Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 186.13 | 184.8 |
|
Annotations: BZ |
|
| 187.14 | 32.8 |
| 191.16 | 0.5 |
| 203.27 | 2.6 |
| 204.09 | 2293.8 |
|
Annotations: Z |
|
| 205.08 | 161.0 |
|
Annotations: ^{1,3}A_{Man}Z |
|
| 221.01 | 2.9 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 222.21 | 164.8 |
|
Annotations: Y |
|
| 234.05 | 0.9 |
| 241.18 | 12.4 |
| 247.21 | 2.1 |
| 249.25 | 1.1 |
| 253.22 | 10.8 |
|
Annotations: CY |
|
| 254.27 | 2.9 |
| 267.11 | 1.4 |
|
Annotations: ^{2,5}A_{GlcNAc} |
|
| 269.13 | 1.9 |
| 277.21 | 0.4 |
| 279.27 | 1.1 |
| 298.16 | 0.5 |
| 301.99 | 21.7 |
| 307.13 | 0.7 |
|
Annotations: BZ |
|
| 316.1 | 0.7 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 324.03 | 0.7 |
| 326.37 | 1.9 |
| 330.17 | 41.5 |
| 340.28 | 0.4 |
| 343.8 | 0.6 |
| 348.25 | 183.3 |
|
Annotations: BZ |
|
| 357.21 | 0.3 |
|
Annotations: ZZ |
|
| 361.1 | 0.3 |
| 363.87 | 16.0 |
| 364.78 | 99.3 |
| 365.36 | 6.6 |
| 366.17 | 9639.8 |
|
Annotations: B |
|
| 367.24 | 1174.6 |
| 368.27 | 14.0 |
| 369.16 | 1.5 |
| 376.51 | 1.3 |
| 381.39 | 0.4 |
| 383.22 | 1.8 |
| 384.63 | 46.5 |
|
Annotations: C |
|
| 388.18 | 1.0 |
| 389.21 | 2.2 |
| 403.21 | 0.4 |
| 405.87 | 2.3 |
|
Annotations: ^{0,2}A_{Man} |
|
| 407.19 | 42.4 |
|
Annotations: Z |
|
| 408.28 | 2.7 |
|
Annotations: ^{1,3}A_{Man}Z |
|
| 413.4 | 0.3 |
| 414.18 | 0.6 |
| 416.04 | 0.4 |
| 420.03 | 1.5 |
| 421.07 | 0.6 |
| 425.25 | 351.6 |
|
Annotations: Y |
|
| 426.25 | 1.5 |
|
Annotations: B |
|
| 439.32 | 3.5 |
| 441.32 | 2.3 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 443.27 | 2.2 |
| 444.12 | 1.3 |
| 447.06 | 0.9 |
|
Annotations: Z |
|
| 447.81 | 47.0 |
| 455.52 | 0.8 |
| 458.17 | 1.5 |
| 459.09 | 2.2 |
|
Annotations: ZZ |
|
| 461.98 | 0.6 |
| 467.77 | 99.4 |
|
Annotations: YZ |
|
| 472.05 | 0.7 |
| 475.43 | 1.5 |
| 476.1 | 0.6 |
| 477.06 | 1.5 |
|
Annotations: YY |
|
| 480.45 | 2.0 |
| 481.22 | 2.2 |
| 482.19 | 1.5 |
| 492.45 | 0.6 |
| 496.12 | 0.9 |
| 499.03 | 1.5 |
| 500.13 | 0.6 |
|
Annotations: ^{1,5}A_{Man} |
|
| 503.35 | 2.9 |
| 504.25 | 0.7 |
| 509.37 | 1.6 |
| 510.35 | 1.1 |
|
Annotations: BZ |
|
| 516.19 | 0.5 |
| 518.11 | 1.4 |
| 519.22 | 1.1 |
| 521.3 | 1.9 |
| 523.26 | 1.4 |
| 524.12 | 0.8 |
| 525.25 | 1.8 |
