Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 185.2 | 0.6 |
| 186.1 | 134.7 |
|
Annotations: BZ |
|
| 187.11 | 1.4 |
| 204.06 | 1439.4 |
|
Annotations: Z |
|
| 205.15 | 55.7 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 222.13 | 249.3 |
|
Annotations: Y |
|
| 223.15 | 13.3 |
|
Annotations: ^{2,4}A_{GlcNAc} |
|
| 228.14 | 1.9 |
|
Annotations: ^{1,4}A_{Man} |
|
| 241.21 | 1.2 |
| 247.23 | 0.3 |
| 269.2 | 1.2 |
| 289.12 | 0.9 |
| 300.19 | 1.9 |
| 305.9 | 4.0 |
| 312.08 | 0.7 |
| 314.75 | 0.7 |
| 324.41 | 0.5 |
|
Annotations: ^{0,2}A_{Man}Y |
|
| 325.22 | 8.9 |
|
Annotations: BY |
|
| 326.37 | 1.6 |
| 330.12 | 11.0 |
| 331.08 | 0.4 |
| 343.15 | 1.2 |
|
Annotations: CY |
|
| 348.18 | 19.3 |
|
Annotations: BZ |
|
| 354.17 | 1.7 |
|
Annotations: CY |
|
| 362.09 | 1.2 |
| 364.63 | 4.7 |
| 365.35 | 28.3 |
| 366.15 | 7851.0 |
|
Annotations: B |
|
| 367.17 | 643.4 |
| 367.87 | 8.6 |
| 371.96 | 2.5 |
| 384.15 | 8.2 |
|
Annotations: C |
|
| 385.4 | 4.2 |
| 386.68 | 0.6 |
| 389.24 | 1.6 |
| 393.78 | 1.8 |
| 395.94 | 9.5 |
| 404.84 | 1.6 |
| 406.41 | 3.3 |
| 407.33 | 45.7 |
|
Annotations: Z |
|
| 408.13 | 2.5 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 409.28 | 0.8 |
| 410.79 | 1.8 |
|
Annotations: ^{2,5}A_{Man}Z |
|
| 416.0 | 1.5 |
| 418.17 | 1.3 |
| 423.82 | 1.6 |
| 424.38 | 1.2 |
| 425.25 | 207.0 |
|
Annotations: Y |
|
| 426.3 | 17.5 |
|
Annotations: B |
|
| 427.3 | 0.6 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 429.22 | 3.5 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 438.22 | 5.3 |
|
Annotations: BZ |
|
| 446.58 | 4.2 |
| 447.29 | 909.2 |
|
Annotations: Z |
|
| 447.95 | 22.0 |
| 449.2 | 1.2 |
| 451.28 | 1.4 |
| 456.27 | 4.2 |
|
Annotations: Y |
|
| 457.88 | 1.3 |
| 459.03 | 2.5 |
|
Annotations: ZZ |
|
| 466.36 | 1.2 |
| 467.83 | 238.9 |
|
Annotations: ZY |
|
| 468.7 | 5.0 |
|
Annotations: BZ |
|
| 473.38 | 4.3 |
| 475.49 | 9.5 |
| 476.84 | 266.9 |
|
Annotations: YY |
|
| 477.66 | 19.0 |
| 478.54 | 2.4 |
| 479.47 | 2.5 |
| 481.93 | 0.3 |
| 486.24 | 0.7 |
| 487.17 | 3.2 |
|
Annotations: BY |
|
| 488.3 | 0.4 |
| 492.18 | 2.2 |
| 503.5 | 1.0 |
| 505.23 | 1.0 |
|
Annotations: CY |
|
| 510.18 | 0.4 |
|
Annotations: BZ |
|
| 519.8 | 1.9 |
| 526.07 | 12.2 |
| 527.25 | 38.4 |
| 528.22 | 4566.2 |
|
Annotations: B |
|
| 529.22 | 488.5 |
| 529.79 | 3.6 |
| 530.72 | 5.0 |
| 531.38 | 1.8 |
| 533.21 | 0.9 |
| 534.97 | 0.7 |
| 537.22 | 6.7 |
|
Annotations: C |
|
| 539.67 | 13.5 |
| 540.36 | 1.1 |
| 541.22 | 1.2 |
| 546.28 | 25.7 |
|
Annotations: C |
|
| 547.94 | 17.7 |
| 548.86 | 590.4 |
|
Annotations: Z |
|
| 549.37 | 27.4 |
| 549.89 | 6.4 |
| 551.23 | 5.5 |
|
Annotations: ZZ |
|
| 555.11 | 0.7 |
