Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library

PubMed Entry

Peak Intensity
272.01 26.6
272.69 26.6

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^{3,5}A_{GlcNAc}
289.22 15.7

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^{0,3}A_{Man}
290.12 3525.0
291.16 130.6

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B^{0,2}X_{NeuGc}
294.07 1.8

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YY
306.25 12.9

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Z^{0,2}X_{Man} B^{2,4}X_{GlcNAc} B^{0,3}X_{NeuGc}
307.43 41.7

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BZ BZ
308.11 3654.8

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B
309.1 334.1

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C^{2,5}X_{NeuGc}
310.1 11.0
310.88 8.8
312.5 12.5
314.22 106.4

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Z^{2,5}X_{Man} B^{3,5}X_{NeuGc} ^{1,5}A_{Man}Z
315.69 13.6

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BZ
317.91 6.0
324.73 60.9

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BY BY CZ CZ BY CZ
325.25 135.1

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CZ BY CZ BY BY CZ
326.03 148.7

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C
327.15 65.2
330.16 162.5

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^{1,4}X_{Man}Y
331.37 11.0
340.04 12.5
342.41 24.3
343.4 34.1

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CY CY
348.14 138.7

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C^{1,5}X_{Man}
349.45 13.7
350.24 612.8

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BY CZ
351.28 21.0

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B^{1,5}X_{Fuc} ^{2,4}A_{GlcNAc}Z B^{2,4}X_{NeuGc}
364.22 67.1
365.06 159.0

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B^{1,4}X_{Fuc}
366.12 25954.1

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YZ ZY
367.13 2004.8

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^{0,4}A_{Man}Z ^{0,4}A_{Man}Z B^{0,2}X_{Man} B^{0,2}X_{Man} ^{1,3}A_{Man}Y C^{0,2}X_{Fuc}
368.12 87.7

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CY
375.04 85.3

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YY
382.01 33.8

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C^{0,2}X_{NeuGc} ^{1,4}A_{Man}Y C^{0,3}X_{Fuc}
384.13 52.8
388.19 6.4

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B^{1,3}X_{NeuGc} B^{0,4}X_{Fuc}
389.36 1.7

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^{1,5}X_{GlcNAc}Y C^{1,3}X_{Fuc} C^{2,4}X_{Fuc} Y^{1,5}X_{Man} C^{2,5}X_{NeuGc}
397.19 5.8

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BZ
400.28 23.0
404.37 36.4

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^{1,5}A_{Man}Y Y^{2,5}X_{Man} C^{3,5}X_{NeuGc}
405.49 13.1
407.17 286.6

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Z
408.27 46.5

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B^{2,5}X_{Gal}
408.82 21.4

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BZ
416.29 7.2

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^{0,2}X_{GlcNAc}Y
417.17 10.8

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BZ
418.22 81.2

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BY CZ
423.12 10.3
425.22 1027.5

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Y
426.19 4.1

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BY CZ
426.69 12.3

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BY CZ CY
433.0 22.5

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B^{2,4}X_{NeuGc}
434.14 138.7
435.31 25.0

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CY
436.14 106.1

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CY
437.19 13.8

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^{2,4}X_{GlcNAc}Z
438.02 1.6

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ZZ ZZ
446.27 15.2

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B^{1,4}X_{Fuc} ^{2,4}X_{GlcNAc}Y
447.3 655.8

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YZ YZ ZY ZY
448.3 5.1

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^{1,3}A_{Man}Y ^{2,4}A_{Man}Y C^{0,2}X_{Fuc}
450.33 4.5
452.2 79.7

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B^{1,3}X_{Gal} B^{2,4}X_{Gal}
453.16 41.3

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^{1,5}X_{Man}
454.18 463.4

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^{1,4}A_{Man}Z B^{0,3}X_{Fuc}
454.96 37.6

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^{1,4}A_{Man} C^{1,4}X_{Fuc}
457.21 3.6
460.46 8.7
467.55 30.9

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^{0,2}X_{Man}
468.87 164.0

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B^{1,3}X_{NeuGc} B^{0,4}X_{Fuc}
470.12 3264.0

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B
471.16 298.1

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C^{3,5}X_{Fuc}
472.11 20.6

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C^{1,4}X_{Man}
475.18 30.9
476.73 474.0

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^{1,5}A_{Man} Y^{0,2}X_{Man} Y^{0,2}X_{Man}
477.28 41.5

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^{1,5}A_{Man} Y^{0,2}X_{Man} Y^{0,2}X_{Man} B^{1,3}X_{Man} B^{2,4}X_{GlcNAc}
485.51 8.5

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Y^{2,5}X_{Man} Y^{2,5}X_{Man}
486.66 81.0

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C^{1,3}X_{Man} C^{2,4}X_{GlcNAc}
487.28 189.4

