Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
Peak | Intensity |
---|---|
241.15 | 0.9 |
Annotations: ^{1,5}A_{Man}Z |
|
294.47 | 1.3 |
Annotations: YY |
|
309.09 | 0.8 |
313.35 | 1.8 |
314.41 | 1.1 |
327.22 | 0.4 |
348.17 | 2.3 |
Annotations: BZ |
|
349.41 | 2.6 |
350.24 | 140.0 |
Annotations: BY CZ |
|
351.28 | 8.8 |
353.21 | 1.4 |
363.76 | 0.4 |
364.5 | 4.8 |
365.41 | 4.6 |
366.19 | 969.0 |
Annotations: B |
|
367.21 | 72.3 |
Annotations: ^{0,4}A_{Man} |
|
368.22 | 9.9 |
Annotations: CY |
|
381.87 | 1.5 |
384.22 | 3.9 |
Annotations: C |
|
385.13 | 0.8 |
387.23 | 0.9 |
387.86 | 1.3 |
389.31 | 0.8 |
407.32 | 10.5 |
Annotations: Z |
|
423.7 | 1.1 |
425.31 | 7.5 |
Annotations: Y |
|
442.96 | 0.3 |
447.24 | 10.2 |
Annotations: BY CZ ZY YZ |
|
447.86 | 4.8 |
449.02 | 3.2 |
456.28 | 1.1 |
Annotations: YY CY |
|
467.79 | 2.1 |
Annotations: Z |
|
468.29 | 1.6 |
476.18 | 2.0 |
Annotations: ^{1,5}A_{Man}Z |
|
476.77 | 8.6 |
Annotations: Y |
|
477.7 | 0.8 |
486.11 | 1.7 |
Annotations: ^{1,5}A_{Man}Y |
|
503.14 | 1.2 |
510.3 | 3.5 |
Annotations: BZ BZ |
|
511.64 | 1.5 |
Annotations: BZ BZ |
|
512.27 | 601.5 |
Annotations: B |
|
513.28 | 72.2 |
514.21 | 1.2 |
Annotations: ^{1,5}A_{Man}Y |
|
517.33 | 1.3 |
520.42 | 3.8 |
Annotations: BY CZ BY CZ |
|
521.19 | 1.3 |
527.21 | 1.9 |
528.27 | 169.5 |
Annotations: BY CZ BY BY CZ CZ |
|
529.23 | 23.2 |
Annotations: CY CY |
|
530.2 | 0.2 |
Annotations: C |
|
533.15 | 0.3 |
533.9 | 1.1 |
541.09 | 4.5 |
Annotations: ZY YZ |
|
546.36 | 0.5 |
Annotations: CY CY |
|
548.82 | 16.3 |
Annotations: Z |
|
551.34 | 2.7 |
Annotations: ZZ |
|
553.12 | 2.6 |
553.91 | 0.4 |
Annotations: ^{0,4}A_{Man}Z |
|
557.78 | 18.9 |
Annotations: Y |
|
558.44 | 3.0 |
559.35 | 2.1 |
561.84 | 0.1 |
562.35 | 0.9 |
569.33 | 22.2 |
Annotations: ZY YZ |
|
570.37 | 1.9 |
Annotations: ^{0,4}A_{Man}Z |
|
578.34 | 10.5 |
587.25 | 35.9 |
Annotations: YY |
|
588.36 | 9.6 |
Annotations: ^{0,4}A_{Man}Y |
|
601.62 | 6.6 |
Annotations: B |
|
620.93 | 0.1 |
Annotations: BZ ZZ |
|
621.96 | 15.5 |
Annotations: Z |
|
629.85 | 22.8 |
Annotations: BY CZ ZY YZ |
|
630.95 | 25.9 |
Annotations: Y |
|
631.77 | 1.5 |
Annotations: ^{2,5}A_{Man}Y |
|
638.85 | 19.8 |
Annotations: CY YY |
|
