Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
GlyToucan Accession Number: G62446JD
Peak | Intensity |
---|---|
256.1 | 5.0 |
257.03 | 2.0 |
274.15 | 220.1 |
275.07 | 12.8 |
291.36 | 0.7 |
292.15 | 190.4 |
Annotations: B |
|
293.07 | 7.7 |
Annotations: ^{3,5}A_{Man}Z ^{1,4}A_{GlcNAc} |
|
294.02 | 3.4 |
Annotations: YY |
|
294.74 | 1.1 |
Annotations: ^{0,4}A_{Man}Y |
|
295.32 | 0.9 |
296.22 | 1.1 |
310.17 | 2.0 |
Annotations: C |
|
312.0 | 0.7 |
325.1 | 1.6 |
Annotations: ^{0,2}A_{Man}Y C^{1,3}X_{Man} |
|
330.7 | 3.8 |
348.16 | 2.9 |
Annotations: BZ BZ |
|
364.68 | 1.7 |
365.29 | 12.3 |
366.19 | 958.7 |
Annotations: B |
|
367.2 | 90.6 |
368.14 | 0.4 |
Annotations: C^{1,5}X_{GlcNAc} C^{2,4}X_{NeuAc} |
|
370.54 | 2.8 |
371.11 | 0.7 |
Annotations: C^{2,4}X_{NeuAc} |
|
374.41 | 1.0 |
Annotations: ^{1,4}A_{Man} |
|
383.2 | 1.3 |
384.16 | 4.0 |
Annotations: C |
|
395.62 | 0.7 |
Annotations: B^{2,5}X_{GlcNAc} |
|
400.2 | 1.6 |
407.32 | 5.3 |
Annotations: Z |
|
408.19 | 0.4 |
Annotations: B^{0,2}X_{Gal} ^{1,3}A_{Man}Z ^{0,4}A_{Man}Z |
|
418.19 | 1.2 |
Annotations: ^{2,5}A_{Man}Y |
|
425.2 | 13.7 |
Annotations: Y |
|
425.92 | 1.8 |
Annotations: ^{1,3}X_{Man}Y ^{1,5}A_{Gal} C^{1,3}X_{Man} ^{1,3}A_{Man}Y ^{0,2}A_{Man}Y ^{0,4}A_{Man}Y ^{1,3}A_{Man} ^{2,4}A_{Man} C^{0,2}X_{Gal} C^{2,4}X_{GlcNAc} Y^{1,3}X_{Man} Y^{1,3}X_{GlcNAc} |
|
436.17 | 2.8 |
Annotations: B^{0,2}X_{NeuAc} |
|
437.41 | 0.6 |
Annotations: ^{2,4}X_{GlcNAc}Z Z^{0,4}X_{GlcNAc} Z^{2,4}X_{GlcNAc} |
|
447.27 | 2.9 |
Annotations: BY CZ BY CZ ZY YZ |
|
451.68 | 2.7 |
Annotations: B^{2,5}X_{NeuAc} |
|
452.49 | 1.2 |
Annotations: B^{2,5}X_{NeuAc} |
|
454.18 | 51.0 |
Annotations: B |
|
455.03 | 7.3 |
Annotations: ^{0,3}A_{Man} |
|
460.33 | 1.1 |
467.79 | 1.8 |
Annotations: Z |
|
472.18 | 1.6 |
Annotations: C |
|
475.02 | 1.6 |
477.34 | 0.5 |
Annotations: C^{0,2}X_{Gal} |
|
487.29 | 1.5 |
494.24 | 1.4 |
495.31 | 38.2 |
496.16 | 6.8 |
505.27 | 2.2 |
Annotations: B^{1,5}X_{Man} ^{1,5}A_{Man}Z C^{2,5}X_{GlcNAc} ^{2,5}X_{Gal}Y Y^{2,5}X_{GlcNAc} ^{2,5}X_{GlcNAc}Y |
|
512.19 | 5.0 |
527.15 | 1.7 |
Annotations: B^{1,4}X_{Man} |
|
528.26 | 227.1 |