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B
488.11 63.0

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C
489.27 62.8
492.12 42.3

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^{1,4}X_{Man}Y ^{1,4}X_{Man}Y Y^{0,3}X_{Man} Y^{1,4}X_{Man} Y^{0,3}X_{Man} Y^{1,4}X_{Man}
494.34 107.4

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BZ BZ
504.99 74.5

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C
506.2 20.6
506.81 25.6

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^{1,3}X_{Man}Y ^{1,3}X_{Man}Y Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man}
509.23 0.8
510.32 59.0
511.33 397.7
512.24 9676.0

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BY CZ BY CZ
513.22 988.6
514.08 6.8
520.14 173.9
520.74 11.0

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^{1,3}A_{Man} ^{2,4}A_{Man}
525.59 39.1
526.35 103.1
527.29 295.8
528.16 12311.3

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Z
529.22 1178.5
533.1 5.9
537.32 74.2

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Y
538.63 16.9
541.17 31.5

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ZY YZ
542.19 3.8

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^{1,5}X_{GlcNAc}Z ^{1,5}X_{GlcNAc}Z Z^{1,5}X_{Man} Z^{1,5}X_{Man}
546.3 161.9
547.25 23.8

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^{0,4}A_{Man}
548.95 278.9

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B^{0,2}X_{GlcNAc} Z^{0,2}X_{Man} Z^{0,2}X_{Man}
549.49 80.8

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YY
557.75 1696.5

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Y^{0,2}X_{Man} ^{1,5}A_{Man}Z C^{0,2}X_{GlcNAc} C^{1,5}X_{Gal} Y^{0,2}X_{Man}
558.39 83.7

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C^{0,2}X_{GlcNAc} C^{1,5}X_{Gal} Y^{0,2}X_{Man} Y^{0,2}X_{Man}
560.43 7.0

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^{0,3}A_{GlcNAc}
562.25 20.5
569.26 899.2

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YZ ZY
570.26 68.3

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B^{2,5}X_{Gal} ^{0,2}X_{Gal}Y Y^{0,2}X_{Man}
570.77 6.9

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^{0,2}X_{Gal}Y Y^{0,2}X_{Man}
571.31 95.0

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BZ
584.89 34.1
585.97 30.5

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^{1,4}X_{Gal}Y B^{1,5}X_{Man}
586.54 5.6

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B^{1,5}X_{Man} ^{2,5}X_{GlcNAc}Y ^{2,5}X_{GlcNAc}Y
587.25 2305.8

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YY
588.19 228.1

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C^{2,4}X_{GlcNAc} C^{2,5}X_{Gal} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} ^{1,3}X_{Man}
591.29 15.3

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^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z
598.22 53.4

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B^{2,5}X_{NeuGc}
601.11 493.7

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^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y B^{2,5}X_{Man}
601.75 32.0

Annotations:

C^{0,2}X_{Man} C^{1,4}X_{Gal} ^{1,4}A_{Man}Y ^{1,4}A_{Man}Y B^{0,2}X_{Gal} C^{1,5}X_{NeuGc}
607.12 18.9
608.35 27.8

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^{2,4}X_{GlcNAc}Y ^{2,4}X_{GlcNAc}Y
609.3 598.9

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Z
610.85 44.3

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C^{0,2}X_{Gal} Z^{0,2}X_{Man}
612.81 8.5

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ZZ
614.38 32.1

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B^{1,3}X_{Gal} B^{2,4}X_{Gal}
615.43 124.7

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^{1,5}X_{Man}Y Y^{1,5}X_{Man}
616.23 416.0

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C^{2,5}X_{NeuGc} B^{1,4}X_{Gal}
617.32 76.8
618.26 44.0

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Y
619.17 5.5

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C^{2,5}X_{Gal}
621.28 7.9

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ZY YZ
628.36 27.3

Annotations:

B^{3,5}X_{NeuGc} ^{1,5}A_{Man}Z
629.93 582.7

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C^{0,3}X_{NeuGc}
630.71 394.9

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YY BZ
631.22 142.9

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YY BZ
632.25 59.6

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^{1,5}X_{GlcNAc} C^{1,3}X_{Gal} C^{2,4}X_{Gal} ^{2,5}A_{Man}Y
633.26 90.6
634.23 33.5
636.28 12.7
637.38 62.3
638.81 2599.8

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^{1,5}A_{Man}Z
639.6 81.8
649.27 81.3

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BY CZ
650.32 29.9

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Z^{2,5}X_{Man}
651.34 10.9

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Y^{0,2}X_{Man}
652.29 21.5

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BZ
653.76 20.0

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^{1,4}X_{GlcNAc}
654.35 12.8

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^{1,4}X_{GlcNAc}
655.25 981.8

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BZ
656.27 122.9

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BZ
657.38 11.8

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^{1,5}X_{NeuGc}Z
667.05 191.9