639.41 | 2.1 |
641.56 | 0.3 |
Annotations: ZZ |
|
646.1 | 0.2 |
Annotations: ^{1,5}A_{Man} |
|
646.96 | 0.4 |
650.28 | 10.9 |
Annotations: ZY YZ |
|
650.83 | 2.4 |
654.06 | 0.4 |
657.69 | 1.5 |
659.42 | 16.1 |
Annotations: YY |
|
672.09 | 0.6 |
Annotations: BZ |
|
672.83 | 1.8 |
673.52 | 2.3 |
674.37 | 79.3 |
Annotations: B |
|
675.34 | 5.5 |
675.96 | 1.8 |
678.43 | 5.1 |
679.38 | 1.4 |
680.96 | 2.2 |
681.75 | 0.1 |
683.71 | 0.5 |
684.91 | 0.1 |
689.34 | 1.0 |
690.32 | 122.3 |
Annotations: BY CZ |
|
691.29 | 19.6 |
692.19 | 3.5 |
Annotations: C |
|
694.39 | 3.1 |
698.27 | 1.1 |
700.59 | 0.1 |
703.05 | 25.7 |
Annotations: B Z |
|
703.68 | 7.5 |
707.25 | 1.7 |
708.38 | 5.7 |
Annotations: CY |
|
710.75 | 2.6 |
712.04 | 45.5 |
Annotations: C Y |
|
713.43 | 2.8 |
Annotations: BZ ZZ ZZ |
|
715.49 | 13.0 |
720.78 | 0.1 |
721.74 | 6.7 |
723.39 | 12.4 |
Annotations: Z |
|
723.91 | 1.4 |
724.78 | 0.3 |
729.3 | 1.0 |
731.4 | 232.5 |
Annotations: Z |
|
732.41 | 41.7 |
Annotations: Y |
|
733.15 | 9.2 |
734.58 | 0.2 |
Annotations: ^{0,4}A_{Man} |
|
738.95 | 2.5 |
739.6 | 2.9 |
740.46 | 434.7 |
Annotations: Y |
|
740.98 | 20.1 |
741.7 | 0.9 |
742.26 | 1.8 |
743.05 | 0.1 |
744.79 | 5.7 |
745.99 | 1.0 |
747.58 | 2.5 |
748.67 | 7.2 |
Annotations: ^{3,5}A_{Man} |
|
749.37 | 259.0 |
Annotations: CY YY YY |
|
750.33 | 59.5 |
753.4 | 0.4 |
754.46 | 0.1 |
763.36 | 1.4 |
766.0 | 0.8 |
767.82 | 0.3 |
768.33 | 0.3 |
770.53 | 0.1 |
772.35 | 1.4 |
774.5 | 2.2 |
775.69 | 0.1 |
777.11 | 1.1 |
778.18 | 0.3 |
780.55 | 0.1 |
782.83 | 0.2 |
783.88 | 2.1 |
791.35 | 1.1 |
792.45 | 3.5 |
794.8 | 4.6 |
795.96 | 8.3 |
816.3 | 1.0 |
817.28 | 1.4 |
827.25 | 1.7 |
833.11 | 1.1 |
834.36 | 0.6 |
835.5 | 4.3 |
836.43 | 35.6 |
Annotations: BY CZ |
|
837.5 | 11.0 |
838.29 | 0.6 |
839.98 | 2.1 |
852.34 | 8.7 |
853.39 | 0.1 |
854.34 | 2.2 |
Annotations: CY |
|
855.44 | 1.0 |
871.78 | 1.5 |
876.77 | 2.9 |
877.39 | 44.2 |
878.44 | 20.3 |
890.22 | 2.4 |
891.34 | 0.7 |
892.36 | 4.8 |
893.41 | 273.6 |
Annotations: BY CZ ZY YZ |
|
894.48 | 69.9 |
895.46 | 109.9 |
896.46 | 18.5 |
897.25 | 3.8 |
907.82 | 1.2 |
909.89 | 3.9 |
910.68 | 4.8 |
911.4 | 538.5 |
Annotations: CY YY |
|
912.42 | 145.2 |
913.18 | 6.1 |
916.42 | 2.0 |
934.52 | 42.7 |
