Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 138.02 | 9.1 |
| 139.03 | 0.3 |
| 139.98 | 0.1 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 144.01 | 0.5 |
| 146.98 | 0.1 |
| 151.0 | 0.3 |
| 157.52 | 0.1 |
| 159.07 | 0.2 |
| 161.98 | 0.3 |
| 163.04 | 0.1 |
|
Annotations: CZ |
|
| 165.09 | 0.1 |
| 167.23 | 0.2 |
| 168.05 | 7.4 |
| 169.08 | 0.3 |
|
Annotations: ^{1,5}A_{Man} |
|
| 171.07 | 0.1 |
| 175.15 | 0.1 |
| 182.13 | 0.2 |
| 183.1 | 0.1 |
|
Annotations: B |
|
| 186.08 | 6.5 |
|
Annotations: BZ |
|
| 187.06 | 0.8 |
| 195.91 | 0.2 |
| 200.89 | 0.3 |
| 202.16 | 0.4 |
| 203.21 | 0.3 |
| 204.06 | 180.5 |
|
Annotations: Z |
|
| 205.08 | 8.9 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 206.2 | 0.1 |
| 207.12 | 0.2 |
| 208.04 | 0.2 |
| 210.06 | 0.1 |
| 210.89 | 0.2 |
| 215.06 | 0.1 |
| 217.25 | 0.2 |
| 217.89 | 0.1 |
| 218.48 | 0.1 |
| 221.09 | 1.4 |
|
Annotations: ^{3,5}A_{Man} |
|
| 222.11 | 9.3 |
|
Annotations: C |
|
| 223.01 | 0.3 |
|
Annotations: ^{0,4}A_{Man}Y |
|
| 223.56 | 0.2 |
|
Annotations: ^{0,4}A_{Man}Y |
|
| 224.08 | 0.3 |
| 226.08 | 0.3 |
| 229.24 | 0.1 |
| 230.21 | 0.2 |
| 231.41 | 0.1 |
| 233.15 | 0.1 |
| 235.16 | 0.2 |
|
Annotations: ^{0,3}A_{Man}Z |
|
| 235.98 | 0.1 |
|
Annotations: ^{2,5}A_{Man} |
|
| 238.03 | 0.1 |
| 242.16 | 0.1 |
| 244.12 | 0.4 |
| 247.67 | 0.2 |
| 251.2 | 0.1 |
| 254.1 | 0.1 |
| 254.99 | 0.1 |
| 256.1 | 0.3 |
| 260.12 | 0.1 |
| 261.07 | 0.3 |
| 262.09 | 0.1 |
| 263.54 | 0.4 |
| 267.23 | 0.2 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 271.3 | 0.1 |
| 273.07 | 0.1 |
| 274.12 | 0.3 |
| 275.13 | 2.3 |
| 276.9 | 0.1 |
| 281.18 | 0.1 |
| 284.04 | 0.4 |
| 284.99 | 0.3 |
|
Annotations: Z |
|
| 289.02 | 0.3 |
| 289.95 | 0.2 |
| 294.21 | 0.2 |
|
Annotations: Y |
|
| 295.06 | 0.4 |
| 295.66 | 0.2 |
| 296.2 | 0.2 |
| 297.27 | 0.3 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 298.13 | 0.1 |
| 300.22 | 0.1 |
| 302.0 | 0.2 |
| 303.42 | 0.1 |
| 304.14 | 0.3 |
| 305.88 | 0.6 |
| 308.86 | 0.1 |
| 311.33 | 0.2 |
| 312.57 | 0.5 |
| 313.25 | 0.1 |
| 313.75 | 0.1 |
| 314.63 | 1.4 |
| 316.13 | 0.4 |
| 317.16 | 0.8 |
| 318.13 | 0.6 |
| 319.04 | 0.3 |
| 320.09 | 0.6 |
| 321.07 | 0.5 |
| 322.23 | 1.1 |
| 323.24 | 0.3 |
| 324.65 | 0.5 |
|
Annotations: BY |
|
| 326.31 | 0.1 |
| 326.97 | 0.2 |
| 327.99 | 0.4 |
| 328.94 | 0.1 |
| 332.98 | 0.1 |
| 335.19 | 0.4 |
| 336.19 | 0.3 |
| 337.1 | 0.3 |
| 338.01 | 0.2 |
|
Annotations: ^{1,5}A_{Man} |
|
| 339.17 | 0.1 |
| 340.1 | 0.3 |
| 341.3 | 0.1 |
| 342.13 | 0.1 |
| 342.97 | 0.3 |
|
Annotations: CY |
|
| 344.01 | 0.2 |
| 345.1 | 0.4 |
| 345.99 | 0.7 |
| 348.1 | 0.4 |
|
Annotations: BZ |
|
| 349.22 | 0.1 |
| 350.07 | 0.4 |
| 350.78 | 0.2 |
| 352.3 | 0.5 |
| 353.09 | 0.2 |
| 355.03 | 0.4 |
| 356.14 | 0.7 |
| 357.21 | 0.8 |
| 358.16 | 0.9 |
| 359.74 | 0.2 |
| 360.27 | 0.1 |
| 360.85 | 0.1 |
| 362.26 | 0.2 |
| 364.15 | 1.6 |
| 364.95 | 0.3 |
| 365.45 | 0.3 |
| 366.21 | 35.8 |