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CY
667.74 13.3

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^{2,5}X_{GlcNAc}
671.0 8.0

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CY
671.57 127.7

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^{1,3}X_{Man}Z ^{0,3}X_{NeuGc}Z
672.44 354.5
673.22 44295.4

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BY CZ BZ
674.27 8203.7

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CZ BY
675.15 412.6
675.76 15.7

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^{2,4}A_{GlcNAc}
682.21 562.3

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BY CZ
682.76 20.7

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CY
683.37 4.5
687.3 89.7

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B^{1,5}X_{Man}
688.4 103.1

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B^{1,4}X_{NeuGc} ^{3,5}X_{NeuGc}Y
689.29 18.8

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^{1,3}X_{Man}Y ^{2,4}X_{GlcNAc}
690.24 15464.4

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^{2,4}X_{GlcNAc}
691.24 2425.2

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CY CY
692.26 102.5

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CY
693.23 28.4

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ZZ
696.19 6.6

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B^{1,5}X_{Gal} ^{2,5}A_{Man}Z ^{2,5}A_{Man}Z
697.38 6.2

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B^{1,5}X_{NeuGc}
699.37 76.6

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B^{0,4}X_{NeuGc}
702.13 196.6

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ZZ YZ ZY
702.99 238.8

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ZY YZ YZ ZY
706.24 12.9

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C^{0,2}X_{NeuGc} C^{1,4}X_{NeuGc} C^{1,5}X_{NeuGc}
706.95 20.8

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C^{1,5}X_{NeuGc}
708.32 283.6
709.08 62.0
709.82 16.4

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^{1,4}X_{NeuGc}Z
710.91 544.4

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ZY YZ YY
711.83 899.7

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YY YY
712.35 125.3

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^{0,2}A_{Man}Z C^{0,2}X_{Gal}
712.89 8.5

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ZZ
714.52 45.9
715.45 50.4

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^{1,3}A_{Man}Z B^{0,2}X_{Fuc} ^{0,4}X_{NeuGc}Z
719.0 77.2

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^{1,4}X_{NeuGc}Y C^{1,5}X_{Fuc} ^{1,5}A_{Man}Z
719.93 1790.4

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YY
720.68 6.3

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^{2,5}A_{GlcNAc} ^{1,5}A_{Man}Y ^{1,5}A_{Man}Y C^{2,5}X_{Gal} C^{2,4}X_{NeuGc} C^{0,3}X_{NeuGc}
724.39 73.3

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^{0,4}X_{NeuGc}Y Z^{1,5}X_{Fuc} ^{1,5}X_{Gal}Z
725.67 3.4

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BZ BZ
730.6 32.2

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^{1,4}X_{Fuc}Z
731.29 2899.7

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YZ ZY
732.44 422.7

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^{0,2}X_{Fuc}Y Y^{0,2}X_{Man} ^{0,2}X_{Gal}Y ^{0,2}X_{Gal}Y Y^{0,2}X_{Man} Y^{0,2}X_{Man}
733.3 149.5

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BZ
733.92 64.6

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BY BY CZ CZ
734.43 44.3

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BY BY CZ CZ
747.83 164.5

Annotations:

Y^{1,4}X_{Fuc} ^{1,4}X_{Gal}Y ^{1,4}X_{Gal}Y Y^{0,3}X_{Man} Y^{1,4}X_{Man} Y^{0,3}X_{Man} Y^{1,4}X_{Man} B^{1,5}X_{Man} B^{1,5}X_{Man}
749.29 10065.1

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YY
750.31 1508.1
751.21 28.6

Annotations:

CY
754.8 210.2

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Z^{3,5}X_{Fuc} B^{0,2}X_{Man} B^{0,2}X_{Man} B^{0,4}X_{NeuGc} ^{3,5}X_{Fuc}Y
755.87 30.9

Annotations:

Y^{0,3}X_{Fuc} ^{1,4}X_{Gal}Y Y^{3,5}X_{Man} Y^{3,5}X_{Man} B^{1,5}X_{Fuc}
757.74 17.5

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C^{1,5}X_{Man} C^{1,5}X_{Man}
762.77 348.3

Annotations:

^{0,4}X_{Fuc}Y ^{1,3}X_{NeuGc}Y ^{1,3}X_{Gal}Y ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Fuc} Y^{2,4}X_{Fuc} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} B^{0,2}X_{Fuc} B^{2,5}X_{Man} B^{2,5}X_{Man} ^{1,4}A_{Man}Y C^{0,3}X_{Fuc}
763.48 409.9

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BY CZ
771.8 20.8

Annotations:

CY
774.72 124.7

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ZZ ZZ
775.57 114.4

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Z
776.76 5.3
778.18 39.2

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B^{0,3}X_{Fuc} B^{3,5}X_{Man} B^{3,5}X_{Man} C^{2,5}X_{NeuGc}
783.34 6.0

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Z
784.14 689.7

Annotations:

Z Y
784.77 47.9

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Y
785.65 7.6

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B^{1,3}X_{Fuc} B^{2,4}X_{Fuc} B^{0,4}X_{Man} B^{1,3}X_{Man} B^{2,4}X_{Man} B^{0,4}X_{Man} B^{1,3}X_{Man} B^{2,4}X_{Man}
787.22 2.4

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C^{0,3}X_{Fuc} C^{3,5}X_{Man} C^{3,5}X_{Man}
790.32 17.8

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B^{3,5}X_{NeuGc}
791.07 41.9

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Y^{0,2}X_{Man} ^{1,5}A_{GlcNAc}
791.81 98.5

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ZY YZ
792.89 2817.2

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Y
793.7 112.3

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BZ
794.38 31.3

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^{0,2}A_{Man} C^{1,3}X_{Fuc} C^{2,4}X_{Fuc} C^{0,4}X_{Man} C^{1,3}X_{Man} C^{2,4}X_{Man} C^{0,4}X_{Man} C^{1,3}X_{Man} C^{2,4}X_{Man}
795.2 21.1

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C^{3,5}X_{Fuc}
795.92 21.3
797.38 11.4

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Z^{1,5}X_{Man} Z^{1,5}X_{Man}
798.32 11.2

Annotations:

B^{0,2}X_{NeuGc} ^{1,5}X_{Man}
799.27 3.8

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B^{1,5}X_{NeuGc}
800.43 113.3

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YY
800.97 1391.7

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YY
801.6 354.2

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^{1,5}A_{Man}
802.32 4.7

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C^{0,4}X_{Fuc} C^{1,3}X_{NeuGc}
810.36 37.8
811.32 25.3

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BY CZ
813.34 86.7

Annotations:

B^{0,3}X_{NeuGc} ^{2,5}X_{Man} ^{0,2}X_{Gal} Y^{0,2}X_{Man} Y^{0,2}X_{Man}
814.26 28.8

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^{0,2}X_{Gal} Y^{0,2}X_{Man} Y^{0,2}X_{Man} ^{0,2}X_{GlcNAc}Z
815.32 22.9

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B
816.43 48.2
817.05 7.7

Annotations:

BZ
817.72 620.7

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BZ
818.45 16.7

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^{0,2}X_{NeuGc}Z ^{0,2}X_{NeuGc}Z
819.27 50827.3

Annotations:

B
820.3 7360.9

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Z^{2,5}X_{Fuc}
821.07 200.3

Annotations:

Z^{2,5}X_{Fuc} B^{3,5}X_{NeuGc} ^{1,4}X_{GlcNAc}Y
821.7 14.4

Annotations:

^{1,4}X_{GlcNAc}Y Y^{0,2}X_{Fuc} Y^{2,5}X_{Man} Y^{2,5}X_{Man} ^{2,5}X_{Gal} B^{3,5}X_{NeuGc}
823.3 26.1
829.31 7.6

Annotations:

CY
833.61 20.0

Annotations:

^{0,3}X_{NeuGc}Z ^{0,3}X_{NeuGc}Z
834.4 191.5

Annotations:

BZ BZ
835.3 4385.4

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BY CZ BY BY CZ CZ
836.35 3931.9

Annotations:

^{1,5}X_{NeuGc}Y Y^{0,3}X_{Fuc} Y^{3,5}X_{Man} Y^{3,5}X_{Man}
837.37 512.6

Annotations:

C
838.21 9.2
842.87 21.3

Annotations:

Z^{0,4}X_{Fuc} ^{0,3}X_{NeuGc}Y ^{0,3}X_{NeuGc}Y
844.36 116.0

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CY CY
844.86 5.7

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CY CY
849.75 73.9

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B^{1,5}X_{Man} ^{3,5}X_{NeuGc}Z B^{1,5}X_{Man}
850.92 106.5

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^{3,5}X_{NeuGc}Y ^{3,5}X_{NeuGc}Y B^{1,4}X_{NeuGc} ^{0,3}X_{NeuGc}Y
851.47 250.6

Annotations:

B^{1,4}X_{NeuGc} Y^{0,4}X_{Fuc}
852.29 17900.3

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BY CZ
853.33 3187.6

Annotations:

CY
854.16 199.0
856.37 125.4

Annotations:

YZ ZY
857.19 26.6

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B^{0,2}X_{Man} B^{0,2}X_{Man} B^{0,4}X_{NeuGc} C^{1,5}X_{GlcNAc}
858.77 31.0

Annotations:

B^{2,4}X_{NeuGc} C^{1,5}X_{Man} C^{1,5}X_{Man} ^{3,5}X_{NeuGc}Y
859.3 40.8
864.27 155.5

Annotations:

YZ YZ ZY ZY
865.0 1582.3

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Z
865.74 147.9

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YY
866.56 9.3

Annotations:

C^{1,5}X_{Fuc}
867.19 5.4

Annotations:

C^{1,5}X_{Fuc} C^{2,4}X_{NeuGc}
867.82 19.0

Annotations:

C^{1,4}X_{NeuGc}
869.28 24.5
870.37 219.1

Annotations:

CY
871.38 153.3

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B^{1,4}X_{Fuc} B^{0,3}X_{Man} B^{1,4}X_{Man} B^{0,3}X_{Man} B^{1,4}X_{Man} ^{1,4}X_{NeuGc}Z ^{1,4}X_{NeuGc}Z
872.17 27.0

Annotations:

B^{1,4}X_{Fuc} B^{0,3}X_{Man} B^{1,4}X_{Man} B^{0,3}X_{Man} B^{1,4}X_{Man} ^{1,4}X_{NeuGc}Z ^{1,4}X_{NeuGc}Z
872.89 26.7

Annotations:

YY YY
873.93 4307.7

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Y
874.55 274.0

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^{2,4}X_{GlcNAc}Z
875.39 58.8

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ZZ ZZ
876.27 79.7
877.39 550.8

Annotations:

^{1,3}A_{Man}Z ^{2,4}A_{Man}Z B^{0,2}X_{Fuc} ^{0,2}X_{Man}Z Z^{0,2}X_{Man} ^{0,4}X_{NeuGc}Z ^{0,4}X_{NeuGc}Z
878.38 167.7

Annotations:

^{1,5}X_{Fuc}Z ^{1,5}X_{Fuc}Z Z^{1,5}X_{Man} Z^{1,5}X_{Man} ^{2,4}X_{NeuGc}Z ^{2,4}X_{NeuGc}Z
879.14 27.4

Annotations:

^{2,4}X_{NeuGc}Z ^{1,3}A_{Man} ^{1,5}X_{Man}Y Y^{1,5}X_{Man} C^{0,4}X_{NeuGc} ^{2,4}X_{NeuGc}Z
880.51 20.8

Annotations:

B^{1,5}X_{Man} C^{1,4}X_{Fuc} C^{0,3}X_{Man} C^{1,4}X_{Man} C^{0,3}X_{Man} C^{1,4}X_{Man} ^{1,4}X_{NeuGc}Y ^{1,4}X_{NeuGc}Y
881.98 17.1

Annotations:

C^{2,5}X_{Fuc} C^{2,4}X_{NeuGc}
891.63 89.4

Annotations:

B^{1,4}X_{Fuc}
893.32 6478.0

Annotations:

YZ YZ ZY ZY
894.38 1083.2

Annotations:

B^{0,2}X_{GlcNAc} ^{0,2}X_{Fuc}Y ^{0,2}X_{Fuc}Y Y^{0,2}X_{Man} Y^{0,2}X_{Man} ^{0,4}X_{NeuGc}Y ^{2,5}X_{Man}Y Y^{2,5}X_{Man} B^{0,4}X_{Fuc} B^{1,3}X_{NeuGc}
895.38 1298.0

Annotations:

C^{1,3}X_{Fuc} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y C^{0,2}X_{Fuc} C^{2,4}X_{Fuc} C^{0,4}X_{Man} C^{1,3}X_{Man} C^{2,4}X_{Man} C^{0,4}X_{Man} C^{1,3}X_{Man} C^{2,4}X_{Man} ^{2,4}X_{NeuGc}Y
896.4 455.3

Annotations:

C^{3,5}X_{Fuc}
909.56 21.6

Annotations:

^{1,4}A_{Man} C^{1,4}X_{Fuc} ^{0,3}X_{Fuc}Y ^{0,3}X_{Fuc}Y Y^{0,3}X_{Man} Y^{1,4}X_{Man} Y^{0,3}X_{Man} Y^{1,4}X_{Man} ^{3,5}X_{Man}Y Y^{3,5}X_{Man} ^{1,5}X_{NeuGc}
910.42 782.0

Annotations:

B^{2,5}X_{GlcNAc}
911.33 20557.4

Annotations:

YY YY
912.36 3468.7

Annotations:

C^{0,2}X_{GlcNAc}
913.31 12.7
913.86 11.6
916.94 467.2

Annotations:

B
917.49 51.9

Annotations:

^{3,5}X_{Fuc}Y ^{3,5}X_{Fuc}Y Y^{3,5}X_{Man} Y^{3,5}X_{Man}
918.45 49.4
919.57 2.6
925.99 16.9

Annotations:

C
927.15 49.3
932.88 6.4
934.45 110.5
935.28 80.4

Annotations:

Z^{0,2}X_{Man} Z^{0,2}X_{Man}
937.58 652.2

Annotations:

Z Z
939.99 26.4
943.95 9.3
945.58 333.4

Annotations:

Z
946.49 2887.0

Annotations:

Y Y
947.11 183.7
948.22 47.4
949.51 30.7
951.54 76.8

Annotations:

Z^{2,5}X_{Man} Z^{2,5}X_{Man}
952.38 229.3
953.62 39.3

Annotations:

