Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 162.14 | 0.6 |
| 166.73 | 1.4 |
| 167.46 | 0.6 |
| 168.06 | 777.9 |
| 169.11 | 36.5 |
|
Annotations: ^{1,5}A_{GlcNAc} |
|
| 170.02 | 1.0 |
|
Annotations: ^{1,5}A_{GlcNAc} |
|
| 171.05 | 1.2 |
| 173.05 | 1.5 |
| 183.97 | 0.4 |
|
Annotations: B |
|
| 186.11 | 484.5 |
|
Annotations: BZ |
|
| 187.14 | 18.2 |
| 188.06 | 0.6 |
| 195.06 | 0.6 |
| 202.15 | 1.8 |
| 202.98 | 10.6 |
| 204.08 | 3562.4 |
|
Annotations: Z |
|
| 205.14 | 177.5 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 206.0 | 1.5 |
| 220.47 | 0.5 |
|
Annotations: ^{3,5}A_{Man}Y |
|
| 221.48 | 3.8 |
| 222.14 | 549.0 |
|
Annotations: Y |
|
| 223.16 | 21.9 |
|
Annotations: ^{0,4}A_{Man}Y |
|
| 224.14 | 2.0 |
| 227.19 | 0.6 |
| 241.13 | 3.0 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 246.11 | 0.6 |
|
Annotations: ^{1,3}A_{Man}Z |
|
| 253.15 | 2.4 |
|
Annotations: ^{0,3}A_{GlcNAc} |
|
| 257.13 | 1.9 |
| 270.1 | 1.6 |
| 270.6 | 0.6 |
| 274.79 | 0.7 |
| 276.09 | 0.9 |
|
Annotations: ^{1,4}A_{Man}Z |
|
| 285.27 | 0.9 |
|
Annotations: Z |
|
| 288.49 | 0.6 |
| 289.22 | 1.6 |
| 301.25 | 0.5 |
|
Annotations: ^{3,5}A_{Man} |
|
| 303.98 | 0.6 |
| 305.83 | 2.2 |
| 307.17 | 0.5 |
|
Annotations: BZ |
|
| 312.8 | 0.9 |
| 314.71 | 6.6 |
| 325.28 | 2.5 |
|
Annotations: BY |
|
| 325.93 | 1.1 |
| 326.86 | 1.3 |
| 330.19 | 4.5 |
| 331.23 | 0.3 |
|
Annotations: ^{1,5}A_{Man} |
|
| 341.43 | 0.8 |
| 342.98 | 2.3 |
|
Annotations: CY |
|
| 345.43 | 0.3 |
|
Annotations: B |
|
| 346.13 | 0.4 |
| 347.38 | 2.3 |
| 348.27 | 26.9 |
|
Annotations: BZ |
|
| 349.1 | 0.9 |
| 354.23 | 1.2 |
|
Annotations: C |
|
| 357.24 | 1.0 |
|
Annotations: BZ |
|
| 357.86 | 0.9 |
| 364.36 | 8.4 |
| 365.09 | 35.2 |
| 366.2 | 13896.8 |
|
Annotations: B |
|
| 367.23 | 1182.3 |
| 368.1 | 13.6 |
| 369.19 | 0.9 |
| 371.59 | 0.9 |
| 375.34 | 3.4 |
|
Annotations: Y |
|
| 379.77 | 0.7 |
| 382.33 | 1.4 |
| 384.33 | 29.5 |
|
Annotations: C |
|
| 385.25 | 0.6 |
| 386.7 | 12.6 |
| 389.37 | 1.5 |
| 394.82 | 1.4 |
| 395.78 | 17.4 |
| 401.28 | 0.9 |
| 404.78 | 0.9 |
| 405.28 | 1.2 |
| 407.27 | 80.7 |
|
Annotations: Z |
|
| 408.2 | 9.0 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 409.12 | 2.2 |
| 411.87 | 1.0 |
| 420.22 | 0.9 |
| 424.44 | 1.3 |
| 425.29 | 287.4 |
|
Annotations: Y |
|
| 426.26 | 24.7 |
|
Annotations: ^{1,3}A_{Man} |
|
| 430.36 | 2.4 |
| 431.72 | 0.7 |
| 432.56 | 0.6 |
| 433.34 | 1.8 |
| 438.28 | 4.8 |
|
Annotations: ^{0,3}A_{Man}Z |
|
| 439.73 | 2.1 |
|
Annotations: ^{3,5}A_{Man}Y |
|
| 444.53 | 1.2 |
| 446.19 | 13.5 |
| 447.32 | 4314.6 |
|
Annotations: B |
|
| 447.92 | 208.9 |
| 448.87 | 8.5 |
| 449.95 | 9.4 |
| 450.96 | 2.0 |
| 452.08 | 3.9 |
|
Annotations: ^{2,5}A_{Man}Z |
|
| 453.03 | 0.8 |
| 456.26 | 23.5 |
|
Annotations: C |
|
| 458.95 | 9.8 |
| 459.71 | 2.0 |
| 466.78 | 7.1 |