Annotations: BY CZ BY BY CZ CZ |
|
529.29 | 31.8 |
533.08 | 0.6 |
545.29 | 1.4 |
546.36 | 6.7 |
Annotations: CY CY |
|
547.25 | 2.4 |
548.85 | 4.7 |
Annotations: Z |
|
549.53 | 0.7 |
Annotations: ^{1,5}A_{Man}Z |
|
551.67 | 1.1 |
Annotations: ZZ |
|
558.01 | 19.0 |
Annotations: Y |
|
560.32 | 1.9 |
Annotations: C^{1,4}X_{NeuAc} |
|
563.54 | 3.0 |
Annotations: BZ |
|
569.3 | 31.1 |
Annotations: ZY YZ |
|
570.22 | 2.2 |
Annotations: ^{0,4}A_{Man}Z |
|
571.3 | 2.2 |
Annotations: B^{2,5}X_{NeuAc} Y^{1,5}X_{Man} ^{1,5}X_{GlcNAc} Y^{1,5}X_{GlcNAc} C^{1,5}X_{Gal} ^{1,5}X_{Gal}Y |
|
578.7 | 0.7 |
Annotations: B^{0,3}X_{NeuAc} C^{0,2}X_{Gal} ^{0,2}X_{Gal}Y |
|
584.57 | 0.9 |
Annotations: ^{3,5}A_{Man}Z ^{1,5}X_{NeuAc}Z Z^{1,4}X_{Man} Z^{1,4}X_{GlcNAc} ^{1,4}X_{Gal}Z B^{1,4}X_{Gal} |
|
585.4 | 2.8 |
Annotations: ^{1,4}A_{GlcNAc} |
|
586.68 | 1.3 |
Annotations: B^{3,5}X_{NeuAc} B^{1,5}X_{GlcNAc} C^{2,5}X_{Gal} ^{2,5}X_{Gal}Y |
|
587.33 | 52.3 |
Annotations: YY |
|
588.34 | 4.0 |
Annotations: ^{0,4}A_{Man}Y |
|
589.51 | 1.3 |
591.61 | 1.5 |
Annotations: ^{2,5}X_{NeuAc}Z |
|
592.83 | 1.9 |
Annotations: BY CZ |
|
602.59 | 6.8 |
Annotations: ^{3,5}A_{Man}Y |
|
603.73 | 8.1 |
604.79 | 1.6 |
Annotations: Z^{0,3}X_{GlcNAc} |
|
610.33 | 0.9 |
615.53 | 0.4 |
Annotations: Y^{1,5}X_{Man} ^{1,5}X_{Man}Y ^{3,5}X_{NeuAc}Y C^{1,5}X_{Man} |
|
617.82 | 2.5 |
Annotations: C^{1,5}X_{NeuAc} ^{0,3}A_{Man}Y C^{1,4}X_{Man} |
|
622.22 | 2.6 |
Annotations: ^{3,5}X_{GlcNAc} Y^{3,5}X_{GlcNAc} |
|
629.86 | 8.1 |
Annotations: ZY BY CZ YZ |
|
633.28 | 1.8 |
635.3 | 3.1 |
639.18 | 62.7 |
Annotations: CY YY |
|
640.27 | 3.9 |
641.44 | 1.6 |
Annotations: Z^{1,4}X_{Man} ^{1,4}X_{Man}Z |
|
643.61 | 2.3 |
Annotations: ^{0,4}X_{NeuAc}Y B^{1,3}X_{Man} B^{0,4}X_{GlcNAc} B^{2,4}X_{GlcNAc} ^{2,4}X_{NeuAc}Z Z^{1,5}X_{GlcNAc} |
|
644.45 | 1.7 |
Annotations: B^{3,5}X_{NeuAc} ^{1,5}A_{Man}Z ^{2,5}A_{Man} |
|
650.34 | 2.0 |
Annotations: Z |
|
650.91 | 1.6 |
655.63 | 5.8 |
656.46 | 9.7 |
657.3 | 2336.3 |
Annotations: B |
|
658.31 | 388.8 |
659.27 | 27.0 |
Annotations: Y |
|
659.95 | 7.4 |
Annotations: ^{1,5}A_{Man} |
|
660.83 | 1.7 |