Y^{0,2}X_{Man} ^{1,5}A_{Man} Y^{0,2}X_{Man}
954.48 885.8

Annotations:

Y
955.19 188.9

Annotations:

C^{1,3}X_{NeuGc} C^{0,4}X_{Fuc}
956.15 58.1
959.69 42.3
963.45 62.2
975.39 3.8

Annotations:

^{0,2}X_{Fuc} ^{2,5}X_{Man} ^{2,5}X_{Man}
977.27 36.9
978.67 40.0
979.46 55.3
980.17 425.5
981.37 7725.6

Annotations:

B
982.39 1827.4

Annotations:

^{1,4}X_{Fuc} ^{0,3}X_{Man} ^{1,4}X_{Man} ^{0,3}X_{Man} ^{1,4}X_{Man}
983.23 5.6

Annotations:

^{2,5}X_{Fuc} ^{1,4}X_{Man}Y ^{1,4}X_{Man}Y Y^{0,3}X_{Man} Y^{1,4}X_{Man} Y^{0,3}X_{Man} Y^{1,4}X_{Man}
985.37 3.6
989.23 3.9
991.48 2.6
992.73 3.8
995.3 1.0

Annotations:

^{1,3}X_{Man}Z ^{1,3}X_{Man}Z Z^{0,4}X_{Man} Z^{1,3}X_{Man} Z^{2,4}X_{Man} Z^{0,4}X_{Man} Z^{1,3}X_{Man} Z^{2,4}X_{Man}
996.81 118.8

Annotations:

BZ
997.4 642.0

Annotations:

^{2,4}X_{Fuc} ^{0,4}X_{Man} ^{1,3}X_{Man} ^{2,4}X_{Man} ^{0,4}X_{Man} ^{1,3}X_{Man} ^{2,4}X_{Man} ^{1,3}X_{Fuc}
998.35 7366.4

Annotations:

^{3,5}X_{Fuc}
999.37 1251.8

Annotations:

C
999.91 26.6
1000.46 39.2
1003.73 10.4
1009.64 21.2
1010.48 54.5
1012.79 84.8
1013.68 55.1

Annotations:

^{1,3}X_{Man}Y ^{1,3}X_{Man}Y Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man}
1014.37 8567.4

Annotations:

BY CZ
1015.36 1166.5
1018.64 8.6
1019.17 12.1
1019.85 1.7
1032.4 152.1

Annotations:

CY
1033.36 35.9
1036.3 1.6
1037.5 92.0

Annotations:

ZZ ZZ
1038.59 60.0
1039.43 1717.8
1040.34 526.3
1053.52 17.6
1054.37 165.4
1055.38 12527.1

Annotations:

Z
1056.45 3133.6
1057.4 4887.3
1058.42 1181.2
1071.47 177.3

Annotations:

^{1,4}A_{Man}
1072.33 743.5
1073.34 30795.2

Annotations:

Y
1074.39 7589.8
1075.45 290.0
1078.44 36.9
1080.54 75.4

Annotations:

ZY YZ
1081.4 8.8
1095.53 25.0
1096.54 280.6
1097.54 68.6

Annotations:

B^{0,2}X_{GlcNAc} Z^{0,2}X_{Man} Z^{0,2}X_{Man}
1098.71 50.7

Annotations:

YY
1099.33 16.7
1101.46 19.2

Annotations:

^{1,5}X_{GlcNAc}Y ^{1,5}X_{GlcNAc}Y Y^{1,5}X_{Man} ^{1,5}X_{Man} Y^{1,5}X_{Man}
1102.43 18.7

Annotations:

^{2,5}A_{Man}Y
1111.78 13.1
1113.33 9.4

Annotations:

B^{2,5}X_{GlcNAc} Z^{2,5}X_{Man} Z^{2,5}X_{Man}
1114.46 926.0

Annotations:

^{1,5}A_{Man}Z
1115.46 168.8

Annotations:

C^{0,2}X_{GlcNAc} Y^{0,2}X_{Man} Y^{0,2}X_{Man}
1116.16 15.7
1117.16 2.8
1118.31 16.4

Annotations:

^{0,2}A_{Man}Y
1119.59 5.3
1124.45 24.2
1141.52 62.1
1142.9 105.2

Annotations:

BY CZ
1143.46 676.6

Annotations:

BY CZ
1144.47 215.0
1159.42 572.3
1160.42 9084.2

Annotations:

BY CZ
1161.43 2351.9

Annotations:

CY
1162.57 51.8
1164.52 2.5
1165.55 8.1
1169.68 16.8
1176.42 276.8
1177.34 42.7
1178.53 66.5

Annotations:

CY
1179.52 18.2
1180.48 2.6
1181.42 36.3
1182.44 6.4

Annotations:

^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z
1183.55 30.4
1184.48 15.9
1192.98 34.5
1199.59 104.1
1200.45 464.2

