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Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library

Peak	Intensity
163.0	2.3
Annotations: B
167.2	1.2
168.05	752.9
169.09	38.3
Annotations: ^{1,5}A_{Man}Y ^{1,5}A_{GlcNAc}
169.97	2.9
Annotations: ^{1,5}A_{Man}Y ^{1,5}A_{GlcNAc}
172.37	0.2
Annotations: CY
173.19	0.3
181.6	1.4
184.11	2.4
186.09	352.3
Annotations: BZ BZ
187.08	22.2
188.03	0.5
195.16	0.9
201.19	1.3
201.99	4.3
202.87	3.6
204.06	2699.7
Annotations: Z Z
205.11	135.5
Annotations: ^{1,3}A_{Man}Z ^{2,4}A_{Man}Z
205.91	3.3
207.13	0.7
213.07	1.2
Annotations: Y
220.11	1.3
221.15	1.8
222.11	253.9
Annotations: Y
222.99	10.0
Annotations: ^{2,4}A_{GlcNAc} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y
224.4	2.4
225.73	1.3
227.28	0.9
239.28	1.4
241.16	2.6
Annotations: ^{1,5}A_{Man}Z
246.1	1.3
Annotations: ^{1,3}A_{Man}Z
259.11	0.9
264.17	1.0
Annotations: B
265.26	1.1
Annotations: ^{0,2}A_{Man}Z
269.23	1.2
272.03	0.9
276.25	1.0
Annotations: ^{1,4}A_{Man}Z
280.18	1.7
282.32	1.2
284.56	0.7
285.47	1.9
Annotations: Z
287.15	2.8
305.11	2.8
306.05	1.8
310.17	0.9
311.18	0.8
313.87	0.8
315.16	0.8
317.11	1.0
Annotations: ^{2,5}A_{Man}
319.1	0.7
322.53	1.3
324.27	1.3
Annotations: ^{0,2}A_{Man}
325.97	1.0
327.9	1.2
329.41	1.1
330.17	15.4
336.16	2.9
340.11	1.3
341.98	1.0
343.94	2.8
345.54	0.9
Annotations: B
346.17	3.2
348.16	32.3
Annotations: BZ BZ
349.15	0.8
350.21	4.0
352.1	0.4
357.15	3.9
Annotations: BZ
357.79	1.1
359.12	0.3
362.56	2.5
363.34	0.7
364.25	57.8
365.21	46.4
366.16	12911.8
Annotations: B Z
367.18	1142.4
367.91	16.1
369.39	3.5
370.11	1.2
371.08	3.6
372.21	2.2
374.04	0.8
375.34	9.7
Annotations: Y
381.32	1.5
383.62	0.1
384.22	21.0
Annotations: C
385.18	6.6
386.74	9.2
389.38	4.6
390.11	1.9
390.9	1.0
394.89	3.1
395.96	8.7
397.24	0.8
398.2	2.4
399.44	1.4
400.28	1.0
401.02	2.0
402.18	0.9
403.72	0.9
405.32	10.1
406.36	0.8
407.27	157.3
Annotations: Z
408.24	19.3
Annotations: ^{1,3}A_{Man}Z ^{2,4}A_{Man}Z
409.18	0.9
410.36	0.8
411.29	0.8
411.84	2.2
413.29	0.4
414.35	5.7
415.29	0.8
420.3	0.8
421.93	0.8
423.29	6.3
424.29	4.8
425.25	483.5
Annotations: Y
426.25	57.9
Annotations: ^{1,3}A_{Man} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y
427.28	3.7
427.95	1.1
428.72	0.6
429.69	3.8
431.28	0.4
432.19	0.8
433.69	1.0
434.26	1.0
435.46	0.7
436.08	1.7
436.99	2.2
438.17	6.7
Annotations: ^{1,4}A_{Man}Z
440.21	0.9
