Negative ion CID fragmentation of O-linked oligosaccharides aldoses-charge induced and charge remote fragmentation

PubMed Entry

GlyToucan Accession Number: G91731DX

Peak Intensity
246.8 25.0

Annotations:

^{2,5}A_{GlcNAc}Z
286.9 19.0
287.8 41.0
294.8 140.0
306.9 56.0

Annotations:

B B
315.0 31.0
322.5 38.0
324.9 115.0

Annotations:

C C
346.0 21.0

Annotations:

BZ
346.9 44.0
365.3 89.0
367.0 160.0

Annotations:

^{2,4}A_{GlcNAc}
371.0 68.0
378.3 19.0
381.0 31.0

Annotations:

^{3,5}A_{GlcNAc}
382.1 54.0

Annotations:

CY
388.4 106.0
389.1 964.0

Annotations:

ZZ
390.1 283.0
390.8 39.0
392.2 35.0
406.5 85.0
407.1 231.0

Annotations:

YZ ZY
408.2 166.0
409.1 464.0
410.0 34.0
422.0 53.0
450.3 37.0
451.1 40.0
452.0 24.0
457.1 31.0
468.1 42.0
470.2 65.0
491.2 51.0
506.2 88.0
508.1 108.0
510.2 486.0

Annotations:

B
511.2 192.0
512.2 234.0

Annotations:

Z
513.5 29.0
525.6 46.0
527.4 43.0
528.4 24.0

Annotations:

C
530.2 57.0

Annotations:

Y
533.2 21.0
538.5 44.0
549.8 44.0
551.2 353.0

Annotations:

ZZ ZZ
552.2 254.0
553.1 17.0
554.2 45.0
569.3 188.0

Annotations:

YZ ZY YZ ZY
570.2 590.0
571.1 225.0
579.2 18.0
584.4 44.0
594.1 26.0
602.1 24.0
604.3 25.0
613.0 39.0
614.1 46.0
622.0 34.0
629.2 26.0
633.2 84.0
637.3 46.0
639.6 153.0
647.3 19.0
648.7 35.0
653.1 21.0
654.5 47.0
655.3 285.0
656.1 149.0
666.2 74.0
667.3 63.0
671.9 20.0
673.3 1759.0
674.3 753.0
675.2 29.0
679.3 25.0
680.3 17.0
681.5 71.0
685.4 41.0
687.4 71.0
690.7 61.0
691.3 18.0
692.4 22.0
693.3 94.0
694.6 17.0
697.1 185.0
698.2 48.0
711.0 19.0
711.7 39.0
712.5 70.0
713.3 268.0

Annotations:

ZZ
715.3 8866.0

Annotations:

Z Z
716.3 2784.0
717.3 665.0
733.4 457.0

Annotations:

Y Y
734.3 139.0
735.5 53.0
744.2 107.0
757.3 41.0
764.3 14.0
769.3 66.0
776.3 29.0
787.3 36.0
798.3 16.0
799.5 31.0
817.3 62.0
824.6 95.0
825.7 28.0
828.3 134.0
829.7 14.0
834.1 57.0
835.6 45.0
836.2 20.0
837.6 100.0
838.5 19.0
841.4 84.0
853.5 49.0
854.5 28.0
854.9 26.0
857.9 43.0
861.6 34.0
863.3 22.0
868.2 61.0
877.3 202.0

Annotations:

Z Z
878.4 199.0
879.5 54.0
880.3 21.0
883.5 24.0
888.7 44.0
895.5 512.0

Annotations:

Y Y
896.5 76.0
897.7 39.0
898.5 19.0
902.5 35.0
911.6 22.0
917.7 39.0
925.3 29.0
926.8 35.0
928.5 54.0
935.9 68.0
937.3 40.0
938.6 80.0
939.2 47.0
940.9 75.0
951.7 18.0
953.7 18.0
959.1 19.0
964.5 27.0
968.6 31.0
969.3 51.0
974.8 71.0
976.6 25.0
978.2 81.0
980.3 60.0
981.5 947.0
982.4 280.0
983.6 115.0
987.6 44.0
993.7 55.0
995.5 87.0
996.7 107.0
997.5 70.0
999.6 988.0
1000.5 551.0
1001.5 330.0
1003.4 94.0
1004.2 105.0
1006.3 123.0
1007.9 133.0
1009.4 78.0
1010.2 26.0
1012.2 30.0
1012.9 108.0
1014.3 22.0
1015.6 34.0
1017.5 34.0
1018.1 37.0
1018.4 33.0
1019.6 70.0
1021.5 139.0
1022.5 41.0
1023.8 177.0
1026.2 36.0
1027.0 91.0
1032.4 35.0
1037.3 38.0
1151.5 181.0

There are 12 similar spectra:

Id Structure Score

3676

0.97

204

0.97

221

0.97

2965

0.96

3093

0.96

507

0.96

2795

0.95

334

0.87

2794

0.87

335

0.86

52

0.70

3092

0.64
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