Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
Peak | Intensity |
---|---|
162.14 | 0.6 |
166.73 | 1.4 |
167.46 | 0.6 |
168.06 | 777.9 |
169.11 | 36.5 |
Annotations: ^{1,5}A_{Man}Y ^{1,5}A_{GlcNAc} |
|
170.02 | 1.0 |
Annotations: ^{1,5}A_{GlcNAc} ^{1,5}A_{Man}Y |
|
171.05 | 1.2 |
173.05 | 1.5 |
183.97 | 0.4 |
Annotations: B |
|
186.11 | 484.5 |
Annotations: BZ BZ |
|
187.14 | 18.2 |
188.06 | 0.6 |
195.06 | 0.6 |
202.15 | 1.8 |
202.98 | 10.6 |
204.08 | 3562.4 |
Annotations: Z Z |
|
205.14 | 177.5 |
Annotations: ^{0,4}A_{Man}Z |
|
206.0 | 1.5 |
220.47 | 0.5 |
Annotations: ^{3,5}A_{Man}Y |
|
221.48 | 3.8 |
222.14 | 549.0 |
Annotations: Y |
|
223.16 | 21.9 |
Annotations: ^{0,4}A_{Man}Y ^{2,4}A_{GlcNAc} |
|
224.14 | 2.0 |
227.19 | 0.6 |
241.13 | 3.0 |
Annotations: ^{1,5}A_{Man}Z |
|
246.11 | 0.6 |
Annotations: ^{1,3}A_{Man}Z |
|
253.15 | 2.4 |
Annotations: ^{0,3}A_{GlcNAc} ^{0,3}A_{Man}Y |
|
257.13 | 1.9 |
270.1 | 1.6 |
270.6 | 0.6 |
274.79 | 0.7 |
276.09 | 0.9 |
Annotations: ^{1,4}A_{Man}Z |
|
285.27 | 0.9 |
Annotations: Z |
|
288.49 | 0.6 |
289.22 | 1.6 |
301.25 | 0.5 |
Annotations: ^{3,5}A_{Man} |
|
303.98 | 0.6 |
305.83 | 2.2 |
307.17 | 0.5 |
Annotations: BZ |
|
312.8 | 0.9 |
314.71 | 6.6 |
325.28 | 2.5 |
Annotations: BY CZ |
|
325.93 | 1.1 |
326.86 | 1.3 |
330.19 | 4.5 |
331.23 | 0.3 |
Annotations: ^{1,5}A_{Man} |
|
341.43 | 0.8 |
342.98 | 2.3 |
Annotations: CY |
|
345.43 | 0.3 |
Annotations: B |
|
346.13 | 0.4 |
347.38 | 2.3 |
348.27 | 26.9 |
Annotations: BZ BZ |
|
349.1 | 0.9 |
354.23 | 1.2 |
Annotations: C |
|
357.24 | 1.0 |
Annotations: BZ |
|
357.86 | 0.9 |
364.36 | 8.4 |
365.09 | 35.2 |
366.2 | 13896.8 |
Annotations: B Z |
|
367.23 | 1182.3 |
368.1 | 13.6 |
369.19 | 0.9 |
371.59 | 0.9 |
375.34 | 3.4 |
Annotations: Y |
|
379.77 | 0.7 |
382.33 | 1.4 |
384.33 | 29.5 |
Annotations: C |
|
385.25 | 0.6 |
386.7 | 12.6 |
389.37 | 1.5 |
394.82 | 1.4 |
395.78 | 17.4 |
401.28 | 0.9 |
404.78 | 0.9 |
405.28 | 1.2 |
407.27 | 80.7 |
Annotations: Z |
|
408.2 | 9.0 |
Annotations: ^{0,4}A_{Man}Z |
|
409.12 | 2.2 |
411.87 | 1.0 |
420.22 | 0.9 |
424.44 | 1.3 |
425.29 | 287.4 |
Annotations: Y |
|
426.26 | 24.7 |
Annotations: ^{1,3}A_{Man} ^{0,4}A_{Man}Y |
|
430.36 | 2.4 |
431.72 | 0.7 |
432.56 | 0.6 |
433.34 | 1.8 |
438.28 | 4.8 |
Annotations: ^{0,3}A_{Man}Z |
|
439.73 | 2.1 |
Annotations: ^{3,5}A_{Man}Y |
|
444.53 | 1.2 |
446.19 | 13.5 |
447.32 | 4314.6 |
Annotations: B |
|
447.92 | 208.9 |
448.87 | 8.5 |
449.95 | 9.4 |
450.96 | 2.0 |
452.08 | 3.9 |
Annotations: ^{2,5}A_{Man}Z |
|
453.03 | 0.8 |
456.26 | 23.5 |