Annotations: C^{1,3}X_{NeuAc} |
|
672.38 | 1.1 |
Annotations: BZ |
|
673.98 | 4.2 |
Annotations: B |
|
674.75 | 2.8 |
Annotations: C |
|
675.4 | 4.2 |
Annotations: C |
|
683.03 | 2.8 |
Annotations: C |
|
685.53 | 1.6 |
688.57 | 1.8 |
Annotations: ^{2,5}X_{Gal} Y^{2,5}X_{GlcNAc} C^{0,3}X_{NeuAc} ^{0,3}X_{NeuAc}Y |
|
689.42 | 0.8 |
Annotations: Y^{1,3}X_{Man} ^{1,3}X_{Man}Y Y^{1,3}X_{GlcNAc} |
|
690.33 | 223.6 |
Annotations: BY CZ |
|
691.42 | 46.4 |
692.45 | 1.2 |
694.29 | 10.8 |
Annotations: Z |
|
694.8 | 2.6 |
Annotations: ^{1,4}X_{Gal} Y^{0,3}X_{GlcNAc} |
|
695.41 | 4.0 |
Annotations: ^{1,4}X_{Gal} Y^{0,3}X_{GlcNAc} |
|
698.05 | 3.8 |
699.34 | 1.3 |
Annotations: B^{0,4}X_{NeuAc} |
|
703.49 | 20.0 |
Annotations: Y |
|
704.48 | 4.8 |
Annotations: B^{1,4}X_{NeuAc} |
|
705.17 | 1.0 |
707.15 | 1.7 |
708.46 | 6.8 |
Annotations: CY |
|
710.07 | 0.6 |
Annotations: B^{1,4}X_{GlcNAc} ^{1,3}X_{Gal} ^{2,4}X_{Gal} Y^{0,4}X_{GlcNAc} Y^{2,4}X_{GlcNAc} |
|
713.48 | 2.1 |
Annotations: BZ ZZ ZZ |
|
723.14 | 0.8 |
Annotations: B^{2,5}X_{GlcNAc} |
|
730.37 | 9.6 |
Annotations: B^{0,3}X_{GlcNAc} |
|
731.4 | 271.8 |
Annotations: Z |
|
732.44 | 47.0 |
Annotations: C^{2,5}X_{GlcNAc} |
|
739.55 | 11.0 |
Annotations: C^{0,3}X_{GlcNAc} ^{1,4}X_{Man} |
|
740.47 | 403.2 |
Annotations: Y |
|
741.23 | 21.8 |
742.4 | 1.3 |
743.01 | 0.9 |
743.82 | 3.1 |
746.12 | 1.7 |
747.34 | 1.0 |
Annotations: C^{3,5}X_{GlcNAc} ^{1,4}A_{Man} |
|
748.46 | 10.7 |
749.37 | 379.4 |
Annotations: CY YY YY |
|
750.38 | 79.7 |
751.17 | 1.4 |
752.92 | 1.7 |
Annotations: B^{1,3}X_{NeuAc} ^{1,3}X_{NeuAc}Z |
|
756.71 | 0.9 |
760.61 | 1.8 |
766.24 | 11.7 |
766.89 | 3.5 |
775.44 | 61.6 |
Annotations: B Z |
|
775.96 | 5.9 |
Annotations: ^{1,5}X_{NeuAc} |
|
776.87 | 2.1 |
Annotations: C^{1,5}X_{Man} ^{1,5}X_{GlcNAc}Y Y^{1,5}X_{GlcNAc} ^{1,5}X_{Man}Y Y^{1,5}X_{Man} |
|
778.31 | 1.4 |
781.21 | 2.3 |
783.02 | 1.5 |
Annotations: ^{2,5}X_{NeuAc} |
|
783.61 | 6.3 |
Annotations: ^{2,5}X_{NeuAc} |
|
784.41 | 250.4 |
Annotations: C Y |
|
784.98 | 19.7 |
786.36 | 0.9 |
787.94 | 1.2 |
788.93 | 1.2 |
Annotations: B^{2,5}X_{GlcNAc} |
|
789.69 | 1.8 |
Annotations: B^{2,5}X_{GlcNAc} |
