Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 167.34 | 0.1 |
| 168.05 | 5.2 |
| 174.11 | 0.1 |
| 181.99 | 0.2 |
| 186.1 | 5.4 |
|
Annotations: BZ |
|
| 189.32 | 0.1 |
| 199.25 | 0.1 |
| 200.84 | 0.1 |
| 203.14 | 0.4 |
| 204.09 | 95.5 |
|
Annotations: Z |
|
| 205.07 | 4.2 |
|
Annotations: ^{1,3}A_{Man}Z |
|
| 206.13 | 0.1 |
|
Annotations: ^{2,5}A_{Man}Z |
|
| 216.45 | 0.2 |
| 217.01 | 0.3 |
| 221.24 | 0.2 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 222.13 | 4.3 |
|
Annotations: C |
|
| 222.87 | 0.2 |
|
Annotations: ^{1,3}A_{Man}Y |
|
| 225.24 | 0.1 |
| 236.12 | 0.1 |
| 244.99 | 0.1 |
| 246.17 | 0.1 |
| 247.27 | 0.2 |
| 254.01 | 0.1 |
| 256.79 | 0.2 |
| 263.02 | 0.1 |
| 263.97 | 0.2 |
|
Annotations: ^{1,3}A_{Man} |
|
| 269.15 | 0.1 |
| 273.3 | 0.2 |
|
Annotations: CY |
|
| 276.97 | 0.1 |
| 283.38 | 0.6 |
| 292.07 | 0.1 |
| 295.03 | 0.1 |
| 301.03 | 0.1 |
| 305.55 | 0.2 |
| 312.12 | 0.1 |
| 314.82 | 0.4 |
| 315.99 | 0.1 |
| 317.02 | 0.2 |
|
Annotations: ^{2,5}A_{Man} |
|
| 318.15 | 0.1 |
| 325.21 | 0.1 |
|
Annotations: BY |
|
| 327.39 | 0.2 |
| 333.46 | 0.2 |
| 336.12 | 0.1 |
| 342.98 | 0.2 |
|
Annotations: CY |
|
| 344.07 | 0.1 |
| 344.98 | 0.2 |
| 348.13 | 0.4 |
| 355.03 | 0.2 |
|
Annotations: C |
|
| 356.02 | 0.4 |
| 356.83 | 0.2 |
|
Annotations: BZ |
|
| 362.98 | 0.2 |
| 365.01 | 0.7 |
| 365.53 | 0.1 |
| 366.23 | 31.2 |
|
Annotations: B |
|
| 367.17 | 1.2 |
| 367.91 | 0.1 |
| 370.29 | 0.2 |
| 374.37 | 0.2 |
| 375.18 | 0.3 |
|
Annotations: Y |
|
| 377.07 | 0.1 |
| 378.15 | 0.3 |
| 379.89 | 0.1 |
| 382.16 | 0.1 |
| 383.11 | 0.2 |
| 384.09 | 0.2 |
|
Annotations: C |
|
| 385.31 | 0.1 |
| 388.03 | 0.3 |
| 394.17 | 0.2 |
| 396.0 | 1.2 |
| 398.38 | 0.3 |
| 400.39 | 0.1 |
| 401.14 | 0.2 |
| 402.39 | 0.1 |
| 402.99 | 0.1 |
| 403.98 | 0.1 |
| 404.99 | 0.4 |
| 407.17 | 0.5 |
|
Annotations: Z |
|
| 407.79 | 0.1 |
| 409.24 | 0.1 |
| 413.03 | 0.1 |
| 414.31 | 0.3 |
| 419.11 | 0.3 |
| 420.18 | 0.1 |
| 423.06 | 0.7 |
| 425.29 | 2.8 |
|
Annotations: Y |
|
| 426.14 | 0.2 |
|
Annotations: ^{1,3}A_{Man} |
|
| 427.36 | 0.1 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 428.3 | 1.2 |
| 429.14 | 0.3 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 430.07 | 0.2 |
| 431.17 | 0.4 |
| 431.99 | 1.1 |
| 433.07 | 0.1 |
| 436.27 | 0.3 |
| 441.85 | 0.1 |
| 444.08 | 0.2 |
| 447.3 | 10.1 |
|
Annotations: B |
|
| 448.11 | 0.4 |
| 448.7 | 0.1 |
| 451.16 | 0.1 |
| 455.39 | 0.3 |
| 456.28 | 0.5 |
|
Annotations: C |
|
| 458.09 | 0.3 |
| 459.06 | 0.2 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 463.12 | 0.1 |
| 463.74 | 0.1 |
| 465.12 | 0.6 |
| 466.22 | 0.4 |
| 467.04 | 0.3 |
| 467.81 | 8.2 |
|
Annotations: Z |
|
| 468.53 | 0.6 |
| 469.09 | 0.3 |
|
Annotations: BZ |
|
| 470.14 | 0.2 |
| 473.0 | 0.4 |
| 473.95 | 0.1 |
| 475.79 | 1.0 |
