Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 163.19 | 0.1 |
|
Annotations: B |
|
| 168.1 | 2.1 |
| 173.07 | 0.2 |
| 174.21 | 0.1 |
| 181.27 | 0.1 |
|
Annotations: C |
|
| 186.12 | 3.9 |
|
Annotations: BZ |
|
| 194.94 | 0.1 |
| 204.09 | 81.1 |
|
Annotations: B |
|
| 205.06 | 2.5 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 221.3 | 0.2 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 222.16 | 3.8 |
|
Annotations: C |
|
| 223.19 | 0.4 |
|
Annotations: ^{0,2}A_{Man}Y |
|
| 226.18 | 0.1 |
| 242.05 | 0.3 |
| 245.93 | 0.1 |
| 247.2 | 0.1 |
| 252.22 | 0.1 |
| 262.34 | 0.2 |
| 276.05 | 0.2 |
|
Annotations: ZZ |
|
| 285.51 | 0.2 |
|
Annotations: ZY |
|
| 289.26 | 0.1 |
| 291.18 | 0.1 |
| 292.38 | 0.1 |
| 293.17 | 0.3 |
| 300.02 | 0.1 |
| 300.54 | 0.1 |
| 301.26 | 0.2 |
| 306.17 | 0.2 |
| 307.32 | 0.1 |
|
Annotations: BZ |
|
| 309.12 | 0.1 |
| 310.32 | 0.1 |
| 314.88 | 0.4 |
| 318.13 | 0.1 |
| 321.23 | 0.2 |
| 323.13 | 0.1 |
| 325.08 | 0.3 |
|
Annotations: BY |
|
| 326.31 | 0.1 |
| 335.24 | 0.1 |
| 337.03 | 0.1 |
|
Annotations: BZ |
|
| 338.24 | 0.2 |
|
Annotations: ^{1,5}A_{Man} |
|
| 340.93 | 0.1 |
| 342.06 | 0.2 |
| 342.88 | 0.2 |
|
Annotations: CY |
|
| 343.92 | 0.3 |
| 346.18 | 0.1 |
| 353.28 | 0.1 |
| 354.19 | 0.3 |
|
Annotations: C |
|
| 355.11 | 0.3 |
|
Annotations: C |
|
| 356.75 | 0.2 |
|
Annotations: BZ |
|
| 357.48 | 0.3 |
|
Annotations: BZ |
|
| 361.39 | 0.1 |
| 364.61 | 1.0 |
| 366.23 | 23.9 |
|
Annotations: B |
|
| 367.18 | 1.4 |
| 367.88 | 0.2 |
| 374.22 | 0.2 |
| 377.11 | 0.1 |
| 378.03 | 0.1 |
| 384.26 | 0.2 |
|
Annotations: C |
|
| 386.53 | 0.1 |
| 387.12 | 0.1 |
| 388.27 | 0.2 |
| 388.86 | 0.1 |
| 390.27 | 0.2 |
| 392.1 | 0.2 |
| 393.11 | 0.2 |
| 394.53 | 0.5 |
| 395.42 | 1.2 |
| 396.2 | 0.3 |
| 397.92 | 0.1 |
| 399.24 | 0.2 |
| 402.17 | 0.2 |
| 404.05 | 0.1 |
| 404.67 | 0.4 |
| 405.99 | 0.5 |
| 407.27 | 0.5 |
|
Annotations: Z |
|
| 408.44 | 0.1 |
| 408.96 | 0.1 |
| 413.35 | 0.2 |
| 417.31 | 0.2 |
| 419.14 | 0.1 |
| 420.27 | 0.3 |
| 421.28 | 0.2 |
| 422.97 | 0.5 |
| 425.17 | 2.5 |
|
Annotations: Y |
|
| 426.17 | 0.3 |
|