|
790.57 | 1.6 |
Annotations: ^{0,3}X_{NeuAc} |
|
792.88 | 2.5 |
Annotations: C^{1,3}X_{NeuAc} |
|
793.38 | 1.4 |
Annotations: C^{1,3}X_{NeuAc} |
|
794.53 | 3.1 |
796.01 | 5.0 |
796.69 | 1.4 |
797.49 | 2.0 |
798.55 | 1.4 |
Annotations: ^{3,5}X_{NeuAc} ^{1,5}X_{GlcNAc} |
|
801.19 | 6.7 |
802.09 | 0.5 |
802.61 | 0.5 |
805.03 | 9.5 |
806.47 | 1.7 |
817.56 | 0.8 |
Annotations: ^{2,5}A_{Man}Z |
|
818.19 | 1.0 |
819.35 | 77.1 |
Annotations: B |
|
820.3 | 18.1 |
Annotations: ^{1,4}X_{GlcNAc} |
|
821.1 | 0.7 |
Annotations: C^{1,4}X_{Man} C^{0,3}X_{GlcNAc} Y^{1,4}X_{Man} ^{1,4}X_{GlcNAc}Y Y^{1,4}X_{GlcNAc} ^{1,4}X_{Man}Y |
|
822.03 | 0.8 |
825.41 | 0.7 |
Annotations: ^{0,4}X_{NeuAc} ^{0,2}X_{GlcNAc} |
|
827.32 | 0.7 |
829.7 | 0.7 |
836.13 | 6.3 |
837.49 | 1.5 |
Annotations: C |
|
840.01 | 1.9 |
842.34 | 2.5 |
846.04 | 0.5 |
850.7 | 2.0 |
851.36 | 1.0 |
Annotations: C^{1,3}X_{Man} ^{0,2}A_{Man}Y C^{2,4}X_{GlcNAc} Y^{1,3}X_{Man} Y^{1,3}X_{GlcNAc} ^{1,3}X_{Man}Y |
|
852.44 | 2.7 |
853.51 | 2.0 |
855.47 | 0.7 |
Annotations: ^{0,4}X_{GlcNAc} ^{2,4}X_{GlcNAc} |
|
858.57 | 1.0 |
860.44 | 109.9 |
Annotations: ^{3,5}X_{GlcNAc}Z Z^{3,5}X_{GlcNAc} |
|
861.41 | 28.8 |
867.12 | 0.9 |
867.96 | 33.4 |
868.72 | 4.1 |
869.89 | 1.2 |
872.0 | 1.4 |
873.1 | 1.2 |
875.79 | 5.6 |
Annotations: BZ BZ ZZ |
|
877.0 | 3.8 |
877.8 | 3.3 |
881.96 | 1.2 |
885.92 | 2.4 |
886.75 | 3.2 |
887.5 | 1.0 |
891.51 | 0.9 |
892.38 | 4.7 |
Annotations: Y^{0,4}X_{GlcNAc} ^{2,4}X_{GlcNAc}Y Y^{2,4}X_{GlcNAc} |
|
893.4 | 337.3 |
Annotations: BY CZ BY CZ ZY YZ |
|
894.44 | 96.0 |
910.12 | 30.1 |
911.41 | 1204.3 |
Annotations: CY CY YY |
|
912.41 | 285.3 |
913.3 | 4.7 |
917.52 | 1.5 |
932.29 | 2.4 |
933.32 | 1.1 |
934.49 | 101.0 |
Annotations: Z |
|
935.42 | 33.0 |
Annotations: B^{0,2}X_{Gal} |
|
936.47 | 5.1 |
950.89 | 1.1 |
Annotations: B^{2,5}X_{Gal} |
|
951.55 | 7.8 |
Annotations: B^{2,5}X_{Gal} |
|
952.43 | 229.3 |
Annotations: Y |
|
953.51 | 59.4 |
Annotations: C^{0,2}X_{Gal} |
|
954.21 | 0.5 |
964.6 | 1.4 |
981.51 | 8.3 |
Annotations: BY CZ |
|
982.43 | 1.6 |
1001.86 | 2.3 |
1002.99 | 0.8 |
1004.34 | 1.3 |
1021.22 | 3.5 |