| 476.81 | 15.4 |
|
Annotations: Y |
|
| 477.34 | 0.2 |
| 477.92 | 3.5 |
| 478.87 | 0.6 |
| 480.05 | 0.4 |
| 481.09 | 0.4 |
| 482.03 | 0.7 |
| 483.07 | 0.9 |
| 483.97 | 0.2 |
| 485.05 | 0.3 |
| 485.98 | 0.3 |
| 487.27 | 0.1 |
|
Annotations: CZ |
|
| 488.14 | 0.2 |
| 489.09 | 0.3 |
| 491.02 | 0.3 |
| 491.79 | 0.1 |
| 492.31 | 0.1 |
| 492.99 | 0.2 |
| 495.05 | 0.3 |
| 497.19 | 0.6 |
| 498.03 | 0.5 |
| 499.07 | 0.1 |
| 499.9 | 1.3 |
| 501.6 | 0.2 |
| 503.31 | 0.6 |
| 503.93 | 0.1 |
| 504.69 | 0.7 |
|
Annotations: CY |
|
| 505.48 | 0.1 |
|
Annotations: CY |
|
| 507.05 | 0.2 |
| 508.66 | 0.2 |
| 509.18 | 0.3 |
| 510.04 | 0.9 |
|
Annotations: BZ |
|
| 511.14 | 0.6 |
| 511.95 | 0.2 |
| 512.9 | 0.6 |
| 513.93 | 0.2 |
| 515.98 | 0.1 |
| 516.69 | 0.4 |
| 517.82 | 0.5 |
| 518.96 | 0.3 |
| 520.01 | 0.4 |
| 521.16 | 2.2 |
| 522.01 | 3.1 |
| 522.74 | 0.2 |
| 524.86 | 0.3 |
| 525.58 | 0.1 |
| 526.66 | 0.4 |
| 527.27 | 0.3 |
| 528.29 | 34.0 |
|
Annotations: BY |
|
| 529.34 | 3.2 |
| 530.46 | 0.7 |
| 535.44 | 0.1 |
| 536.82 | 0.2 |
| 538.17 | 0.3 |
| 538.99 | 2.3 |
| 540.06 | 1.7 |
| 541.12 | 0.8 |
| 541.95 | 0.6 |
| 542.77 | 0.2 |
| 544.17 | 0.1 |
| 544.68 | 0.2 |
| 545.62 | 0.3 |
| 546.34 | 0.3 |
|
Annotations: CY |
|
| 547.48 | 0.4 |
| 548.03 | 0.4 |
| 548.9 | 6.4 |
| 549.57 | 0.5 |
| 556.79 | 0.2 |
| 557.69 | 0.1 |
| 558.91 | 0.5 |
| 564.55 | 0.3 |
| 567.69 | 0.1 |
| 569.28 | 2.1 |
|
Annotations: YZ |
|
| 570.21 | 0.7 |
| 571.39 | 0.1 |
| 574.3 | 0.2 |
| 586.4 | 0.1 |
| 587.37 | 13.7 |
|
Annotations: YY |
|
| 588.26 | 1.4 |
| 591.17 | 0.1 |
| 610.25 | 0.2 |
| 610.92 | 0.4 |
| 634.5 | 0.1 |
| 641.29 | 0.2 |
| 644.24 | 0.3 |
| 657.43 | 0.1 |
| 672.12 | 0.1 |
|
Annotations: BZ |
|
| 673.38 | 0.1 |
| 675.37 | 0.2 |
| 681.68 | 0.1 |
| 682.9 | 0.4 |
| 688.61 | 0.3 |
| 689.53 | 0.8 |
| 690.38 | 50.9 |
|
Annotations: B |
|
| 691.39 | 7.1 |
| 694.38 | 0.1 |
| 696.27 | 0.2 |
| 697.9 | 0.1 |
| 703.52 | 0.3 |
| 705.37 | 0.1 |
| 707.73 | 0.1 |
| 708.33 | 0.7 |
|
Annotations: C |
|
| 709.38 | 0.1 |
| 710.09 | 0.1 |
| 714.99 | 0.2 |
| 726.26 | 0.2 |
| 729.66 | 0.2 |
| 730.55 | 0.7 |
| 731.44 | 26.4 |
|
Annotations: Z |
|
| 732.5 | 4.1 |
| 733.11 | 0.2 |
| 735.67 | 0.3 |
| 747.61 | 0.7 |
| 748.5 | 1.3 |
| 749.41 | 78.3 |
|
Annotations: Y |
|
| 750.42 | 14.3 |
| 750.93 | 0.1 |
| 788.46 | 0.1 |
| 802.29 | 0.2 |
| 852.87 | 0.1 |
| 861.5 | 0.1 |
| 876.19 | 0.2 |
| 891.25 | 0.3 |
| 892.0 | 0.5 |
| 892.67 | 0.6 |
| 893.47 | 47.4 |
|
Annotations: B |
|
| 894.45 | 8.5 |
| 895.36 | 0.7 |
| 907.58 | 0.1 |
| 908.45 | 0.1 |
| 909.04 | 0.3 |
| 910.0 | 3.4 |
| 910.72 | 3.8 |
| 911.45 | 180.5 |
|
Annotations: C |
|
| 912.46 | 37.5 |
| 913.18 | 0.5 |
| 914.66 | 0.2 |
| 934.41 | 0.1 |
|
Annotations: Z |
|
| 952.73 | 0.3 |
|
Annotations: Y |
|
| 963.59 | 0.2 |
| 964.39 | 0.1 |