Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
| Peak | Intensity |
|---|---|
| 241.15 | 0.9 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 294.47 | 1.3 |
|
Annotations: YY |
|
| 309.09 | 0.8 |
| 313.35 | 1.8 |
| 314.41 | 1.1 |
| 327.22 | 0.4 |
| 348.17 | 2.3 |
|
Annotations: BZ |
|
| 349.41 | 2.6 |
| 350.24 | 140.0 |
|
Annotations: BY |
|
| 351.28 | 8.8 |
| 353.21 | 1.4 |
| 363.76 | 0.4 |
| 364.5 | 4.8 |
| 365.41 | 4.6 |
| 366.19 | 969.0 |
|
Annotations: B |
|
| 367.21 | 72.3 |
|
Annotations: ^{0,4}A_{Man} |
|
| 368.22 | 9.9 |
|
Annotations: CY |
|
| 381.87 | 1.5 |
| 384.22 | 3.9 |
|
Annotations: C |
|
| 385.13 | 0.8 |
| 387.23 | 0.9 |
| 387.86 | 1.3 |
| 389.31 | 0.8 |
| 407.32 | 10.5 |
|
Annotations: Z |
|
| 423.7 | 1.1 |
| 425.31 | 7.5 |
|
Annotations: Y |
|
| 442.96 | 0.3 |
| 447.24 | 10.2 |
|
Annotations: BY |
|
| 447.86 | 4.8 |
| 449.02 | 3.2 |
| 456.28 | 1.1 |
|
Annotations: CY |
|
| 467.79 | 2.1 |
|
Annotations: Z |
|
| 468.29 | 1.6 |
| 476.18 | 2.0 |
|
Annotations: ^{1,5}A_{Man}Z |
|
| 476.77 | 8.6 |
|
Annotations: Y |
|
| 477.7 | 0.8 |
| 486.11 | 1.7 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 503.14 | 1.2 |
| 510.3 | 3.5 |
|
Annotations: BZ |
|
| 511.64 | 1.5 |
|
Annotations: BZ |
|
| 512.27 | 601.5 |
|
Annotations: B |
|
| 513.28 | 72.2 |
| 514.21 | 1.2 |
|
Annotations: ^{1,5}A_{Man}Y |
|
| 517.33 | 1.3 |
| 520.42 | 3.8 |
|
Annotations: BY |
|
| 521.19 | 1.3 |
| 527.21 | 1.9 |
| 528.27 | 169.5 |
|
Annotations: BY |
|
| 529.23 | 23.2 |
|
Annotations: CY |
|
| 530.2 | 0.2 |
|
Annotations: C |
|
| 533.15 | 0.3 |
| 533.9 | 1.1 |
| 541.09 | 4.5 |
|
Annotations: ZY |
|
| 546.36 | 0.5 |
|
Annotations: CY |
|
| 548.82 | 16.3 |
|
Annotations: Z |
|
| 551.34 | 2.7 |
|
Annotations: ZZ |
|
| 553.12 | 2.6 |
| 553.91 | 0.4 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 557.78 | 18.9 |
|
Annotations: Y |
|
| 558.44 | 3.0 |
| 559.35 | 2.1 |
| 561.84 | 0.1 |
| 562.35 | 0.9 |
| 569.33 | 22.2 |
|
Annotations: ZY |
|
| 570.37 | 1.9 |
|
Annotations: ^{0,4}A_{Man}Z |
|
| 578.34 | 10.5 |
| 587.25 | 35.9 |
|
Annotations: YY |
|
| 588.36 | 9.6 |
|
Annotations: ^{0,4}A_{Man}Y |
|
| 601.62 | 6.6 |
|
Annotations: B |
|
| 620.93 | 0.1 |
|
Annotations: BZ |
|
| 621.96 | 15.5 |
|
Annotations: Z |
|
| 629.85 | 22.8 |
|
Annotations: BY |
|
| 630.95 | 25.9 |
|
Annotations: Y |
|
| 631.77 | 1.5 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 638.85 | 19.8 |
|
Annotations: CY |
|