Annotations: ^{0,4}A_{Man} |
|
| 426.88 | 0.1 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 427.97 | 0.1 |
| 429.09 | 0.2 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 430.61 | 0.4 |
| 432.25 | 0.1 |
| 436.12 | 0.2 |
| 437.09 | 0.4 |
| 438.27 | 0.8 |
| 440.02 | 0.1 |
|
Annotations: ^{3,5}A_{Man} |
|
| 441.94 | 0.1 |
| 442.63 | 0.1 |
| 445.11 | 0.6 |
|
Annotations: ^{0,2}A_{Man}Y |
|
| 446.46 | 1.1 |
| 447.31 | 1.8 |
|
Annotations: B |
|
| 448.12 | 0.1 |
| 450.95 | 0.1 |
| 451.52 | 0.1 |
| 454.2 | 0.3 |
| 455.32 | 0.8 |
| 455.93 | 0.1 |
|
Annotations: C |
|
| 456.63 | 0.1 |
|
Annotations: C |
|
| 457.54 | 0.1 |
| 458.17 | 0.4 |
| 459.04 | 0.5 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 459.93 | 0.2 |
| 460.95 | 0.4 |
| 462.14 | 0.3 |
| 463.27 | 0.2 |
| 464.14 | 0.2 |
| 465.11 | 0.6 |
| 466.08 | 0.8 |
| 466.83 | 0.5 |
| 467.84 | 14.8 |
|
Annotations: Z |
|
| 468.41 | 0.6 |
| 469.02 | 0.2 |
|
Annotations: BZ |
|
| 469.55 | 0.1 |
|
Annotations: BZ |
|
| 471.86 | 0.1 |
| 473.44 | 0.1 |
| 474.06 | 0.1 |
| 475.6 | 2.8 |
| 476.8 | 29.3 |
|
Annotations: Y |
|
| 477.42 | 1.0 |
| 478.02 | 2.9 |
| 479.06 | 0.4 |
| 480.1 | 0.1 |
| 480.91 | 0.4 |
| 482.24 | 0.1 |
| 483.26 | 0.3 |
| 484.12 | 0.1 |
| 485.32 | 0.2 |
| 486.03 | 0.4 |
| 486.87 | 0.2 |
|
Annotations: BY |
|
| 487.64 | 0.1 |
|
Annotations: BY |
|
| 489.2 | 0.1 |
| 491.17 | 0.2 |
| 491.9 | 0.1 |
| 493.23 | 0.7 |
| 494.69 | 1.0 |
| 496.21 | 0.5 |
| 497.12 | 1.4 |
| 498.2 | 0.3 |
| 499.0 | 0.8 |
| 500.23 | 0.1 |
| 501.14 | 0.4 |
| 503.54 | 0.3 |
| 506.3 | 0.1 |
| 507.21 | 0.2 |
| 508.08 | 0.2 |
| 509.11 | 0.3 |
| 510.1 | 0.2 |
|
Annotations: BZ |
|
| 510.96 | 0.4 |
| 512.06 | 0.5 |
| 513.18 | 0.6 |
| 513.88 | 0.1 |
| 515.09 | 0.1 |
| 517.14 | 0.2 |
| 519.12 | 0.5 |
| 520.01 | 0.6 |
| 521.18 | 2.1 |
| 522.0 | 4.1 |
| 522.96 | 0.6 |
| 524.18 | 0.1 |
| 525.61 | 0.3 |
| 526.91 | 1.5 |
| 528.3 | 29.4 |
|
Annotations: CZ |
|
| 529.3 | 3.1 |
| 530.33 | 0.2 |
| 530.9 | 0.1 |
| 534.93 | 0.2 |
| 537.09 | 0.3 |
| 537.6 | 0.4 |
| 538.29 | 0.1 |
| 539.15 | 2.9 |
| 539.96 | 0.7 |
| 540.61 | 1.6 |
| 541.25 | 0.5 |
