Structural determination of neutral O-linked oligosaccharide alditols by negative ion LC-electrospray-MSn.
GlyToucan Accession Number: G04459VF
Peak | Intensity |
---|---|
340.1 | 322.6 |
340.8 | 1331.6 |
370.7 | 1577.6 |
383.7 | 2781.8 |
Annotations: YY |
|
388.9 | 11238.4 |
389.5 | 813.0 |
455.1 | 986.0 |
456.2 | 408.4 |
Annotations: ^{0,3}X_{Fuc}Y ^{3,5}X_{Gal}Y ^{3,5}X_{GalNAc} |
|
460.2 | 705.2 |
463.9 | 554.8 |
Annotations: ^{1,5}A_{GalNAc}Z |
|
471.1 | 711.2 |
473.8 | 162.8 |
474.8 | 903.4 |
482.4 | 412.0 |
Annotations: ^{1,5}A_{GalNAc}Y |
|
490.8 | 2707.8 |
492.0 | 855.4 |
Annotations: BZ BZ |
|
494.2 | 320.8 |
509.2 | 5229.4 |
512.1 | 13498.4 |
Annotations: Z |
|
513.3 | 7355.4 |
530.0 | 37023.6 |
Annotations: Y |
|
531.2 | 3675.2 |
542.1 | 101.6 |
551.1 | 267.8 |
553.0 | 7588.4 |
Annotations: YZ ZY |
|
570.0 | 374.8 |
Annotations: ^{0,4}A_{GalNAc}Y ^{0,4}A_{GalNAc}Y C^{0,2}X_{Fuc} C^{2,5}X_{Gal} C^{0,2}X_{Fuc} |
|
571.0 | 223.4 |
Annotations: YY |
|
583.4 | 1099.0 |
591.1 | 503.6 |
595.5 | 1444.4 |
606.8 | 439.4 |
614.0 | 970.6 |
Annotations: C^{1,3}X_{Fuc} C^{2,4}X_{Fuc} C^{0,4}X_{Gal} C^{2,4}X_{Gal} C^{1,3}X_{Fuc} C^{2,4}X_{Fuc} ^{1,3}X_{GalNAc}Z ^{1,3}X_{GalNAc}Z |
|
619.7 | 927.6 |
621.0 | 6382.6 |
625.1 | 3582.2 |
Annotations: ^{1,4}X_{Gal}Z Z^{1,4}X_{Gal} |
|
626.2 | 88.8 |
637.2 | 8886.4 |
637.8 | 231.0 |
638.9 | 524.6 |
654.2 | 2405.8 |
655.2 | 28982.0 |
Annotations: ^{1,3}X_{Gal}Z Z^{1,3}X_{Gal} ^{2,4}X_{GalNAc}Z ^{2,4}X_{GalNAc}Z |
|
656.2 | 16451.0 |
Annotations: B |
|
657.3 | 1071.4 |
663.6 | 228.0 |
666.9 | 3474.2 |
668.1 | 2028.0 |
670.1 | 1195.4 |
673.1 | 1831.4 |
Annotations: ^{1,3}X_{Gal}Y Y^{1,3}X_{Gal} ^{2,4}X_{GalNAc}Y ^{2,4}X_{GalNAc}Y |
|
678.6 | 1135.0 |
679.3 | 6605.8 |
697.2 | 19140.0 |
Annotations: ZZ ZZ ZZ ZZ |
|
698.1 | 5635.4 |
709.0 | 2982.4 |
715.0 | 2546.0 |
Annotations: YZ ZY YZ YZ YZ ZY ZY ZY |
|
716.0 | 7844.8 |
Annotations: ^{0,4}A_{GalNAc} |
|
734.1 | 278.2 |
801.0 | 8025.6 |
