0.4
319.83 0.3
321.14 1.1
322.06 0.6
323.24 1.4
324.14 0.6
326.01 1.0
327.05 2.6
327.78 0.3
329.21 0.9
330.18 0.6
331.06 1.1
331.93 0.2
333.16 1.4
334.13 0.7
335.25 1.9
335.99 0.3
337.41 1.6
338.1 2.3

Annotations:

^{1,5}A_{Man}
339.18 0.7
339.75 0.2
340.96 0.2
342.07 1.0
343.06 0.8

Annotations:

CY
344.11 0.7
344.74 1.2
345.94 2.6
347.14 2.6
348.24 1.5

Annotations:

BZ
349.05 1.7
350.08 0.6
351.42 1.5
352.22 1.3
353.08 0.6
354.42 0.5
355.14 1.5
356.11 4.2
356.87 0.5
357.44 1.2
358.13 1.2
359.29 0.8
360.13 1.8
361.17 0.4
362.07 0.4
363.03 2.9
364.13 4.1
364.94 2.1
366.17 193.8

Annotations:

B B Z
367.15 20.9
368.09 1.6
369.19 28.9
370.16 11.3
371.27 2.7
372.1 1.3
372.8 0.6
374.1 3.1
375.32 4.4

Annotations:

C Y
376.18 0.7
377.4 1.6
378.13 2.1
379.07 3.5
380.11 2.3
381.06 0.9
382.3 0.8
382.99 0.7
384.09 4.5

Annotations:

C
385.07 3.0
386.08 4.5
386.79 5.7
388.12 2.4
389.11 3.7
390.52 1.5
391.86 0.3
393.11 1.1
394.33 1.5
395.42 1.1
396.12 1.7
396.89 2.1
398.4 0.8
399.1 0.5
400.17 0.9
401.2 3.6
402.24 3.5
403.18 3.0
404.02 1.0
405.32 2.1
406.45 1.4
407.24 7.0

Annotations:

Z
408.24 1.0
408.87 0.3
409.57 0.5
410.41 0.3
412.38 3.8
413.46 1.6
414.2 2.9
415.23 1.0
416.03 1.5
417.08 2.8
417.96 1.9
419.23 0.9
420.08 0.4
421.4 1.5
422.37 2.1
423.24 2.0
424.27 3.9
425.23 42.5

Annotations:

Y
426.2 6.8

Annotations:

^{1,3}A_{Man} ^{2,4}A_{Man}
427.01 0.5
427.95 0.7
429.2 1.8
430.22 4.6
431.07 5.4
432.18 5.6
433.17 5.9
434.04 1.5
435.23 0.4
436.74 0.5
437.88 4.3
439.21 3.2
440.09 14.8
441.19 10.0
441.9 2.6
442.64 0.4
443.18 8.8
444.14 8.2
445.81 3.9
446.36 1.5
447.0 1.0
448.2 3.8
449.02 6.4
449.99 2.0
451.0 1.2
454.6 1.3
455.34 1.5
456.73 2.4
458.05 56.2
459.17 95.1
460.12 25.5
461.06 5.7
462.17 1.0
462.98 0.9
464.08 0.6
464.87 1.3
465.99 0.6
466.89 22.2
467.75 250.8
468.42 22.4
469.69 0.7

Annotations:

^{2,5}A_{Man}
470.38 0.8

Annotations:

^{2,5}A_{Man}
471.96 0.2
474.47 1.1
475.84 7.4
476.95 2.7
478.19 1.0
478.9 0.5
480.53 0.2
482.11 0.6
488.01 0.3
489.14 0.4
490.22 0.4
492.26 1.4
493.3 0.4
497.34 0.2
502.12 0.2
503.37 0.2
509.21 0.4
510.22 2.4

Annotations:

BZ
512.31 0.6
513.35 0.3
526.32 2.8
527.42 3.9
528.19 487.9

Annotations:

B
529.22 73.0
530.12 2.4
544.2 0.2
544.95 0.4
546.2 6.5

Annotations:

C
547.31 2.5
548.99 0.2
551.29 0.7
552.49 0.8
555.6 0.2
558.38 0.6
560.87 0.6
564.71 0.3
566.15 0.9
567.29 0.4
567.88 0.8
569.29 90.5

Annotations:

Z
570.26 17.2
571.08 2.3
578.72 0.7
581.44 0.9
582.05 0.3
585.22 6.9
586.1 3.0
587.23 473.6

Annotations:

Y
588.28 66.5
589.27 6.5
590.05 1.9
591.14 1.0
592.34 0.3
606.38 0.4
617.47 0.2
618.05 0.5
621.32 0.1
621.92 0.4
626.41 0.4
628.33 0.6
632.27 0.2
634.33 0.2
635.32 0.6
636.92 0.2
637.67 1.9
645.84 1.4
663.5 0.2
669.25 0.2
682.57 0.5
688.63 0.9
689.34 0.3
690.44 1.1
693.42 1.0
695.26 1.8
696.54 0.3
713.31 8.0
714.35 2.1
720.59 0.3
729.55 14.1
730.45 9.3
731.29 532.3

Annotations:

Z B
732.33 124.6
733.34 3.8
745.84 0.3
747.0 0.5
747.59 31.5
748.51 54.3
749.28 2104.6

Annotations:

C Y
750.29 405.8
751.25 17.3
754.44 0.2
755.43 0.5
765.46 0.3
769.27 3.2
787.45 0.6
788.31 0.3
828.18 0.2

There are 1 similar spectra:

Id Structure Score

2729

0.99
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