| 639.41 | 2.1 |
| 641.56 | 0.3 |
|
Annotations: ZZ |
|
| 646.1 | 0.2 |
|
Annotations: ^{1,5}A_{Man} |
|
| 646.96 | 0.4 |
| 650.28 | 10.9 |
|
Annotations: ZY |
|
| 650.83 | 2.4 |
| 654.06 | 0.4 |
| 657.69 | 1.5 |
| 659.42 | 16.1 |
|
Annotations: YY |
|
| 672.09 | 0.6 |
|
Annotations: BZ |
|
| 672.83 | 1.8 |
| 673.52 | 2.3 |
| 674.37 | 79.3 |
|
Annotations: B |
|
| 675.34 | 5.5 |
| 675.96 | 1.8 |
| 678.43 | 5.1 |
| 679.38 | 1.4 |
| 680.96 | 2.2 |
| 681.75 | 0.1 |
| 683.71 | 0.5 |
| 684.91 | 0.1 |
| 689.34 | 1.0 |
| 690.32 | 122.3 |
|
Annotations: BY |
|
| 691.29 | 19.6 |
| 692.19 | 3.5 |
|
Annotations: C |
|
| 694.39 | 3.1 |
| 698.27 | 1.1 |
| 700.59 | 0.1 |
| 703.05 | 25.7 |
|
Annotations: B |
|
| 703.68 | 7.5 |
| 707.25 | 1.7 |
| 708.38 | 5.7 |
|
Annotations: CY |
|
| 710.75 | 2.6 |
| 712.04 | 45.5 |
|
Annotations: C |
|
| 713.43 | 2.8 |
|
Annotations: BZ |
|
| 715.49 | 13.0 |
| 720.78 | 0.1 |
| 721.74 | 6.7 |
| 723.39 | 12.4 |
|
Annotations: Z |
|
| 723.91 | 1.4 |
| 724.78 | 0.3 |
| 729.3 | 1.0 |
| 731.4 | 232.5 |
|
Annotations: Z |
|
| 732.41 | 41.7 |
|
Annotations: Y |
|
| 733.15 | 9.2 |
| 734.58 | 0.2 |
|
Annotations: ^{0,4}A_{Man} |
|
| 738.95 | 2.5 |
| 739.6 | 2.9 |
| 740.46 | 434.7 |
|
Annotations: Y |
|
| 740.98 | 20.1 |
| 741.7 | 0.9 |
| 742.26 | 1.8 |
| 743.05 | 0.1 |
| 744.79 | 5.7 |
| 745.99 | 1.0 |
| 747.58 | 2.5 |
| 748.67 | 7.2 |
|
Annotations: ^{3,5}A_{Man} |
|
| 749.37 | 259.0 |
|
Annotations: CY |
|
| 750.33 | 59.5 |
| 753.4 | 0.4 |
| 754.46 | 0.1 |
| 763.36 | 1.4 |
| 766.0 | 0.8 |
| 767.82 | 0.3 |
| 768.33 | 0.3 |
| 770.53 | 0.1 |
| 772.35 | 1.4 |
| 774.5 | 2.2 |
| 775.69 | 0.1 |
| 777.11 | 1.1 |
| 778.18 | 0.3 |
| 780.55 | 0.1 |
| 782.83 | 0.2 |
| 783.88 | 2.1 |
| 791.35 | 1.1 |
| 792.45 | 3.5 |
| 794.8 | 4.6 |
| 795.96 | 8.3 |
| 816.3 | 1.0 |
| 817.28 | 1.4 |
| 827.25 | 1.7 |
| 833.11 | 1.1 |
| 834.36 | 0.6 |
| 835.5 | 4.3 |
| 836.43 | 35.6 |
|
Annotations: BY |
|
| 837.5 | 11.0 |
| 838.29 | 0.6 |
| 839.98 | 2.1 |
| 852.34 | 8.7 |
| 853.39 | 0.1 |
| 854.34 | 2.2 |
|
Annotations: CY |
|
| 855.44 | 1.0 |
| 871.78 | 1.5 |
| 876.77 | 2.9 |
| 877.39 | 44.2 |
| 878.44 | 20.3 |
| 890.22 | 2.4 |
| 891.34 | 0.7 |
| 892.36 | 4.8 |
| 893.41 | 273.6 |
|
Annotations: BY |
|
| 894.48 | 69.9 |
| 895.46 | 109.9 |
| 896.46 | 18.5 |
| 897.25 | 3.8 |
| 907.82 | 1.2 |
| 909.89 | 3.9 |
| 910.68 | 4.8 |
| 911.4 | 538.5 |
|
Annotations: CY |
|
| 912.42 | 145.2 |
| 913.18 | 6.1 |
| 916.42 | 2.0 |