Annotations: C |
|
458.95 | 9.8 |
459.71 | 2.0 |
466.78 | 7.1 |
467.87 | 593.0 |
Annotations: Z |
|
468.6 | 27.2 |
Annotations: ^{0,2}A_{Man}Z |
|
469.12 | 0.9 |
469.79 | 1.3 |
Annotations: ^{2,5}A_{Man}Y |
|
475.13 | 0.7 |
475.91 | 1.8 |
476.9 | 285.8 |
Annotations: Y |
|
477.54 | 3.4 |
478.2 | 4.3 |
479.0 | 0.4 |
479.51 | 0.7 |
481.4 | 0.3 |
482.12 | 0.8 |
Annotations: ^{1,5}A_{Man}Z |
|
484.68 | 0.9 |
486.34 | 2.9 |
Annotations: ^{0,2}A_{Man}Y |
|
487.09 | 0.8 |
488.04 | 0.9 |
490.2 | 0.9 |
492.29 | 7.8 |
493.31 | 1.4 |
510.32 | 20.1 |
Annotations: BZ BZ |
|
511.15 | 0.3 |
514.31 | 0.5 |
526.15 | 5.5 |
526.82 | 38.9 |
527.59 | 8.5 |
528.26 | 6399.4 |
Annotations: B |
|
529.3 | 912.2 |
530.26 | 19.5 |
530.9 | 3.2 |
531.51 | 1.0 |
533.34 | 0.5 |
538.81 | 1.3 |
540.01 | 13.5 |
545.19 | 3.1 |
545.75 | 0.3 |
Annotations: C |
|
546.35 | 94.8 |
Annotations: C |
|
547.31 | 8.6 |
547.99 | 21.8 |
548.87 | 742.1 |
549.54 | 17.9 |
550.19 | 7.2 |
553.38 | 1.6 |
554.78 | 1.0 |
558.81 | 1.1 |
567.74 | 3.0 |
568.29 | 1.3 |
569.33 | 721.0 |
Annotations: Z |
|
570.37 | 133.3 |
571.13 | 1.1 |
576.76 | 0.4 |
577.64 | 0.6 |
584.98 | 2.9 |
585.66 | 12.7 |
586.39 | 24.9 |
587.32 | 2165.5 |
Annotations: Y |
|
588.37 | 353.7 |
Annotations: ^{0,4}A_{Man} |
|
589.25 | 9.7 |
603.69 | 1.5 |
609.37 | 1.7 |
611.48 | 0.6 |
612.53 | 0.4 |
628.48 | 6.4 |
629.46 | 1.0 |
630.48 | 1.9 |
636.37 | 4.4 |
648.48 | 0.7 |
Annotations: ^{0,2}A_{Man} |
|
652.47 | 1.1 |
654.39 | 3.3 |
672.33 | 3.1 |
687.12 | 0.9 |
688.38 | 2.1 |
689.16 | 2.7 |
690.38 | 286.9 |
Annotations: B |
|
691.38 | 43.9 |
695.54 | 6.9 |
696.47 | 0.6 |
706.28 | 0.9 |
707.66 | 5.4 |
708.44 | 36.8 |
Annotations: C |
|
709.45 | 5.8 |
710.23 | 1.9 |
712.58 | 2.3 |
713.39 | 16.9 |
Annotations: BZ |
|
714.4 | 8.8 |
729.75 | 19.2 |
730.49 | 36.0 |
731.36 | 4885.9 |
Annotations: Z |
|
732.39 | 1037.9 |
733.22 | 26.7 |
736.13 | 2.0 |
745.93 | 0.5 |
746.91 | 12.5 |
747.81 | 123.7 |
748.64 | 134.2 |
749.37 | 8089.4 |
Annotations: Y |
|
750.4 | 1528.5 |
751.21 | 40.2 |
752.01 | 5.8 |
753.21 | 2.2 |
754.19 | 1.3 |
767.45 | 0.6 |
781.46 | 1.1 |
789.76 | 1.4 |
790.49 | 1.2 |
809.58 | 0.7 |
810.39 | 0.7 |
821.51 | 2.3 |
857.12 | 0.8 |
875.47 | 16.5 |
876.47 | 0.9 |
888.24 | 2.3 |
890.7 | 2.4 |
891.69 | 4.8 |
892.44 | 21.7 |
893.46 | 981.2 |
Annotations: B |
|
894.47 | 248.3 |
895.42 | 7.6 |
909.33 | 0.6 |
909.9 | 3.1 |
910.68 | 4.2 |
911.5 | 130.4 |
Annotations: C |
|
912.47 | 18.2 |
934.57 | 26.3 |
Annotations: Z |
|
935.42 | 8.9 |
950.93 | 0.5 |
952.55 | 13.9 |
Annotations: Y |
|
953.3 | 2.2 |