1022.46 | 134.8 |
Annotations: B^{3,5}X_{GlcNAc} Z^{3,5}X_{GlcNAc} ^{3,5}X_{GlcNAc}Z |
|
1023.49 | 27.5 |
1039.83 | 1.6 |
1040.45 | 24.4 |
Annotations: C^{3,5}X_{GlcNAc} Y^{3,5}X_{GlcNAc} ^{3,5}X_{GlcNAc}Y |
|
1041.55 | 5.9 |
1042.44 | 2.5 |
1053.85 | 6.0 |
Annotations: B^{1,4}X_{Man} |
|
1054.77 | 1.6 |
Annotations: ^{1,3}X_{Man} C^{2,4}X_{GlcNAc} Y^{1,3}X_{Man} ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{0,4}X_{GlcNAc} Y^{2,4}X_{GlcNAc} ^{2,4}X_{GlcNAc}Y |
|
1055.47 | 150.8 |
Annotations: BY CZ |
|
1056.49 | 50.9 |
1057.59 | 4.7 |
1063.37 | 0.7 |
1073.49 | 17.2 |
Annotations: CY |
|
1074.44 | 3.7 |
1078.48 | 3.7 |
Annotations: ZZ ZZ BZ |
|
1079.48 | 2.4 |
1094.32 | 1.0 |
1095.37 | 7.7 |
1096.49 | 792.8 |
Annotations: Z |
|
1097.49 | 224.5 |
Annotations: ^{1,5}A_{Man}Z |
|
1098.54 | 1.2 |
1111.49 | 3.8 |
1112.09 | 2.3 |
1112.94 | 64.3 |
1113.7 | 56.9 |
1114.45 | 2514.5 |
Annotations: Y |
|
1115.48 | 677.4 |
Annotations: ^{1,5}A_{Man}Y |
|
1116.38 | 41.0 |
1116.99 | 2.0 |
1136.6 | 3.1 |
1142.07 | 1.2 |
Annotations: Y^{1,5}X_{Man} ^{1,5}X_{GlcNAc} Y^{1,5}X_{GlcNAc} C^{1,5}X_{Gal} ^{1,5}X_{Gal}Y |
|
1142.95 | 1.2 |
Annotations: BY CZ |
|
1143.59 | 4.7 |
Annotations: BY CZ |
|
1144.69 | 2.3 |
1155.38 | 1.1 |
Annotations: B^{0,3}X_{NeuAc} |
|
1166.46 | 3.0 |
Annotations: BZ |
|
1175.81 | 1.2 |
1182.87 | 1.7 |
Annotations: ^{2,5}X_{NeuAc}Z |
|
1183.55 | 2.3 |
1184.53 | 115.6 |
Annotations: BY CZ |
|
1185.5 | 39.1 |
1186.5 | 7.7 |
Annotations: ^{1,5}X_{NeuAc}Y C^{1,4}X_{Gal} Y^{1,4}X_{Man} ^{1,4}X_{GlcNAc} Y^{1,4}X_{GlcNAc} ^{1,4}X_{Gal}Y |
|
1189.48 | 1.2 |
Annotations: C^{3,5}X_{NeuAc} C^{1,5}X_{GlcNAc} |
|
1202.52 | 78.4 |
Annotations: CY |
|
1203.53 | 47.3 |
1204.57 | 1.6 |
1205.11 | 1.1 |
1225.56 | 5.8 |
Annotations: Z^{3,5}X_{GlcNAc} |
|
1226.55 | 1.8 |
Annotations: B^{0,4}X_{NeuAc} B^{0,2}X_{GlcNAc} |
|
1239.52 | 1.5 |
Annotations: Z^{0,4}X_{GlcNAc} Z^{2,4}X_{GlcNAc} |
|
1240.71 | 0.8 |
Annotations: BZ ZZ |
|
1243.46 | 19.0 |
Annotations: ^{3,5}X_{GlcNAc} Y^{3,5}X_{GlcNAc} |
|
1244.7 | 3.2 |
Annotations: C^{0,4}X_{NeuAc} C^{0,2}X_{GlcNAc} |
|
1257.51 | 3.3 |
