Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 135.11 | 0.2 |
| 135.94 | 0.8 |
| 137.05 | 0.2 |
| 138.02 | 77.1 |
| 139.16 | 1.4 |
| 142.11 | 0.5 |
|
Annotations: ^{0,2}A_{Man}Y |
|
| 143.05 | 0.4 |
| 144.05 | 6.6 |
| 148.98 | 0.5 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 149.97 | 0.2 |
| 151.08 | 0.3 |
| 152.98 | 0.3 |
| 154.07 | 0.2 |
|
Annotations: BZ |
|
| 161.95 | 0.2 |
| 163.06 | 1.0 |
|
Annotations: CZ |
|
| 165.93 | 0.8 |
| 167.05 | 0.5 |
| 168.04 | 54.1 |
| 169.19 | 0.3 |
|
Annotations: ^{1,5}A_{Man} |
|
| 170.09 | 0.5 |
| 171.92 | 0.3 |
|
Annotations: CY |
|
| 173.15 | 0.2 |
| 174.03 | 0.4 |
| 176.93 | 0.5 |
| 179.31 | 0.7 |
| 181.16 | 0.3 |
|
Annotations: CY |
|
| 182.51 | 0.2 |
| 184.2 | 0.3 |
| 186.08 | 69.3 |
|
Annotations: BZ |
|
| 187.13 | 3.8 |
| 193.22 | 0.3 |
| 196.07 | 0.2 |
| 197.11 | 0.2 |
| 201.08 | 0.7 |
| 202.14 | 3.3 |
| 202.94 | 0.9 |
| 204.02 | 1295.3 |
|
Annotations: Z |
|
| 205.08 | 68.1 |
|
Annotations: ^{1,3}A_{Man}Z |
|
| 206.12 | 1.9 |
| 207.15 | 0.3 |
| 209.11 | 0.3 |
| 213.01 | 0.2 |
|
Annotations: Y |
|
| 215.21 | 0.7 |
| 217.99 | 0.2 |
| 219.3 | 0.6 |
| 220.1 | 3.2 |
| 221.09 | 14.1 |
| 222.09 | 36.4 |
|
Annotations: C |
|
| 223.22 | 1.4 |
|
Annotations: ^{1,3}A_{Man}Y |
|
| 224.11 | 1.2 |
| 225.04 | 0.3 |
| 226.04 | 2.4 |
| 227.24 | 0.3 |
| 227.97 | 0.9 |
| 229.23 | 0.3 |
| 230.27 | 0.2 |
| 231.17 | 0.8 |
| 233.13 | 0.6 |
| 234.09 | 1.1 |
| 235.25 | 0.2 |
|
Annotations: ^{1,4}A_{Man}Z |
|
| 238.11 | 0.9 |
| 239.12 | 0.7 |
| 239.96 | 0.4 |
| 244.14 | 0.4 |
| 247.12 | 0.7 |
| 248.27 | 0.9 |
| 249.3 | 0.2 |
|
Annotations: ^{2,5}A_{Man}Z |
|
| 250.0 | 0.2 |
| 251.14 | 0.4 |
| 252.08 | 0.3 |
| 255.05 | 0.1 |
| 256.14 | 0.2 |
| 258.09 | 1.1 |
| 259.11 | 0.3 |
| 260.22 | 0.7 |
| 261.2 | 0.9 |
| 262.14 | 0.6 |
| 263.1 | 0.6 |
| 263.93 | 0.8 |
|
Annotations: ^{1,3}A_{Man} |
|
| 265.25 | 0.7 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 266.44 | 0.2 |
| 267.29 | 0.4 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 268.89 | 1.3 |
| 271.25 | 0.3 |
| 273.18 | 0.2 |
|
Annotations: C |
|
| 274.09 | 0.4 |
|
Annotations: C |
|
| 278.07 | 0.4 |
| 279.13 | 0.4 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 280.03 | 0.5 |
| 281.25 | 2.0 |
| 282.12 | 0.6 |
| 283.32 | 1.3 |
|
Annotations: ^{0,2}A_{Man}Y |
|
| 283.98 | 0.2 |
| 284.49 | 0.2 |
| 285.32 | 1.2 |
|
Annotations: Z |
|
| 286.94 | 0.3 |
| 287.93 | 0.9 |
| 288.95 | 0.6 |
| 290.07 | 0.4 |
| 291.34 | 0.3 |
| 291.89 | 0.2 |
| 293.3 | 1.1 |
| 295.17 | 6.7 |