441.93	1.1
444.16	3.1
446.35	68.7
447.26	3142.2
Annotations: B
447.87	305.3
448.76	12.9
449.89	41.1
452.15	2.0
Annotations: ^{2,5}A_{Man}Z
456.35	152.5
Annotations: C
456.97	13.5
458.13	13.3
458.68	1.2
459.25	13.0
460.03	2.1
461.19	1.9
462.52	0.2
464.49	1.2
466.11	2.3
466.79	16.1
467.81	659.4
Annotations: Z
468.36	57.0
Annotations: ^{0,2}A_{Man}Z
468.92	6.4
470.33	2.3
Annotations: ^{2,5}A_{Man}Y
471.33	2.1
472.28	1.1
473.0	1.2
475.12	1.2
475.75	16.2
476.82	144.5
Annotations: Y
477.93	43.9
479.17	5.1
480.1	3.8
482.21	4.0
Annotations: ^{1,5}A_{Man}Z
484.91	0.8
485.77	1.1
Annotations: ^{0,2}A_{Man}Y
486.5	0.5
Annotations: ^{0,2}A_{Man}Y
487.69	0.9
489.29	4.1
491.04	3.9
492.3	5.4
494.06	0.7
496.18	2.3
497.07	8.1
497.99	2.7
499.07	0.7
504.76	1.7
507.81	0.7
508.98	2.8
510.27	10.9
Annotations: BZ BZ
511.12	8.3
512.14	2.0
513.19	4.7
514.18	2.8
518.01	0.2
518.96	1.1
521.66	4.2
522.42	1.0
523.96	1.3
525.69	2.3
526.45	19.6
527.15	28.1
528.23	6333.0
Annotations: B
529.25	1006.8
529.99	9.7
530.57	16.7
533.43	0.7
537.31	0.9
538.26	0.8
539.27	40.7
540.15	22.2
541.28	4.2
542.43	4.6
544.3	2.5
546.3	52.5
Annotations: C
546.93	2.3
547.8	75.2
548.79	2068.5
549.34	94.6
550.1	9.6
551.09	2.3
553.11	4.0
558.95	1.6
564.27	0.9
567.45	11.6
568.29	12.6
569.3	892.2
Annotations: Z
570.3	131.5
571.43	3.2
577.11	0.7
584.77	1.2
585.6	15.1
586.41	24.6
587.29	1393.1
Annotations: Y
588.33	231.1
Annotations: ^{1,3}A_{Man} ^{2,4}A_{Man}
589.18	5.9
590.26	1.8
605.59	1.0
606.21	1.1
608.35	1.6
611.38	0.7
626.38	1.5
627.56	0.2
668.25	0.3
677.31	1.2
681.64	3.2
683.98	0.7
688.95	4.1
690.35	135.5
Annotations: B
691.33	18.8
692.06	1.0
693.45	0.9
695.22	0.9
695.79	3.0
696.42	3.8
702.43	0.9
706.31	4.4
707.64	4.9
708.34	63.4
Annotations: C
709.34	15.8
712.61	1.7
713.34	16.5
Annotations: BZ
714.35	6.2
727.98	2.0
729.51	27.7
730.45	56.7
731.31	5881.3
Annotations: Z
732.35	1338.0
733.2	30.6
733.75	5.2
741.43	1.2
746.4	7.8
747.63	135.2
748.48	99.8
749.31	7742.1
Annotations: Y
750.36	1388.6
751.33	43.3
752.13	5.7
753.7	1.6
764.88	1.5
772.57	0.8
774.36	0.6
811.58	1.4
857.47	1.3
858.46	0.9
874.52	1.1
875.37	6.8
876.3	3.3
890.79	2.2
891.58	9.6
892.57	4.4
893.42	438.3
Annotations: B
894.4	107.3
895.47	6.4
909.32	0.7
910.01	1.4
910.58	4.8
911.44	99.8
Annotations: C
912.44	19.0
934.43	10.7
Annotations: Z
935.6	0.9
950.56	0.6
952.48	10.8
Annotations: Y
953.45	2.6
1076.43	2.0