Annotations:

^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y
1201.47 7425.6

Annotations:

B^{2,5}X_{Man}
1202.49 2009.2

Annotations:

B^{0,2}X_{Gal}
1203.24 83.1

Annotations:

C^{0,2}X_{Man}
1211.52 1.7
1214.61 1.8
1215.4 4.3
1216.32 119.6

Annotations:

^{2,4}X_{GlcNAc}Y ^{2,4}X_{GlcNAc}Y
1217.43 17387.3

Annotations:

Z
1218.5 6008.2

Annotations:

B^{2,5}X_{Gal}
1219.45 16463.3

Annotations:

C^{2,5}X_{Man}
1220.45 4514.5

Annotations:

C^{0,2}X_{Gal}
1221.08 106.9
1221.76 46.8
1231.33 9.2
1232.33 10.9

Annotations:

B^{1,4}X_{Gal}
1233.33 46.5
1234.44 1466.0
1235.4 37532.0

Annotations:

Y
1236.45 10253.6

Annotations:

C^{2,5}X_{Gal}
1237.31 157.4
1239.86 35.7
1241.6 5.9
1242.48 97.2

Annotations:

ZY YZ
1243.38 32.2
1244.58 5.3
1257.52 66.5
1258.54 624.6
1259.51 201.9
1260.48 302.8

Annotations:

YY
1261.52 85.8
1270.34 18.3

Annotations:

Z^{1,5}X_{Man}
1275.4 216.5
1276.48 2140.4

Annotations:

^{1,5}A_{Man}Z
1277.49 642.9
1280.54 1.7

Annotations:

C^{1,3}X_{Gal} C^{2,4}X_{Gal} ^{0,2}A_{Man}Y
1287.29 28.9
1288.38 60.3

Annotations:

Y^{1,5}X_{Man}
1302.39 3.1

Annotations:

Y^{0,2}X_{Man}
1303.4 10.2
1304.18 59.5

Annotations:

BZ
1305.49 588.8
1306.55 230.0
1320.7 3.0
1321.4 550.4
1322.44 427.6

Annotations:

BY CZ
1323.33 50.4
1325.63 9.9
1340.75 13.7

Annotations:

CY
1341.3 23.1
1344.63 29.8
1345.65 46.0

Annotations:

BZ
1346.53 153.1

Annotations:

BY CZ
1347.59 63.5
1358.61 1.2

Annotations:

^{3,5}X_{NeuGc}Z
1361.22 50.3
1362.59 1254.2
1363.52 13896.8

Annotations:

BY CZ
1364.54 4047.4

Annotations:

CY
1365.52 70.4
1377.82 36.5
1378.73 66.5

Annotations:

^{2,4}X_{GlcNAc}
1379.49 797.3
1380.61 2351.9
1381.42 30042.0

Annotations:

CY
1382.47 11916.9
1383.28 267.9
1384.3 116.5
1385.97 22.9

Annotations:

ZZ
1387.17 5.8
1393.79 31.3
1396.28 26.3
1397.52 326.8
1398.37 134.9
1399.17 11.0
1403.52 9.5

Annotations:

YZ ZY
1404.54 455.9

Annotations:

YZ YZ ZY ZY
1405.41 161.8

Annotations:

B^{0,2}X_{Gal}
1420.52 1123.0

Annotations:

ZY YZ
1421.71 751.2

Annotations:

YY
1422.56 915.1

Annotations:

YY YY
1423.52 315.7

Annotations:

^{0,2}A_{Man}Z C^{0,2}X_{Gal}
1424.8 9.6
1428.7 16.6
1429.47 13.9

Annotations:

^{0,4}X_{NeuGc}Z
1436.57 12.7

Annotations:

^{1,4}X_{NeuGc}Y
1437.51 114.0

Annotations:

^{1,5}A_{Man}Z
1438.51 2473.0

Annotations:

YY
1439.51 829.0

Annotations:

^{1,5}A_{Man}Y ^{1,5}A_{Man}Y C^{2,5}X_{Gal}
1440.12 38.1

Annotations:

C^{0,3}X_{NeuGc}
1449.74 23.7

Annotations:

BZ BZ
1466.76 28.2

Annotations:

Y^{1,5}X_{Fuc} ^{1,5}X_{Gal}Y
1467.54 426.7

Annotations:

BY BY CZ CZ
1468.59 249.7
1483.54 133.2

Annotations:

BY CZ
1490.44 38.5
1500.71 24.2
1506.54 23.4

Annotations:

Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} ^{1,3}X_{Gal}Z ^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z ^{2,4}X_{Gal}Z Z^{0,4}X_{Man} Z^{1,3}X_{Man} Z^{2,4}X_{Man} Z^{0,4}X_{Man} Z^{1,3}X_{Man} Z^{2,4}X_{Man}
1507.53 62.9