| 296.11 | 3.2 |
| 297.12 | 0.2 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 299.36 | 0.3 |
| 300.02 | 0.2 |
| 301.26 | 0.9 |
| 303.15 | 2.0 |
| 304.15 | 1.1 |
| 305.38 | 1.4 |
| 307.26 | 0.8 |
|
Annotations: BZ |
|
| 308.07 | 0.8 |
| 309.25 | 0.3 |
| 310.19 | 0.3 |
| 312.99 | 0.9 |
| 314.08 | 0.5 |
| 315.04 | 1.8 |
| 315.89 | 3.3 |
| 317.2 | 2.5 |
| 318.18 | 1.7 |
| 319.06 | 0.4 |
| 319.83 | 0.3 |
| 321.14 | 1.1 |
| 322.06 | 0.6 |
| 323.24 | 1.4 |
| 324.14 | 0.6 |
| 326.01 | 1.0 |
| 327.05 | 2.6 |
| 327.78 | 0.3 |
| 329.21 | 0.9 |
| 330.18 | 0.6 |
| 331.06 | 1.1 |
| 331.93 | 0.2 |
| 333.16 | 1.4 |
| 334.13 | 0.7 |
| 335.25 | 1.9 |
| 335.99 | 0.3 |
| 337.41 | 1.6 |
| 338.1 | 2.3 |
|
Annotations: ^{1,5}A_{Man} |
|
| 339.18 | 0.7 |
| 339.75 | 0.2 |
| 340.96 | 0.2 |
| 342.07 | 1.0 |
| 343.06 | 0.8 |
|
Annotations: CY |
|
| 344.11 | 0.7 |
| 344.74 | 1.2 |
| 345.94 | 2.6 |
| 347.14 | 2.6 |
| 348.24 | 1.5 |
|
Annotations: BZ |
|
| 349.05 | 1.7 |
| 350.08 | 0.6 |
| 351.42 | 1.5 |
| 352.22 | 1.3 |
| 353.08 | 0.6 |
| 354.42 | 0.5 |
| 355.14 | 1.5 |
| 356.11 | 4.2 |
| 356.87 | 0.5 |
| 357.44 | 1.2 |
| 358.13 | 1.2 |
| 359.29 | 0.8 |
| 360.13 | 1.8 |
| 361.17 | 0.4 |
| 362.07 | 0.4 |
| 363.03 | 2.9 |
| 364.13 | 4.1 |
| 364.94 | 2.1 |
| 366.17 | 193.8 |
|
Annotations: B |
|
| 367.15 | 20.9 |
| 368.09 | 1.6 |
| 369.19 | 28.9 |
| 370.16 | 11.3 |
| 371.27 | 2.7 |
| 372.1 | 1.3 |
| 372.8 | 0.6 |
| 374.1 | 3.1 |
| 375.32 | 4.4 |
|
Annotations: C |
|
| 376.18 | 0.7 |
| 377.4 | 1.6 |
| 378.13 | 2.1 |
| 379.07 | 3.5 |
| 380.11 | 2.3 |
| 381.06 | 0.9 |
| 382.3 | 0.8 |
| 382.99 | 0.7 |
| 384.09 | 4.5 |
|
Annotations: C |
|
| 385.07 | 3.0 |
| 386.08 | 4.5 |
| 386.79 | 5.7 |
| 388.12 | 2.4 |
| 389.11 | 3.7 |
| 390.52 | 1.5 |
| 391.86 | 0.3 |
| 393.11 | 1.1 |
| 394.33 | 1.5 |
| 395.42 | 1.1 |
| 396.12 | 1.7 |
| 396.89 | 2.1 |
| 398.4 | 0.8 |
| 399.1 | 0.5 |
| 400.17 | 0.9 |
| 401.2 | 3.6 |
| 402.24 | 3.5 |
| 403.18 | 3.0 |
| 404.02 | 1.0 |
| 405.32 | 2.1 |
| 406.45 | 1.4 |
| 407.24 | 7.0 |
|
Annotations: Z |
|
| 408.24 | 1.0 |
| 408.87 | 0.3 |
| 409.57 | 0.5 |
| 410.41 | 0.3 |
| 412.38 | 3.8 |
| 413.46 | 1.6 |
| 414.2 | 2.9 |
| 415.23 | 1.0 |
| 416.03 | 1.5 |
| 417.08 | 2.8 |
| 417.96 | 1.9 |
| 419.23 | 0.9 |
| 420.08 | 0.4 |
| 421.4 | 1.5 |
| 422.37 | 2.1 |
| 423.24 | 2.0 |
| 424.27 | 3.9 |
| 425.23 | 42.5 |
|
Annotations: Y |
|
| 426.2 | 6.8 |
|
Annotations: ^{1,3}A_{Man} |
|
| 427.01 | 0.5 |
| 427.95 | 0.7 |
| 429.2 | 1.8 |
| 430.22 | 4.6 |
| 431.07 | 5.4 |