| 542.48 | 0.4 |
| 546.39 | 0.3 |
|
Annotations: CY |
|
| 547.52 | 0.7 |
| 548.75 | 2.9 |
| 549.35 | 0.9 |
| 551.63 | 0.1 |
|
Annotations: ZZ |
|
| 553.63 | 0.1 |
| 556.88 | 0.5 |
| 557.89 | 0.1 |
| 558.77 | 0.7 |
| 559.52 | 0.2 |
| 569.36 | 3.3 |
|
Annotations: ZY |
|
| 570.35 | 0.6 |
| 573.71 | 0.3 |
| 575.97 | 0.2 |
| 577.93 | 0.1 |
| 581.71 | 0.1 |
| 584.66 | 0.1 |
| 585.24 | 0.1 |
| 586.37 | 0.7 |
| 587.37 | 14.4 |
|
Annotations: YY |
|
| 588.32 | 1.2 |
| 589.44 | 0.5 |
| 590.82 | 0.1 |
| 594.43 | 0.2 |
| 601.72 | 0.2 |
| 602.27 | 0.3 |
| 628.15 | 0.2 |
| 648.9 | 0.2 |
| 654.27 | 0.1 |
| 655.88 | 0.1 |
| 672.17 | 0.1 |
|
Annotations: BZ |
|
| 682.87 | 0.1 |
| 683.66 | 0.2 |
| 684.24 | 0.1 |
| 688.42 | 0.5 |
| 689.51 | 1.3 |
| 690.39 | 31.7 |
|
Annotations: B |
|
| 691.36 | 4.6 |
| 692.58 | 0.1 |
| 708.36 | 0.1 |
|
Annotations: C |
|
| 713.48 | 0.2 |
|
Annotations: BZ |
|
| 714.57 | 0.1 |
| 716.18 | 0.2 |
| 727.27 | 0.3 |
| 728.35 | 0.1 |
| 729.45 | 0.7 |
| 730.45 | 0.8 |
| 731.41 | 33.4 |
|
Annotations: Z |
|
| 732.42 | 4.3 |
| 734.31 | 0.2 |
| 736.18 | 0.4 |
| 744.27 | 0.3 |
| 747.1 | 0.1 |
| 747.72 | 1.6 |
| 748.56 | 0.9 |
| 749.4 | 90.2 |
|
Annotations: Y |
|
| 750.38 | 9.0 |
| 751.51 | 0.2 |
| 754.43 | 0.3 |
| 755.38 | 0.1 |
| 756.53 | 0.5 |
| 760.82 | 0.1 |
| 764.69 | 0.3 |
| 770.1 | 0.1 |
| 788.36 | 0.1 |
| 851.57 | 0.2 |
| 858.18 | 0.1 |
| 876.39 | 0.2 |
| 883.34 | 0.1 |
| 891.57 | 0.5 |
| 892.58 | 0.9 |
| 893.47 | 35.6 |
|
Annotations: B |
|
| 894.46 | 5.7 |
| 897.31 | 0.1 |
| 908.44 | 0.1 |
| 909.26 | 0.9 |
| 910.32 | 2.2 |
| 910.88 | 0.4 |
|
Annotations: C |
|
| 911.45 | 163.2 |
|
Annotations: C |
|
| 912.46 | 28.3 |
| 913.23 | 0.9 |
| 913.93 | 0.4 |
| 918.38 | 0.1 |
| 931.53 | 0.2 |
| 932.43 | 0.1 |
| 934.15 | 0.2 |
|
Annotations: Z |
|
| 934.8 | 0.1 |
|
Annotations: Z |
|
| 947.43 | 0.1 |
| 951.67 | 0.2 |
| 952.46 | 0.9 |
|
Annotations: Y |
|
| 953.22 | 0.2 |
| 955.49 | 0.3 |
| 974.5 | 0.4 |
| 1034.7 | 0.2 |
| 1035.24 | 0.1 |
| 1058.58 | 0.1 |
| 1075.67 | 0.1 |
| 1092.44 | 0.2 |
| 1094.58 | 1.2 |
| 1095.33 | 0.3 |
| 1105.47 | 0.1 |