| 934.52 | 42.7 |
|
Annotations: Z |
|
| 935.48 | 19.7 |
| 940.77 | 6.4 |
|
Annotations: ^{2,5}A_{Man}Y |
|
| 942.46 | 1.3 |
| 952.42 | 98.1 |
|
Annotations: Y |
|
| 953.44 | 22.8 |
| 998.34 | 8.0 |
|
Annotations: BY |
|
| 999.42 | 3.7 |
| 1000.95 | 0.2 |
| 1035.32 | 1.6 |
| 1037.43 | 0.7 |
|
Annotations: BZ |
|
| 1038.6 | 2.7 |
| 1039.5 | 212.2 |
|
Annotations: BY |
|
| 1040.44 | 66.3 |
| 1040.98 | 0.1 |
| 1053.4 | 0.2 |
| 1054.61 | 2.0 |
| 1055.46 | 259.8 |
|
Annotations: BY |
|
| 1056.5 | 90.6 |
| 1057.49 | 325.8 |
|
Annotations: CY |
|
| 1058.5 | 94.1 |
| 1059.36 | 15.3 |
| 1060.65 | 2.0 |
| 1062.66 | 1.2 |
|
Annotations: ZZ |
|
| 1072.04 | 1.0 |
| 1073.37 | 8.2 |
|
Annotations: CY |
|
| 1074.51 | 5.8 |
| 1078.46 | 1.5 |
|
Annotations: ZZ |
|
| 1079.6 | 0.2 |
| 1080.5 | 23.0 |
|
Annotations: ZY |
|
| 1081.49 | 8.4 |
| 1094.97 | 5.6 |
| 1095.68 | 3.7 |
| 1096.5 | 256.0 |
|
Annotations: Z |
|
| 1097.53 | 76.8 |
| 1098.48 | 33.8 |
|
Annotations: YY |
|
| 1099.37 | 12.0 |
| 1111.96 | 1.6 |
| 1112.93 | 11.7 |
| 1113.74 | 47.7 |
| 1114.48 | 757.5 |
|
Annotations: Y |
|
| 1115.48 | 231.2 |
| 1116.35 | 15.6 |
| 1163.37 | 0.7 |
| 1199.36 | 1.7 |
| 1200.04 | 6.0 |
| 1200.76 | 5.9 |
| 1201.52 | 429.1 |
|
Annotations: B |
|
| 1202.54 | 165.6 |
| 1203.43 | 19.1 |
| 1203.95 | 0.9 |
| 1206.04 | 0.6 |
| 1218.98 | 0.5 |
|
Annotations: C |
|
| 1219.52 | 12.8 |
|
Annotations: C |
|
| 1220.67 | 7.1 |
| 1224.33 | 1.6 |
|
Annotations: BZ |
|
| 1234.56 | 0.8 |
| 1240.47 | 1.1 |
|
Annotations: BZ |
|
| 1241.59 | 6.7 |
| 1242.56 | 402.5 |
|
Annotations: Z |
|
| 1243.58 | 139.3 |
| 1244.5 | 8.5 |
| 1256.61 | 1.0 |
| 1257.87 | 10.3 |
| 1258.57 | 310.2 |
|
Annotations: BY |
|
| 1259.66 | 191.6 |
| 1260.51 | 1321.0 |
|
Annotations: Y |
|
| 1261.53 | 513.8 |
| 1262.47 | 30.5 |
| 1263.45 | 4.4 |
| 1274.11 | 1.9 |
| 1275.43 | 26.3 |
| 1276.53 | 774.7 |
|
Annotations: CY |
|
| 1277.54 | 305.9 |
| 1278.5 | 15.9 |
| 1299.8 | 1.5 |
|
Annotations: ZY |
|
| 1317.39 | 1.8 |
|
Annotations: YY |
|
| 1386.63 | 1.2 |
| 1387.62 | 1.3 |
| 1401.3 | 1.2 |
| 1402.37 | 3.5 |
| 1403.66 | 36.2 |
| 1404.61 | 1112.7 |
|
Annotations: B |
|
| 1405.64 | 481.9 |
| 1406.55 | 14.1 |
| 1419.24 | 1.1 |
| 1420.5 | 4.6 |
| 1421.16 | 121.5 |
| 1421.86 | 183.3 |
| 1422.55 | 5321.5 |
|
Annotations: C |
|
| 1423.59 | 2212.3 |
| 1424.52 | 165.7 |
| 1425.42 | 6.2 |
| 1427.74 | 1.1 |
| 1462.08 | 1.3 |
| 1479.42 | 2.5 |
|
Annotations: Y |
|
| 1539.96 | 0.4 |