|
Annotations: B |
|
| 367.17 | 2.9 |
| 369.17 | 6.4 |
| 370.18 | 3.0 |
| 371.24 | 0.6 |
| 371.88 | 0.2 |
| 374.1 | 1.4 |
| 375.19 | 1.2 |
|
Annotations: C |
|
| 376.06 | 0.7 |
| 376.86 | 0.4 |
| 377.94 | 0.4 |
| 379.03 | 0.6 |
| 380.16 | 1.2 |
| 382.12 | 0.2 |
| 382.94 | 0.2 |
| 384.0 | 0.5 |
|
Annotations: C |
|
| 385.21 | 1.7 |
| 386.1 | 1.2 |
| 387.18 | 1.6 |
| 388.04 | 0.3 |
| 389.03 | 0.5 |
| 390.37 | 0.1 |
| 391.36 | 0.5 |
| 391.97 | 0.3 |
| 393.15 | 0.1 |
| 394.22 | 0.2 |
| 394.89 | 0.9 |
| 395.77 | 1.4 |
| 396.68 | 0.1 |
| 398.06 | 0.7 |
| 399.02 | 0.2 |
| 399.91 | 0.3 |
| 400.98 | 0.1 |
| 401.83 | 0.1 |
| 402.97 | 0.4 |
| 403.93 | 0.6 |
| 405.1 | 0.1 |
| 405.65 | 0.4 |
| 406.25 | 0.5 |
| 407.51 | 1.4 |
|
Annotations: Z |
|
| 408.93 | 0.4 |
| 410.19 | 0.3 |
| 410.8 | 0.2 |
| 411.73 | 0.5 |
| 412.24 | 0.1 |
| 413.31 | 0.4 |
| 414.29 | 0.2 |
| 415.45 | 0.7 |
| 416.13 | 0.7 |
| 417.23 | 1.0 |
| 418.27 | 1.8 |
| 419.22 | 0.9 |
| 420.25 | 0.7 |
| 422.5 | 0.1 |
| 423.62 | 0.2 |
| 424.4 | 0.5 |
| 425.23 | 1.2 |
|
Annotations: Y |
|
| 427.05 | 0.2 |
| 427.87 | 0.2 |
| 428.82 | 0.6 |
| 429.94 | 2.9 |
| 431.05 | 2.0 |
| 432.01 | 1.5 |
| 433.1 | 0.5 |
| 434.02 | 0.5 |
| 435.11 | 0.7 |
| 436.22 | 0.2 |
| 438.17 | 2.4 |
| 438.97 | 1.0 |
| 440.01 | 6.8 |
|
Annotations: ^{3,5}A_{Man} |
|
| 441.04 | 4.3 |
| 442.04 | 1.3 |
| 443.1 | 1.3 |
| 444.23 | 0.7 |
| 445.83 | 1.6 |
| 446.5 | 1.6 |
| 447.08 | 0.8 |
| 448.08 | 0.3 |
| 448.83 | 1.0 |
| 454.16 | 0.5 |
| 456.8 | 0.2 |
| 457.72 | 2.8 |
| 458.22 | 11.7 |
| 459.19 | 19.0 |
| 460.2 | 4.4 |
| 461.15 | 0.5 |
| 462.02 | 0.1 |
| 462.96 | 0.1 |
| 463.91 | 0.1 |
| 464.81 | 0.4 |
| 466.71 | 1.9 |
| 467.81 | 26.2 |
| 468.55 | 3.8 |
| 474.42 | 0.1 |
| 475.77 | 2.4 |
| 476.65 | 1.5 |
| 477.66 | 0.1 |
| 478.52 | 0.5 |
| 489.31 | 0.1 |
| 495.73 | 0.6 |
| 508.67 | 0.2 |
| 510.42 | 0.1 |
|
Annotations: BZ |
|
| 522.23 | 0.2 |
| 526.15 | 0.7 |
| 527.23 | 1.2 |
| 528.25 | 84.6 |
|
Annotations: B |
|
| 529.27 | 10.8 |
| 530.14 | 0.2 |
| 531.4 | 0.2 |
| 546.26 | 1.1 |
|
Annotations: C |
|
| 547.95 | 0.1 |
| 558.8 | 0.3 |
| 561.08 | 0.1 |
| 564.03 | 0.2 |
| 566.36 | 0.1 |
| 567.21 | 0.2 |
| 569.3 | 8.9 |
|
Annotations: Z |
|
| 570.25 | 1.7 |
| 585.37 | 0.4 |
| 586.25 | 1.4 |
| 587.29 | 51.9 |
|
Annotations: Y |
|
| 588.29 | 8.6 |
| 589.03 | 0.1 |
| 612.0 | 0.4 |
| 618.98 | 0.2 |
| 626.17 | 0.1 |
| 630.37 | 0.2 |
| 683.22 | 0.1 |
| 689.42 | 0.2 |
| 690.28 | 0.3 |
| 694.73 | 0.1 |
| 695.35 | 0.1 |
| 696.39 | 0.2 |
| 707.32 | 0.2 |
| 711.35 | 0.1 |
| 713.34 | 0.3 |
| 727.31 | 0.2 |
| 729.38 | 0.2 |
| 730.16 | 1.4 |
| 730.7 | 0.3 |
| 731.33 | 105.3 |
|
Annotations: B |
|
| 732.36 | 21.1 |
| 733.35 | 1.6 |
| 738.27 | 0.2 |
| 739.36 | 0.2 |
| 746.64 | 0.1 |
| 747.93 | 7.2 |
| 749.32 | 269.0 |
|
Annotations: C |
|
| 750.36 | 56.7 |
| 751.38 | 2.8 |
| 752.27 | 0.1 |
| 769.39 | 0.2 |
| 789.28 | 0.2 |
| 793.5 | 0.1 |
| 806.46 | 0.1 |
| 933.45 | 0.1 |