Annotations:

BZ
1508.54 443.4

Annotations:

Z^{3,5}X_{Fuc}
1509.56 257.8

Annotations:

B^{0,2}X_{Man} B^{0,2}X_{Man} B^{0,4}X_{NeuGc} ^{3,5}X_{Fuc}Y
1521.75 6.7
1522.68 8.5

Annotations:

Z^{0,4}X_{Fuc} ^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z
1523.66 31.4

Annotations:

^{0,4}X_{Fuc}Y ^{1,3}X_{NeuGc}Y
1524.54 776.8

Annotations:

^{1,3}X_{Gal}Y ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Fuc} Y^{2,4}X_{Fuc} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man}
1525.51 2141.3

Annotations:

BY CZ
1526.04 27.2

Annotations:

BY CZ
1526.6 1188.5

Annotations:

Y^{3,5}X_{Fuc}
1527.43 179.8

Annotations:

C^{0,2}X_{Man} C^{0,2}X_{Man} C^{0,4}X_{NeuGc}
1532.61 10.1
1539.43 12.5

Annotations:

B^{1,4}X_{Fuc} B^{0,3}X_{Man} B^{1,4}X_{Man} B^{0,3}X_{Man} B^{1,4}X_{Man}
1541.81 43.9

Annotations:

B^{2,5}X_{Fuc}
1542.59 805.5
1543.52 913.7

Annotations:

CY
1544.54 42.2
1547.59 11.2
1548.75 5.7

Annotations:

ZZ ZZ
1563.59 19.0
1565.46 59.2
1566.59 761.0

Annotations:

Z
1567.52 186.2

Annotations:

Y
1568.61 11.6
1582.13 35.9

Annotations:

ZY YZ
1582.66 379.5

Annotations:

ZY YZ
1583.54 278.0
1584.56 3202.0

Annotations:

Y
1585.62 1256.6

Annotations:

B^{0,4}X_{Fuc} B^{1,3}X_{NeuGc}
1586.61 16.1
1597.58 57.9

Annotations:

B^{1,5}X_{NeuGc}
1599.09 31.2
1599.65 117.7
1600.56 1492.0

Annotations:

YY
1601.52 856.6

Annotations:

^{1,5}A_{Man}
1602.2 38.9
1611.93 5.3

Annotations:

B^{2,5}X_{NeuGc}
1629.41 347.0

Annotations:

B
1630.66 109.8
1646.71 37.2
1647.52 8.7

Annotations:

C
1652.56 30.1

Annotations:

BZ BZ
1653.49 52.3
1669.8 11.7
1670.68 1040.7

Annotations:

BY BY CZ CZ
1671.64 679.6
1672.82 50.4

Annotations:

^{1,5}X_{NeuGc}Y Y^{0,3}X_{Fuc} Y^{3,5}X_{Man} Y^{3,5}X_{Man}
1686.63 610.7

Annotations:

CZ BY
1687.61 209.6
1688.54 820.3

Annotations:

CY CY
1689.52 606.9
1690.66 25.5
1703.74 18.8
1704.62 212.8

Annotations:

CY
1705.6 61.9
1711.76 10.3

Annotations:

YZ ZY
1727.6 24.2

Annotations:

YZ YZ ZY ZY
1728.74 597.8

Annotations:

Z
1729.65 171.6

Annotations:

YY
1730.86 11.1

Annotations:

C^{0,2}X_{Man} C^{0,2}X_{Man} C^{0,4}X_{NeuGc}
1744.68 46.6

Annotations:

B^{2,5}X_{Fuc}
1745.52 69.3

Annotations:

YY YY
1746.54 3594.8

Annotations:

Y
1747.64 2094.8
1748.32 11.1
1749.53 12.9
1776.6 4.2

Annotations:

C^{0,3}X_{Fuc} C^{3,5}X_{Man} C^{3,5}X_{Man} ^{1,4}X_{NeuGc}Y
1810.71 2.1
1814.59 21.9
1831.85 181.0

Annotations:

^{2,4}X_{Man}Y Y^{0,4}X_{Man} Y^{1,3}X_{Man} Y^{2,4}X_{Man} ^{1,3}X_{Fuc}Y ^{1,3}X_{Fuc}Y ^{2,4}X_{Fuc}Y ^{2,4}X_{Fuc}Y ^{0,4}X_{Man}Y ^{1,3}X_{Man}Y
1832.68 1340.2

Annotations:

B
1833.68 597.5

Annotations:

^{3,5}X_{Fuc}Y ^{3,5}X_{Fuc}Y Y^{3,5}X_{Man} Y^{3,5}X_{Man}
1834.87 21.0
1848.93 52.9
1849.76 12.7
1850.62 170.5

Annotations:

C
1851.75 240.7
1852.57 18.9
1854.6 2.5
1873.6 7.7

Annotations:

Z Z
1889.6 17.4

Annotations:

Z

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