Annotations: ^{2,4}X_{GlcNAc} Y^{0,4}X_{GlcNAc} Y^{2,4}X_{GlcNAc} |
|
1258.56 | 296.9 |
Annotations: BY CZ ZY YZ |
|
1259.57 | 102.1 |
1260.39 | 4.1 |
Annotations: C^{2,5}X_{GlcNAc} |
|
1275.27 | 30.6 |
1276.52 | 924.8 |
Annotations: CY YY |
|
1277.55 | 342.8 |
1278.65 | 6.8 |
1280.51 | 2.3 |
1299.7 | 10.7 |
Annotations: Z |
|
1300.57 | 6.4 |
1315.63 | 0.5 |
1316.49 | 1.1 |
1317.59 | 104.5 |
Annotations: Y |
|
1318.62 | 44.6 |
Annotations: ^{1,5}A_{Man} |
|
1319.66 | 5.6 |
1328.51 | 4.4 |
Annotations: BZ |
|
1329.81 | 0.7 |
1344.31 | 2.4 |
Annotations: B^{2,5}X_{NeuAc} ^{2,5}X_{NeuAc}Z |
|
1345.04 | 1.4 |
Annotations: ^{1,5}X_{Gal} |
|
1346.57 | 228.1 |
Annotations: B |
|
1347.59 | 82.7 |
1348.54 | 9.2 |
Annotations: C^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}Y Y^{1,4}X_{GlcNAc} |
|
1364.61 | 21.8 |
Annotations: C |
|
1365.73 | 9.2 |
1366.57 | 2.5 |
1369.63 | 3.1 |
1370.69 | 4.3 |
1380.06 | 1.9 |
1383.43 | 1.3 |
1385.45 | 4.9 |
1386.66 | 7.0 |
1387.58 | 299.0 |
Annotations: Z |
|
1388.6 | 116.3 |
1389.75 | 7.4 |
Annotations: ^{1,4}X_{Gal} Y^{0,3}X_{GlcNAc} |
|
1402.9 | 5.2 |
1403.82 | 9.4 |
1404.33 | 61.9 |
1404.87 | 120.2 |
1405.6 | 2019.6 |
Annotations: Y |
|
1406.61 | 797.5 |
1407.65 | 41.9 |
1408.38 | 6.3 |
1409.82 | 0.5 |
1460.0 | 0.7 |
Annotations: B^{0,3}X_{GlcNAc} |
|
1461.07 | 6.3 |
Annotations: Z |
|
1461.63 | 71.7 |
Annotations: Z |
|
1462.66 | 35.3 |
1463.64 | 4.7 |
Annotations: C^{2,5}X_{GlcNAc} |
|
1476.72 | 0.9 |
1477.66 | 6.7 |
Annotations: C^{0,3}X_{GlcNAc} ^{1,4}X_{Man} |
|
1478.34 | 29.1 |
1478.96 | 8.9 |
1479.62 | 660.8 |
Annotations: Y |
|
1480.64 | 277.4 |
1481.65 | 21.2 |
1483.08 | 1.0 |
1513.79 | 1.6 |
1531.58 | 5.1 |
1532.69 | 4.3 |
1533.63 | 0.9 |
1546.82 | 1.3 |
1547.62 | 8.1 |
1548.81 | 64.4 |
1549.66 | 1037.7 |
Annotations: B Z |
|
1550.67 | 511.8 |
1551.53 | 33.0 |
Annotations: ^{1,5}X_{NeuAc} |
|
1552.21 | 2.3 |
1561.8 | 0.8 |
1565.35 | 24.8 |
Annotations: ^{2,5}X_{NeuAc} |
|
1565.94 | 69.3 |
Annotations: ^{2,5}X_{NeuAc} |
|
1566.83 | 305.7 |
1567.59 | 6433.5 |
Annotations: C Y |
|
1568.63 | 3135.4 |
1569.63 | 257.7 |
1570.4 | 8.2 |
1571.17 | 1.2 |
1571.75 | 1.4 |