| 555.64 | 3.1 |
| 556.85 | 39.4 |
| 557.82 | 1863.8 |
|
Annotations: Y |
|
| 558.43 | 94.6 |
| 559.01 | 18.6 |
| 560.86 | 4.0 |
| 561.93 | 1.5 |
| 563.88 | 2.5 |
| 565.18 | 2.7 |
| 566.11 | 2.4 |
| 567.22 | 3.3 |
| 568.44 | 2.0 |
| 569.29 | 302.3 |
|
Annotations: ZY |
|
| 570.3 | 18.4 |
| 571.93 | 1.7 |
| 574.89 | 2.7 |
| 576.26 | 0.9 |
| 585.44 | 7.1 |
| 586.59 | 2.6 |
| 587.29 | 747.3 |
|
Annotations: YY |
|
| 588.29 | 102.2 |
|
Annotations: ^{0,4}A_{Man} |
|
| 594.47 | 0.3 |
| 611.8 | 3.8 |
| 613.28 | 2.1 |
| 621.05 | 15.2 |
| 623.17 | 2.6 |
| 628.22 | 2.0 |
| 628.8 | 3.9 |
| 629.79 | 53.0 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 630.45 | 1.9 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 638.76 | 4.6 |
| 654.33 | 7.0 |
| 672.34 | 8.5 |
|
Annotations: BZ |
|
| 673.33 | 1.4 |
| 677.37 | 3.0 |
| 688.51 | 8.2 |
| 689.55 | 30.1 |
| 690.29 | 2366.5 |
|
Annotations: BY |
|
| 691.31 | 371.4 |
| 692.03 | 4.3 |
| 693.01 | 1.4 |
| 696.21 | 2.6 |
| 707.74 | 0.6 |
| 708.4 | 28.8 |
|
Annotations: CY |
|
| 709.27 | 1.4 |
| 713.28 | 16.7 |
|
Annotations: ZZ |
|
| 714.08 | 0.6 |
| 729.21 | 3.8 |
| 729.98 | 5.7 |
| 730.65 | 6.1 |
| 731.32 | 1506.9 |
|
Annotations: Z |
|
| 732.32 | 267.8 |
| 733.28 | 5.5 |
| 746.54 | 2.7 |
| 747.35 | 20.6 |
| 748.34 | 85.6 |
| 749.3 | 3715.9 |
|
Annotations: Y |
|
| 750.34 | 632.0 |
| 751.06 | 10.9 |
| 752.28 | 1.6 |
| 773.22 | 3.0 |
| 780.13 | 1.1 |
| 790.37 | 4.8 |
| 798.31 | 5.2 |
| 810.62 | 1.0 |
|
Annotations: ^{0,2}A_{Man} |
|
| 816.35 | 1.2 |
| 850.51 | 0.7 |
| 852.36 | 54.7 |
|
Annotations: B |
|
| 853.37 | 8.3 |
| 857.33 | 1.2 |
| 858.05 | 5.9 |
| 869.49 | 2.0 |
| 870.44 | 5.6 |
|
Annotations: C |
|
| 871.28 | 2.2 |
| 873.78 | 1.0 |
| 875.42 | 6.8 |
|
Annotations: BZ |
|
| 875.95 | 2.1 |
| 877.43 | 1.8 |
| 890.72 | 2.8 |
| 891.98 | 10.8 |
| 892.68 | 3.6 |
| 893.36 | 1265.7 |
|
Annotations: Z |
|
| 894.36 | 288.8 |
| 909.67 | 30.6 |
| 910.58 | 137.3 |
| 911.34 | 4662.5 |
|
Annotations: Y |
|
| 912.38 | 1039.3 |
| 913.28 | 19.9 |
| 916.27 | 0.9 |
|
Annotations: ZZ |
|
| 933.67 | 0.6 |
| 934.49 | 25.2 |
|
Annotations: ZY |
|
| 935.41 | 6.2 |
| 952.45 | 23.7 |
|
Annotations: YY |
|
| 953.41 | 5.7 |
| 954.0 | 2.7 |
| 994.26 | 1.1 |
| 1002.45 | 0.9 |
| 1035.53 | 2.5 |
| 1036.08 | 1.4 |
| 1037.53 | 3.4 |
| 1052.56 | 1.7 |
| 1053.45 | 5.7 |
| 1054.0 | 0.9 |
| 1054.58 | 25.4 |
| 1055.45 | 550.0 |
|
Annotations: B |
|
| 1056.43 | 194.8 |
| 1057.33 | 3.1 |
| 1072.53 | 3.8 |
| 1073.49 | 76.7 |
|
Annotations: C |
|
| 1074.53 | 21.2 |
| 1075.67 | 1.5 |
| 1095.19 | 0.6 |
| 1096.59 | 12.0 |
|
Annotations: Z |
|
| 1097.44 | 5.2 |
| 1114.56 | 17.4 |
|
Annotations: Y |
|
| 1115.5 | 10.3 |