Annotations: ^{1,3}X_{Fuc}Z ^{2,4}X_{Fuc}Z ^{0,4}X_{Gal}Z ^{2,4}X_{Gal}Z Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} Z^{0,4}X_{Gal} Z^{2,4}X_{Gal} Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} ^{2,4}X_{Fuc}Z ^{1,3}X_{Fuc}Z |
|
801.7 | 0.2 |
Annotations: ^{1,3}X_{Fuc}Z ^{2,4}X_{Fuc}Z ^{1,3}X_{Fuc}Z ^{2,4}X_{Fuc}Z ^{0,4}X_{Gal}Z ^{2,4}X_{Gal}Z Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} Z^{0,4}X_{Gal} Z^{2,4}X_{Gal} Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} |
|
814.1 | 243.6 |
818.8 | 1401.6 |
819.4 | 16832.2 |
Annotations: ^{2,4}X_{GalNAc} ^{1,3}X_{Fuc}Y ^{2,4}X_{Fuc}Y ^{1,3}X_{Fuc}Y ^{2,4}X_{Fuc}Y ^{0,4}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Fuc} Y^{2,4}X_{Fuc} Y^{0,4}X_{Gal} Y^{2,4}X_{Gal} Y^{1,3}X_{Fuc} Y^{2,4}X_{Fuc} |
|
820.5 | 2235.2 |
836.0 | 209.0 |
839.9 | 625.8 |
844.2 | 965.0 |
852.6 | 586.8 |
861.1 | 51290.8 |
Annotations: Z Z |
|
862.0 | 24135.0 |
862.8 | 0.2 |
873.2 | 449.4 |
875.2 | 1616.4 |
877.0 | 396.2 |
Annotations: YZ ZY ZY YZ YZ ZY |
|
879.3 | 9368.8 |
Annotations: Y Y |
|
880.3 | 5082.8 |
892.3 | 107.2 |
895.0 | 1847.4 |
Annotations: YY YY YY |
|
898.6 | 185.2 |
903.3 | 1199.4 |
Annotations: ^{0,2}X_{Gal}Z Z^{0,2}X_{Gal} Z^{0,2}X_{Gal} ^{0,2}X_{Gal}Z ^{0,2}X_{Gal}Z ^{0,2}X_{Gal}Z |
|
904.4 | 148.2 |
Annotations: ^{2,5}A_{GalNAc}Z ^{2,5}A_{GalNAc}Z ^{2,5}A_{GalNAc}Z |
|
910.0 | 1364.4 |
912.3 | 3772.8 |
920.1 | 480.6 |
Annotations: ^{0,2}A_{GalNAc}Z ^{0,2}A_{GalNAc}Z ^{0,2}A_{GalNAc}Z |
|
921.3 | 2505.4 |
Annotations: Y^{0,2}X_{Gal} ^{0,2}X_{Gal}Y ^{0,2}X_{Gal}Y Y^{0,2}X_{Gal} ^{0,2}X_{Gal}Y ^{0,2}X_{Gal}Y |
|
929.2 | 1211.8 |
929.8 | 356.0 |
930.8 | 89.8 |
947.0 | 382.6 |
963.2 | 2024.2 |
Annotations: ^{0,4}X_{Gal}Z ^{2,4}X_{Gal}Z ^{0,4}X_{Gal}Z ^{2,4}X_{Gal}Z ^{1,3}X_{Fuc}Z ^{2,4}X_{Fuc}Z Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} Z^{0,4}X_{Gal} Z^{2,4}X_{Gal} ^{1,3}X_{Fuc}Z ^{1,3}X_{Fuc}Z ^{2,4}X_{Fuc}Z ^{2,4}X_{Fuc}Z Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} Z^{0,4}X_{Gal} Z^{2,4}X_{Gal} Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} ^{0,4}X_{Gal}Z ^{0,4}X_{Gal}Z ^{2,4}X_{Gal}Z ^{2,4}X_{Gal}Z |
