Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 310.11 | 7.5 |
|
Annotations: C |
|
| 312.93 | 12.4 |
| 330.02 | 5.9 |
|
Annotations: ^{1,4}X_{Man}Y |
|
| 364.78 | 3.8 |
| 366.17 | 1466.0 |
|
Annotations: YZ |
|
| 367.19 | 49.1 |
| 381.18 | 7.6 |
| 407.22 | 7.3 |
|
Annotations: Z |
|
| 425.43 | 10.1 |
|
Annotations: Y |
|
| 452.68 | 4.4 |
|
Annotations: ^{1,5}X_{Man} |
|
| 454.18 | 313.9 |
|
Annotations: B |
|
| 455.27 | 6.0 |
|
Annotations: ^{0,3}A_{Man} |
|
| 458.34 | 5.9 |
|
Annotations: ZZ |
|
| 505.95 | 5.7 |
|
Annotations: ^{2,5}X_{Gal}Y |
|
| 526.39 | 8.4 |
| 528.3 | 369.4 |
|
Annotations: BY |
|
| 529.25 | 23.5 |
| 549.14 | 41.9 |
|
Annotations: YZ |
|
| 569.31 | 19.9 |
|
Annotations: YZ |
|
| 585.8 | 9.6 |
|
Annotations: B^{1,5}X_{GlcNAc} |
|
| 586.49 | 11.7 |
|
Annotations: B^{1,5}X_{GlcNAc} |
|
| 587.37 | 31.4 |
|
Annotations: YY |
|
| 616.28 | 24.4 |
|
Annotations: C^{0,2}X_{NeuAc} |
|
| 629.79 | 55.5 |
|
Annotations: YZ |
|
| 639.29 | 35.5 |
| 640.32 | 17.2 |
| 656.39 | 117.9 |
| 657.25 | 7360.1 |
|
Annotations: B |
|
| 658.3 | 809.4 |
| 689.4 | 9.4 |
|
Annotations: ^{1,3}X_{Man}Y |
|
| 690.28 | 374.4 |
| 691.31 | 59.4 |
| 694.23 | 16.2 |
|
Annotations: Z |
|
| 708.31 | 24.5 |
| 710.84 | 26.5 |
| 731.33 | 295.5 |
|
Annotations: YZ |
|
| 732.3 | 27.4 |
|
Annotations: C^{2,5}X_{GlcNAc} |
|
| 740.16 | 11.7 |
|
Annotations: YY |
|
| 748.07 | 18.1 |
| 749.2 | 375.9 |
|
Annotations: YY |
|
| 750.26 | 34.7 |
| 775.23 | 32.1 |
|
Annotations: Z |
|
| 784.37 | 15.3 |
|
Annotations: Y |
|
| 803.83 | 16.0 |
|
Annotations: B^{2,5}X_{Gal} |
|
| 811.75 | 10.9 |
|
Annotations: B^{1,4}X_{Gal} |
|
| 818.47 | 19.8 |
| 819.33 | 291.1 |
|
Annotations: B |
|
| 820.43 | 66.3 |
|
Annotations: ^{1,4}X_{GlcNAc} |
|
| 821.69 | 112.1 |
|
Annotations: YY |
|
| 835.69 | 14.4 |
|
Annotations: C^{1,3}X_{Gal} |
|
| 847.87 | 8.2 |
|
Annotations: ^{1,5}X_{NeuAc}Z |
|
| 850.32 | 6.4 |
| 852.39 | 56.5 |
| 853.3 | 12.4 |
| 856.6 | 85.8 |
|
Annotations: BY |
|
| 860.43 | 3.9 |
|
Annotations: ^{3,5}X_{GlcNAc}Z |
|
| 861.45 | 8.0 |
| 870.44 | 8.0 |
|
Annotations: ^{3,5}X_{NeuAc}Z |
|
| 876.99 | 15.6 |
|
Annotations: Z |
|
| 878.42 | 10.9 |
|
Annotations: B^{1,3}X_{NeuAc} |
|
| 885.8 | 32.9 |
|
Annotations: Y |
|
| 892.24 | 31.3 |
|
Annotations: B^{1,5}X_{NeuAc} |
|
| 893.32 | 734.5 |
|
Annotations: YZ |
|
| 894.38 | 101.5 |
| 910.21 | 28.7 |
| 911.4 | 883.5 |
|
Annotations: YY |
|
| 912.25 | 119.2 |
| 930.69 | 9.1 |
| 934.4 | 5.3 |
|
Annotations: YZ |
|
| 935.44 | 25.8 |
|
Annotations: ^{1,3}X_{NeuAc}Z |
|
| 948.51 | 103.5 |
| 949.35 | 22.1 |
| 952.68 | 29.6 |
|
Annotations: YY |
|
| 957.91 | 146.0 |
|
Annotations: Z |
|
| 966.16 | 28.6 |
| 967.12 | 453.9 |
|
Annotations: Y |
|
| 967.67 | 59.1 |
| 970.53 | 10.8 |
| 973.88 | 10.9 |
| 981.39 | 24.0 |
|
Annotations: BY |
|
| 1001.92 | 14.7 |
|
Annotations: B |
|
| 1002.84 | 8.4 |
|
Annotations: ^{1,5}X_{NeuAc} |
|
| 1022.53 | 14.9 |
|
Annotations: ^{3,5}X_{GlcNAc}Z |
|
| 1023.48 | 41.9 |
| 1030.35 | 11.4 |
| 1040.34 | 27.9 |
|
Annotations: ^{3,5}X_{GlcNAc}Y |
|
| 1041.3 | 13.3 |
| 1055.43 | 730.2 |