Annotations: Z |
|
935.48 | 19.7 |
940.77 | 6.4 |
Annotations: ^{2,5}A_{Man}Y |
|
942.46 | 1.3 |
952.42 | 98.1 |
Annotations: Y |
|
953.44 | 22.8 |
998.34 | 8.0 |
Annotations: BY CZ |
|
999.42 | 3.7 |
1000.95 | 0.2 |
1035.32 | 1.6 |
1037.43 | 0.7 |
Annotations: BZ |
|
1038.6 | 2.7 |
1039.5 | 212.2 |
Annotations: BY CZ BY CZ |
|
1040.44 | 66.3 |
1040.98 | 0.1 |
1053.4 | 0.2 |
1054.61 | 2.0 |
1055.46 | 259.8 |
Annotations: BY CZ |
|
1056.5 | 90.6 |
1057.49 | 325.8 |
Annotations: CY CY |
|
1058.5 | 94.1 |
1059.36 | 15.3 |
1060.65 | 2.0 |
1062.66 | 1.2 |
Annotations: ZZ |
|
1072.04 | 1.0 |
1073.37 | 8.2 |
Annotations: CY |
|
1074.51 | 5.8 |
1078.46 | 1.5 |
Annotations: ZZ |
|
1079.6 | 0.2 |
1080.5 | 23.0 |
Annotations: ZY YZ |
|
1081.49 | 8.4 |
1094.97 | 5.6 |
1095.68 | 3.7 |
1096.5 | 256.0 |
Annotations: Z |
|
1097.53 | 76.8 |
1098.48 | 33.8 |
Annotations: YY |
|
1099.37 | 12.0 |
1111.96 | 1.6 |
1112.93 | 11.7 |
1113.74 | 47.7 |
1114.48 | 757.5 |
Annotations: Y |
|
1115.48 | 231.2 |
1116.35 | 15.6 |
1163.37 | 0.7 |
1199.36 | 1.7 |
1200.04 | 6.0 |
1200.76 | 5.9 |
1201.52 | 429.1 |
Annotations: B |
|
1202.54 | 165.6 |
1203.43 | 19.1 |
1203.95 | 0.9 |
1206.04 | 0.6 |
1218.98 | 0.5 |
Annotations: C |
|
1219.52 | 12.8 |
Annotations: C |
|
1220.67 | 7.1 |
1224.33 | 1.6 |
Annotations: BZ ZZ |
|
1234.56 | 0.8 |
1240.47 | 1.1 |
Annotations: BZ ZZ |
|
1241.59 | 6.7 |
1242.56 | 402.5 |
Annotations: Z |
|
1243.58 | 139.3 |
1244.5 | 8.5 |
1256.61 | 1.0 |
1257.87 | 10.3 |
1258.57 | 310.2 |
Annotations: ZY YZ BY CZ |
|
1259.66 | 191.6 |
1260.51 | 1321.0 |
Annotations: Y |
|
1261.53 | 513.8 |
1262.47 | 30.5 |
1263.45 | 4.4 |
1274.11 | 1.9 |
1275.43 | 26.3 |
1276.53 | 774.7 |
Annotations: CY YY |
|
1277.54 | 305.9 |
1278.5 | 15.9 |
1299.8 | 1.5 |
Annotations: ZY YZ |
|
1317.39 | 1.8 |
Annotations: YY |
|
1386.63 | 1.2 |
1387.62 | 1.3 |
1401.3 | 1.2 |
1402.37 | 3.5 |
1403.66 | 36.2 |
1404.61 | 1112.7 |
Annotations: B Z |
|
1405.64 | 481.9 |
1406.55 | 14.1 |
1419.24 | 1.1 |
1420.5 | 4.6 |
1421.16 | 121.5 |
1421.86 | 183.3 |
1422.55 | 5321.5 |
Annotations: C Y |
|
1423.59 | 2212.3 |
1424.52 | 165.7 |
1425.42 | 6.2 |
1427.74 | 1.1 |
1462.08 | 1.3 |
1479.42 | 2.5 |
Annotations: Y |
|
1539.96 | 0.4 |