|
967.6 | 2503.6 |
Annotations: ^{3,5}X_{Gal}Y ^{0,3}X_{Fuc}Y Y^{0,3}X_{Fuc} Y^{3,5}X_{Gal} ^{0,3}X_{Fuc}Y ^{0,3}X_{Fuc}Y Y^{0,3}X_{Fuc} Y^{3,5}X_{Gal} Y^{0,3}X_{Fuc} ^{3,5}X_{Gal}Y ^{3,5}X_{Gal}Y ^{3,5}X_{Gal}Y |
|
977.4 | 167.0 |
981.8 | 171.8 |
Annotations: Y^{1,3}X_{Fuc} ^{0,4}X_{Gal}Y ^{1,3}X_{Gal} ^{2,4}X_{Gal}Y ^{0,4}X_{Gal}Y ^{1,3}X_{Gal} ^{2,4}X_{Gal}Y ^{1,3}X_{Fuc}Y ^{2,4}X_{Fuc}Y Y^{1,3}X_{Fuc} Y^{2,4}X_{Fuc} Y^{0,4}X_{Gal} Y^{2,4}X_{Gal} ^{1,3}X_{Fuc}Y ^{1,3}X_{Fuc}Y ^{2,4}X_{Fuc}Y ^{2,4}X_{Fuc}Y Y^{2,4}X_{Fuc} Y^{0,4}X_{Gal} Y^{2,4}X_{Gal} Y^{1,3}X_{Fuc} Y^{2,4}X_{Fuc} ^{0,4}X_{Gal}Y ^{0,4}X_{Gal}Y ^{2,4}X_{Gal}Y ^{2,4}X_{Gal}Y |
|
984.4 | 319.6 |
995.6 | 212.6 |
1000.2 | 250.2 |
1000.9 | 815.8 |
1005.8 | 434.0 |
1023.3 | 18410.2 |
Annotations: Z Z Z |
|
1024.1 | 5645.8 |
1025.2 | 3864.6 |
1028.4 | 739.4 |
1029.5 | 165.6 |
1031.2 | 330.2 |
1041.1 | 14757.2 |
Annotations: Y Y Y |
|
1042.3 | 9192.4 |
1042.9 | 357.0 |
1048.0 | 763.0 |
1051.7 | 1211.8 |
1057.7 | 223.2 |
1062.0 | 297.0 |
1063.5 | 1001.2 |
1065.2 | 2944.2 |
1066.3 | 2600.2 |
1095.1 | 117.8 |
1103.0 | 191.6 |
1108.4 | 595.4 |
1110.4 | 170.4 |
1111.4 | 126.2 |
1113.3 | 93.4 |
Annotations: ^{0,3}X_{Fuc} ^{3,5}X_{Gal} ^{0,3}X_{Fuc} ^{3,5}X_{Gal} ^{0,3}X_{Fuc} |
|
1115.3 | 1198.4 |
1125.3 | 999.2 |
1127.2 | 11314.4 |
Annotations: ^{1,3}X_{Fuc} ^{2,4}X_{Fuc} ^{0,4}X_{Gal} ^{2,4}X_{Gal} ^{1,3}X_{Fuc} ^{2,4}X_{Fuc} ^{0,4}X_{Gal} ^{2,4}X_{Gal} ^{1,3}X_{Fuc} ^{2,4}X_{Fuc} |
|
1128.2 | 9669.6 |
1135.3 | 616.6 |
1143.6 | 792.0 |
Annotations: ^{0,4}X_{Fuc} ^{0,4}X_{Fuc} ^{0,4}X_{Fuc} |
|
1144.5 | 313.8 |
1145.3 | 7370.8 |
1146.3 | 6820.2 |
1151.0 | 180.8 |
1156.0 | 240.8 |
1165.8 | 276.0 |
1169.3 | 453.2 |
1170.4 | 2278.4 |
1171.2 | 664.4 |
1209.4 | 524.4 |
1221.9 | 128.0 |
1223.0 | 1327.8 |
1224.2 | 266.8 |
1261.3 | 593.0 |