| 467.87 | 593.0 |
|
Annotations: Z |
|
| 468.6 | 27.2 |
|
Annotations: ^{0,2}A_{Man}Z |
|
| 469.12 | 0.9 |
| 469.79 | 1.3 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 475.13 | 0.7 |
| 475.91 | 1.8 |
| 476.9 | 285.8 |
|
Annotations: Y |
|
| 477.54 | 3.4 |
| 478.2 | 4.3 |
| 479.0 | 0.4 |
| 479.51 | 0.7 |
| 481.4 | 0.3 |
| 482.12 | 0.8 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 484.68 | 0.9 |
| 486.34 | 2.9 |
|
Annotations: ^{0,2}A_{Man}Y |
|
| 487.09 | 0.8 |
| 488.04 | 0.9 |
| 490.2 | 0.9 |
| 492.29 | 7.8 |
| 493.31 | 1.4 |
| 510.32 | 20.1 |
|
Annotations: BZ |
|
| 511.15 | 0.3 |
| 514.31 | 0.5 |
| 526.15 | 5.5 |
| 526.82 | 38.9 |
| 527.59 | 8.5 |
| 528.26 | 6399.4 |
|
Annotations: B |
|
| 529.3 | 912.2 |
| 530.26 | 19.5 |
| 530.9 | 3.2 |
| 531.51 | 1.0 |
| 533.34 | 0.5 |
| 538.81 | 1.3 |
| 540.01 | 13.5 |
| 545.19 | 3.1 |
| 545.75 | 0.3 |
|
Annotations: C |
|
| 546.35 | 94.8 |
|
Annotations: C |
|
| 547.31 | 8.6 |
| 547.99 | 21.8 |
| 548.87 | 742.1 |
| 549.54 | 17.9 |
| 550.19 | 7.2 |
| 553.38 | 1.6 |
| 554.78 | 1.0 |
| 558.81 | 1.1 |
| 567.74 | 3.0 |
| 568.29 | 1.3 |
| 569.33 | 721.0 |
|
Annotations: Z |
|
| 570.37 | 133.3 |
| 571.13 | 1.1 |
| 576.76 | 0.4 |
| 577.64 | 0.6 |
| 584.98 | 2.9 |
| 585.66 | 12.7 |
| 586.39 | 24.9 |
| 587.32 | 2165.5 |
|
Annotations: Y |
|
| 588.37 | 353.7 |
|
Annotations: ^{0,4}A_{Man} |
|
| 589.25 | 9.7 |
| 603.69 | 1.5 |
| 609.37 | 1.7 |
| 611.48 | 0.6 |
| 612.53 | 0.4 |
| 628.48 | 6.4 |
| 629.46 | 1.0 |
| 630.48 | 1.9 |
| 636.37 | 4.4 |
| 648.48 | 0.7 |
|
Annotations: ^{0,2}A_{Man} |
|
| 652.47 | 1.1 |
| 654.39 | 3.3 |
| 672.33 | 3.1 |
| 687.12 | 0.9 |
| 688.38 | 2.1 |
| 689.16 | 2.7 |
| 690.38 | 286.9 |
|
Annotations: B |
|
| 691.38 | 43.9 |
| 695.54 | 6.9 |
| 696.47 | 0.6 |
| 706.28 | 0.9 |
| 707.66 | 5.4 |
| 708.44 | 36.8 |
|
Annotations: C |
|
| 709.45 | 5.8 |
| 710.23 | 1.9 |
| 712.58 | 2.3 |
| 713.39 | 16.9 |
|
Annotations: BZ |
|
| 714.4 | 8.8 |
| 729.75 | 19.2 |
| 730.49 | 36.0 |
| 731.36 | 4885.9 |
|
Annotations: Z |
|
| 732.39 | 1037.9 |
| 733.22 | 26.7 |
| 736.13 | 2.0 |
| 745.93 | 0.5 |
| 746.91 | 12.5 |
| 747.81 | 123.7 |
| 748.64 | 134.2 |
| 749.37 | 8089.4 |
|
Annotations: Y |
|
| 750.4 | 1528.5 |
| 751.21 | 40.2 |
| 752.01 | 5.8 |
| 753.21 | 2.2 |
| 754.19 | 1.3 |
| 767.45 | 0.6 |
| 781.46 | 1.1 |
| 789.76 | 1.4 |
| 790.49 | 1.2 |
| 809.58 | 0.7 |
| 810.39 | 0.7 |
| 821.51 | 2.3 |
| 857.12 | 0.8 |
| 875.47 | 16.5 |
| 876.47 | 0.9 |
| 888.24 | 2.3 |
| 890.7 | 2.4 |
| 891.69 | 4.8 |
| 892.44 | 21.7 |
| 893.46 | 981.2 |
|
Annotations: B |
|
| 894.47 | 248.3 |
| 895.42 | 7.6 |
| 909.33 | 0.6 |
| 909.9 | 3.1 |
| 910.68 | 4.2 |
| 911.5 | 130.4 |
|
Annotations: C |
|
| 912.47 | 18.2 |
| 934.57 | 26.3 |
|
Annotations: Z |
|
| 935.42 | 8.9 |
| 950.93 | 0.5 |
| 952.55 | 13.9 |
|
Annotations: Y |
|
| 953.3 | 2.2 |