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Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library

Peak	Intensity
186.14	13.7
Annotations: BZ
202.88	24.9
204.08	3416.9
Annotations: Z B Z
205.09	124.5
Annotations: ^{1,3}A_{Man}Z ^{2,4}A_{Man}Z
222.11	154.7
Annotations: Y C
223.14	11.5
Annotations: ^{2,4}A_{Man}Y ^{1,3}A_{Man}Y ^{0,4}A_{Man} ^{0,2}A_{Man} ^{2,4}A_{Man} ^{1,3}A_{Man}
251.23	13.6
258.8	3.9
285.19	11.8
Annotations: YZ ZY
286.15	11.5
294.62	1.8
314.69	11.3
324.39	2.4
325.21	57.5
Annotations: BY BY CZ CZ BY CZ
326.2	15.2
343.27	13.1
Annotations: CY CY
348.19	15.4
365.4	19.2
366.19	3066.3
Annotations: B
367.2	262.2
Annotations: ^{0,4}A_{Man}Z ^{0,4}A_{Man}Z
367.81	6.7
Annotations: ^{2,5}A_{Man}Z
375.72	9.6
Annotations: ^{0,2}A_{Man}Z
384.25	3.4
Annotations: C
385.35	1.2
Annotations: ^{0,2}A_{Man}Y ^{0,4}A_{Man}Y ^{0,4}A_{Man}Y
387.12	18.7
393.16	3.5
394.98	13.7
395.91	76.3
398.74	9.3
Annotations: ^{3,5}A_{Man}Y ^{3,5}A_{Man}Y
400.23	10.8
407.29	47.2
Annotations: Z
425.22	254.1
Annotations: Y
426.34	11.5
Annotations: BY CZ BY CZ BY CZ
438.87	6.7
447.21	164.3
Annotations: YZ YZ ZY ZY
447.85	12.2
450.24	9.2
456.29	8.6
Annotations: YY YY
458.85	22.6
Annotations: ^{1,5}A_{Man}
467.08	16.9
467.82	275.0
Annotations: Z
468.43	20.2
475.79	74.2
476.83	819.2
Annotations: Y
477.41	116.0
478.78	6.3
Annotations: ^{2,5}A_{Man}
480.31	4.8
487.2	25.8
Annotations: B
488.24	8.8
492.43	10.2
508.11	5.3
Annotations: B
510.29	18.5
Annotations: BZ
516.72	12.6
Annotations: C
518.19	26.6
524.91	1.6
526.36	24.7
527.22	29.2
528.23	1813.6
Annotations: Z
529.22	215.5
530.17	2.9
537.18	14.8
Annotations: Y
540.04	50.9
Annotations: ZZ
546.29	21.2
Annotations: CY
547.79	14.4
548.88	788.0
Annotations: YZ ZY
549.94	14.6
551.33	11.2
Annotations: ZZ
555.88	7.1
556.8	97.4
557.84	2126.6
Annotations: YY
558.5	119.7
560.31	15.2
563.85	5.9
565.9	2.8
569.3	78.4
Annotations: YZ ZY
570.17	7.6
581.91	12.4
586.48	4.7
587.29	667.2
Annotations: YY
588.28	99.8
589.11	10.5
591.08	12.0
593.86	32.7
600.19	17.1
601.28	1.3
608.21	11.9
609.35	45.8
Annotations: B Z
611.43	13.4
617.89	1.8
Annotations: C Y
620.83	27.2
628.78	85.8
629.89	659.5
Annotations: Z Z
630.7	71.5
634.43	19.0
635.48	2.1
636.27	6.0
637.93	58.5
638.84	2661.8
Annotations: Y Y
639.42	307.6
640.0	38.8
646.47	11.4
647.15	11.4
647.68	4.1
648.59	9.2
649.19	13.5
Annotations: BY CZ
649.9	20.9
653.24	6.7
659.38	7.5
662.78	8.2
668.88	14.4
672.37	5.8
674.85	15.2
685.12	6.6
688.15	25.3
689.54	23.6
690.29	2746.1
691.27	385.5
691.84	19.8
701.87	28.4
708.25	57.8
708.86	18.4
710.14	9.4
711.47	9.3
715.72	3.7
720.79	10.2
729.2	6.3
731.33	1048.7
Annotations: BY CZ YZ ZY
732.32	154.3
733.16	10.0
747.15	31.0
747.67	26.7
748.44	117.0
749.32	3739.4
Annotations: CY YY
750.34	634.9
751.4	20.2
Annotations: ^{0,2}A_{Man}Z
752.19	2.6
753.39	6.0
Annotations: ^{2,5}A_{Man}Y
756.36	8.9
788.32	5.1
799.33	5.2
829.14	8.9
Annotations: CY
829.96	6.0
834.1	4.2
Annotations: BZ BZ BZ
850.39	63.2
851.47	76.5
852.37	4163.8
Annotations: BY CZ BY BY CZ CZ
853.37	932.3
854.43	13.0
855.16	19.2
857.39	4.0
870.38	30.2
Annotations: CY CY CY
871.39	11.3
871.98	8.2
891.46	14.2
892.53	72.5
893.38	2409.5
Annotations: YZ YZ ZY ZY
894.38	440.3
894.95	9.7
895.59	18.0
907.48	12.2
909.66	207.1
910.57	135.3
911.36	10177.0
Annotations: YY YY
912.39	2334.2
913.35	38.5
914.45	8.5
934.7	25.1
Annotations: Z
935.48	16.1
952.41	50.3
Annotations: Y
953.52	13.9
954.17	5.5
972.23	8.0
Annotations: ^{0,2}A_{Man}
979.64	2.7
1012.13	11.4
1012.94	24.0
1013.51	30.0
1014.4	3620.8
Annotations: B
1015.42	912.6
1016.37	54.8
1016.91	4.4
1032.37	26.2
Annotations: C
1037.36	5.9
Annotations: BZ BZ ZZ ZZ
1038.14	7.9
1053.45	72.5
1054.45	77.2
1055.43	4728.4
Annotations: Z
1056.43	1380.7
1057.38	49.1
1070.42	13.2
1071.64	339.3
1072.53	682.3
1073.39	18329.7
Annotations: Y
1074.43	4961.3
1075.47	232.0
1077.98	1.4
Annotations: ZZ
1114.53	38.0
Annotations: YY
1200.19	17.7
1215.66	53.4
1216.71	53.3
1217.48	6850.9
Annotations: B Z
1218.49	2413.6
1219.37	170.0
1222.27	16.9
1231.24	10.3
1232.58	13.9
1233.76	787.4
1234.65	949.6
1235.43	31032.9
Annotations: C Y
1236.45	11818.5
1237.41	783.1
1238.32	30.7
1239.11	38.7
1242.54	5.6
1258.52	4.9
Annotations: Z Z
1276.25	9.5
Annotations: Y Y