| 526.39 | 85.5 |
| 527.23 | 142.7 |
| 528.29 | 2117.2 |
|
Annotations: B |
|
| 529.27 | 282.8 |
| 530.61 | 1.0 |
| 532.05 | 2.0 |
| 533.37 | 1.2 |
| 534.41 | 1.6 |
| 535.17 | 1.8 |
| 540.09 | 0.4 |
| 541.12 | 0.3 |
| 546.32 | 4.2 |
|
Annotations: C |
|
| 548.71 | 45.3 |
|
Annotations: Z |
|
| 549.36 | 2.6 |
| 550.24 | 1.1 |
| 552.28 | 0.8 |
| 557.94 | 6.2 |
|
Annotations: Y |
|
| 559.27 | 2.6 |
| 562.06 | 0.6 |
| 563.35 | 0.8 |
| 565.4 | 0.7 |
| 566.46 | 0.3 |
| 567.36 | 53.9 |
| 568.55 | 0.7 |
| 569.27 | 91.6 |
|
Annotations: YZ |
|
| 570.33 | 16.5 |
| 575.05 | 1.2 |
| 576.13 | 3.9 |
| 577.32 | 1.4 |
| 578.29 | 1.0 |
| 579.09 | 1.0 |
| 581.85 | 0.5 |
| 582.41 | 2.3 |
| 583.82 | 1.1 |
| 585.45 | 5.5 |
| 586.42 | 5.7 |
| 587.39 | 381.3 |
|
Annotations: YY |
|
| 588.4 | 2.7 |
|
Annotations: ^{1,3}A_{Man} |
|
| 589.21 | 1.8 |
| 590.76 | 5.7 |
| 592.0 | 1.0 |
| 593.64 | 1.7 |
| 594.42 | 1.9 |
| 595.47 | 5.0 |
| 596.01 | 0.4 |
| 597.69 | 1.3 |
| 601.47 | 0.9 |
| 602.53 | 1.9 |
| 603.15 | 0.8 |
| 607.35 | 1.1 |
| 609.38 | 0.8 |
| 612.05 | 1.7 |
| 619.39 | 1.9 |
| 620.25 | 9.7 |
| 621.29 | 10.1 |
| 622.33 | 7.2 |
| 623.2 | 1.4 |
| 637.54 | 6.8 |
| 638.15 | 1.1 |
| 638.98 | 1.7 |
| 639.55 | 1.1 |
| 659.05 | 1.0 |
| 688.35 | 1.4 |
| 689.24 | 81.2 |
| 690.33 | 2296.9 |
|
Annotations: BY |
|
| 691.46 | 584.5 |
| 692.58 | 1.9 |
| 708.49 | 105.2 |
|
Annotations: CY |
|
| 709.54 | 30.8 |
| 713.3 | 0.4 |
|
Annotations: ZZ |
|
| 730.39 | 0.3 |
| 731.39 | 1306.5 |
|
Annotations: Z |
|
| 732.37 | 410.6 |
| 733.15 | 52.7 |
| 733.99 | 0.6 |
| 736.39 | 1.0 |
| 747.38 | 1.4 |
| 748.76 | 12.5 |
| 749.43 | 1792.6 |
|
Annotations: Y |
|
| 750.52 | 414.2 |
| 764.41 | 2.4 |
| 847.84 | 1.3 |
| 851.48 | 51.6 |
| 852.43 | 99.7 |
|
Annotations: B |
|
| 875.46 | 10.8 |
|
Annotations: BZ |
|
| 891.31 | 6.9 |
| 891.84 | 0.9 |
| 892.51 | 4.2 |
| 893.39 | 3825.4 |
|
Annotations: Z |
|
| 894.43 | 1136.8 |
| 895.39 | 79.5 |
| 909.38 | 47.3 |
| 910.4 | 28.2 |
| 911.42 | 3230.6 |
|
Annotations: Y |
|
| 912.44 | 792.6 |
| 913.48 | 23.0 |
| 1038.23 | 0.7 |
| 1054.57 | 0.7 |
| 1055.56 | 182.3 |
|
Annotations: B |
|
| 1056.67 | 257.0 |
| 1073.62 | 64.9 |
|
Annotations: C |
|
| 1074.42 | 0.4 |
| 1090.59 | 0.2 |
| 1093.51 | 20.5 |
| 1095.61 | 0.7 |
| 1117.1 | 0.5 |