| 432.18 | 5.6 |
| 433.17 | 5.9 |
| 434.04 | 1.5 |
| 435.23 | 0.4 |
| 436.74 | 0.5 |
| 437.88 | 4.3 |
| 439.21 | 3.2 |
| 440.09 | 14.8 |
| 441.19 | 10.0 |
| 441.9 | 2.6 |
| 442.64 | 0.4 |
| 443.18 | 8.8 |
| 444.14 | 8.2 |
| 445.81 | 3.9 |
| 446.36 | 1.5 |
| 447.0 | 1.0 |
| 448.2 | 3.8 |
| 449.02 | 6.4 |
| 449.99 | 2.0 |
| 451.0 | 1.2 |
| 454.6 | 1.3 |
| 455.34 | 1.5 |
| 456.73 | 2.4 |
| 458.05 | 56.2 |
| 459.17 | 95.1 |
| 460.12 | 25.5 |
| 461.06 | 5.7 |
| 462.17 | 1.0 |
| 462.98 | 0.9 |
| 464.08 | 0.6 |
| 464.87 | 1.3 |
| 465.99 | 0.6 |
| 466.89 | 22.2 |
| 467.75 | 250.8 |
| 468.42 | 22.4 |
| 469.69 | 0.7 |
|
Annotations: ^{2,5}A_{Man} |
|
| 470.38 | 0.8 |
|
Annotations: ^{2,5}A_{Man} |
|
| 471.96 | 0.2 |
| 474.47 | 1.1 |
| 475.84 | 7.4 |
| 476.95 | 2.7 |
| 478.19 | 1.0 |
| 478.9 | 0.5 |
| 480.53 | 0.2 |
| 482.11 | 0.6 |
| 488.01 | 0.3 |
| 489.14 | 0.4 |
| 490.22 | 0.4 |
| 492.26 | 1.4 |
| 493.3 | 0.4 |
| 497.34 | 0.2 |
| 502.12 | 0.2 |
| 503.37 | 0.2 |
| 509.21 | 0.4 |
| 510.22 | 2.4 |
|
Annotations: BZ |
|
| 512.31 | 0.6 |
| 513.35 | 0.3 |
| 526.32 | 2.8 |
| 527.42 | 3.9 |
| 528.19 | 487.9 |
|
Annotations: B |
|
| 529.22 | 73.0 |
| 530.12 | 2.4 |
| 544.2 | 0.2 |
| 544.95 | 0.4 |
| 546.2 | 6.5 |
|
Annotations: C |
|
| 547.31 | 2.5 |
| 548.99 | 0.2 |
| 551.29 | 0.7 |
| 552.49 | 0.8 |
| 555.6 | 0.2 |
| 558.38 | 0.6 |
| 560.87 | 0.6 |
| 564.71 | 0.3 |
| 566.15 | 0.9 |
| 567.29 | 0.4 |
| 567.88 | 0.8 |
| 569.29 | 90.5 |
|
Annotations: Z |
|
| 570.26 | 17.2 |
| 571.08 | 2.3 |
| 578.72 | 0.7 |
| 581.44 | 0.9 |
| 582.05 | 0.3 |
| 585.22 | 6.9 |
| 586.1 | 3.0 |
| 587.23 | 473.6 |
|
Annotations: Y |
|
| 588.28 | 66.5 |
| 589.27 | 6.5 |
| 590.05 | 1.9 |
| 591.14 | 1.0 |
| 592.34 | 0.3 |
| 606.38 | 0.4 |
| 617.47 | 0.2 |
| 618.05 | 0.5 |
| 621.32 | 0.1 |
| 621.92 | 0.4 |
| 626.41 | 0.4 |
| 628.33 | 0.6 |
| 632.27 | 0.2 |
| 634.33 | 0.2 |
| 635.32 | 0.6 |
| 636.92 | 0.2 |
| 637.67 | 1.9 |
| 645.84 | 1.4 |
| 663.5 | 0.2 |
| 669.25 | 0.2 |
| 682.57 | 0.5 |
| 688.63 | 0.9 |
| 689.34 | 0.3 |
| 690.44 | 1.1 |
| 693.42 | 1.0 |
| 695.26 | 1.8 |
| 696.54 | 0.3 |
| 713.31 | 8.0 |
| 714.35 | 2.1 |
| 720.59 | 0.3 |
| 729.55 | 14.1 |
| 730.45 | 9.3 |
| 731.29 | 532.3 |
|
Annotations: B |
|
| 732.33 | 124.6 |
| 733.34 | 3.8 |
| 745.84 | 0.3 |
| 747.0 | 0.5 |
| 747.59 | 31.5 |
| 748.51 | 54.3 |
| 749.28 | 2104.6 |
|
Annotations: C |
|
| 750.29 | 405.8 |
| 751.25 | 17.3 |
| 754.44 | 0.2 |
| 755.43 | 0.5 |
| 765.46 | 0.3 |
| 769.27 | 3.2 |
| 787.45 | 0.6 |
| 788.31 | 0.3 |
| 828.18 | 0.2 |