| 1056.54 | 81.0 |
| 1073.54 | 32.5 |
| 1078.42 | 6.1 |
|
Annotations: ZZ |
|
| 1093.48 | 9.4 |
| 1095.85 | 40.9 |
| 1096.53 | 195.4 |
|
Annotations: YZ |
|
| 1097.49 | 30.4 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 1112.04 | 13.5 |
| 1113.47 | 15.0 |
| 1114.48 | 254.5 |
|
Annotations: YY |
|
| 1115.34 | 62.3 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 1165.34 | 5.7 |
| 1183.8 | 8.1 |
| 1184.49 | 195.2 |
|
Annotations: CZ |
|
| 1185.45 | 87.3 |
| 1202.56 | 98.3 |
|
Annotations: CY |
|
| 1203.37 | 26.6 |
| 1217.6 | 20.6 |
| 1218.29 | 4.0 |
| 1240.41 | 12.9 |
|
Annotations: ZZ |
|
| 1243.42 | 20.8 |
|
Annotations: ^{3,5}X_{GlcNAc}Y |
|
| 1257.92 | 27.4 |
|
Annotations: ^{2,4}X_{GlcNAc}Y |
|
| 1258.5 | 667.8 |
|
Annotations: YZ |
|
| 1259.52 | 171.8 |
| 1274.8 | 8.1 |
|
Annotations: C^{1,4}X_{Man} |
|
| 1275.55 | 72.9 |
| 1276.5 | 1998.8 |
|
Annotations: YY |
|
| 1277.49 | 711.4 |
| 1278.33 | 3.7 |
| 1313.71 | 4.4 |
| 1329.32 | 12.7 |
| 1345.7 | 43.7 |
|
Annotations: Y^{1,5}X_{Gal} |
|
| 1346.55 | 879.2 |
|
Annotations: BY |
|
| 1347.55 | 267.1 |
| 1364.41 | 55.5 |
|
Annotations: CY |
|
| 1366.62 | 7.0 |
| 1369.46 | 36.0 |
| 1385.46 | 8.2 |
| 1387.57 | 454.0 |
|
Annotations: Z |
|
| 1388.52 | 59.6 |
|
Annotations: B^{0,2}X_{Gal} |
|
| 1402.96 | 15.6 |
| 1404.34 | 121.0 |
|
Annotations: B^{2,5}X_{Gal} |
|
| 1405.02 | 38.7 |
|
Annotations: Y |
|
| 1405.53 | 1766.6 |
|
Annotations: Y |
|
| 1406.59 | 761.9 |
|
Annotations: C^{0,2}X_{Gal} |
|
| 1407.62 | 9.7 |
| 1420.62 | 65.0 |
| 1421.78 | 43.5 |
| 1438.58 | 52.0 |
| 1439.84 | 15.6 |
| 1461.72 | 6.0 |
|
Annotations: YZ |
|
| 1462.73 | 21.7 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 1474.51 | 19.6 |
| 1475.58 | 5.2 |
|
Annotations: B^{3,5}X_{GlcNAc} |
|
| 1479.58 | 147.3 |
|
Annotations: YY |
|
| 1480.74 | 13.7 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 1508.64 | 38.7 |
|
Annotations: BY |
|
| 1509.63 | 6.1 |
| 1528.06 | 11.4 |
| 1531.71 | 12.8 |
|
Annotations: BZ |
|
| 1532.71 | 6.4 |
| 1548.76 | 10.3 |
| 1549.61 | 1771.0 |
|
Annotations: Z |
|
| 1550.61 | 561.1 |
| 1564.9 | 24.9 |
| 1565.87 | 103.3 |
|
Annotations: ^{2,5}X_{NeuAc}Y |
|
| 1566.59 | 255.7 |
| 1567.54 | 7782.9 |
|
Annotations: Y |
|
| 1568.58 | 2834.2 |
| 1569.23 | 108.4 |
| 1570.05 | 16.9 |
| 1623.64 | 26.3 |
|
Annotations: YZ |
|
| 1637.55 | 68.7 |
|
Annotations: ^{1,4}X_{NeuAc}Z |
|
| 1641.76 | 165.9 |
|
Annotations: YY |
|
| 1642.57 | 12.3 |
|
Annotations: C^{3,5}X_{NeuAc} |
|
| 1696.75 | 23.5 |
|
Annotations: ^{3,5}X_{GlcNAc} |
|
| 1711.7 | 104.0 |
|
Annotations: BY |
|
| 1728.47 | 44.1 |
| 1729.69 | 53.1 |
|
Annotations: CY |
|
| 1730.52 | 4.5 |
| 1752.78 | 53.8 |
|
Annotations: Z |
|
| 1753.81 | 18.0 |
| 1768.92 | 19.8 |
| 1770.79 | 139.7 |
|
Annotations: Y |
|
| 1771.81 | 53.6 |
|
Annotations: ^{1,5}A_{Man} |
|
| 1799.68 | 36.1 |
|
Annotations: B |
|
| 1800.63 | 11.4 |
| 1840.63 | 54.5 |
| 1841.75 | 25.9 |
| 1856.97 | 16.0 |
| 1858.68 | 172.2 |
| 1859.8 | 80.7 |
| 1914.61 | 10.2 |
|
Annotations: Z |
|
| 1915.83 | 29.0 |
| 1932.72 | 277.9 |
|
Annotations: Y |
|
| 1933.75 | 157.9 |