Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library
Peak | Intensity |
---|---|
163.1 | 38.2 |
Annotations: B |
|
168.05 | 43.2 |
182.9 | 0.6 |
184.14 | 0.3 |
Annotations: Y |
|
185.12 | 6.3 |
186.07 | 2077.2 |
Annotations: BZ ZZ |
|
187.14 | 204.5 |
188.12 | 1.2 |
195.99 | 0.4 |
199.03 | 0.5 |
200.09 | 0.3 |
200.8 | 0.1 |
202.03 | 22.2 |
202.78 | 85.2 |
204.01 | 52364.3 |
Annotations: B |
|
205.06 | 3244.8 |
Annotations: ^{1,3}A_{Man}Z ^{2,4}A_{Man}Z |
|
205.92 | 38.2 |
Annotations: ^{2,5}A_{Man}Z |
|
206.45 | 5.6 |
Annotations: ^{2,5}A_{Man}Z |
|
207.16 | 0.3 |
208.09 | 24.0 |
209.04 | 0.8 |
210.42 | 0.6 |
213.94 | 0.1 |
Annotations: ^{2,4}A_{Man} ^{1,3}A_{Man} ^{0,2}A_{Man}Z |
|
217.1 | 1.6 |
218.01 | 0.8 |
219.0 | 22.0 |
220.19 | 0.3 |
221.19 | 11.0 |
Annotations: ^{1,5}A_{Man}Z |
|
222.12 | 1560.0 |
Annotations: C |
|
223.05 | 34.0 |
Annotations: ^{0,2}A_{Man}Y ^{0,4}A_{Man} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y |
|
223.98 | 1.2 |
227.25 | 0.8 |
228.01 | 47.0 |
229.05 | 9.8 |
Annotations: ^{1,4}A_{Man} |
|
230.1 | 0.9 |
Annotations: ^{1,5}A_{Man}Y |
|
232.1 | 0.3 |
233.31 | 0.1 |
234.83 | 0.4 |
Annotations: BZ |
|
235.97 | 0.1 |
237.04 | 0.4 |
Annotations: ^{3,5}A_{Man} |
|
238.19 | 1.0 |
239.09 | 0.1 |
240.08 | 1.6 |
241.12 | 1.1 |
242.97 | 0.1 |
244.0 | 1.8 |
Annotations: BY CZ |
|
244.92 | 0.5 |
245.99 | 13.1 |
247.19 | 0.5 |
250.01 | 0.5 |
252.09 | 0.2 |
253.46 | 0.1 |
Annotations: CY |
|
254.21 | 0.3 |
255.11 | 0.5 |
Annotations: BZ BZ |
|
255.63 | 82.1 |
Annotations: BZ BZ |
|
257.95 | 0.2 |
259.16 | 0.2 |
260.07 | 0.4 |
261.11 | 0.5 |
262.14 | 0.6 |
263.16 | 1.2 |
263.89 | 0.1 |
Annotations: ^{1,3}A_{Man} |
|
265.17 | 0.2 |
267.06 | 8.8 |
267.99 | 0.2 |
269.06 | 1.2 |
270.1 | 66.6 |
272.34 | 62.3 |
275.12 | 0.1 |
276.11 | 0.4 |
278.15 | 0.4 |
279.1 | 0.1 |
280.26 | 0.1 |
283.54 | 0.5 |
284.12 | 1.6 |
285.13 | 0.5 |
286.08 | 1.0 |
Annotations: Y |
|
287.07 | 1.3 |
288.21 | 12.1 |
290.04 | 4.0 |
291.14 | 79.9 |
292.13 | 0.2 |
294.09 | 1.9 |
Annotations: ^{1,4}A_{Man} |
|
294.83 | 0.1 |
296.1 | 25.3 |
296.95 | 3.8 |
299.98 | 0.9 |
300.99 | 0.3 |
302.1 | 0.3 |
305.14 | 0.2 |
306.02 | 3.6 |
307.26 | 4.5 |
Annotations: BZ |
|
308.23 | 2.1 |
309.03 | 44.0 |
309.73 | 0.4 |
310.9 | 0.3 |
312.27 | 0.3 |
312.98 | 5.4 |
314.04 | 2.2 |
314.61 | 819.9 |
315.2 | 5.4 |
315.99 | 1.5 |
317.75 | 1.6 |
318.99 | 29.8 |
320.2 | 1.6 |
321.0 | 0.5 |
321.94 | 24.4 |
324.1 | 0.9 |
324.82 | 61.6 |
Annotations: BY CZ |
|
326.11 | 28.3 |
327.12 | 21.7 |
328.05 | 1.2 |
329.01 | 1.9 |
330.17 | 66.1 |
331.27 | 6.0 |
Annotations: ^{1,5}A_{Man} |
|
332.17 | 10.8 |
333.1 | 0.3 |
334.16 | 0.5 |
336.95 | 0.6 |
Annotations: BZ |
|
338.22 | 1.1 |
Annotations: ^{1,5}A_{Man} |
|
338.98 | 0.8 |
340.18 | 0.5 |
341.05 | 0.1 |
341.9 | 1.6 |
342.61 | 28.5 |
343.2 | 54.4 |
Annotations: CY |
|
344.52 | 1.1 |
345.95 | 0.1 |
Annotations: B |
|
347.09 | 7.0 |
348.1 | 146.6 |
348.73 | 13.7 |
Annotations: ZZ |
|
349.27 | 135.2 |
Annotations: ZZ |
|
350.14 | 9012.9 |
Annotations: Z |
|
351.11 | 1211.9 |
351.66 | 45.4 |
353.17 | 0.6 |
354.0 | 1.0 |
355.82 | 1.0 |
357.01 | 0.6 |
Annotations: BZ ZZ |
|
358.27 | 0.6 |
Annotations: YZ ZY |
|
359.04 | 3.3 |
359.97 | 1.8 |
360.87 | 0.1 |
363.1 | 2.0 |
363.93 | 56.8 |
364.53 | 1.1 |
365.22 | 25.1 |
366.15 | 9833.2 |
Annotations: B |
|
367.25 | 1231.0 |
Annotations: YY |
|
368.16 | 1198.0 |
Annotations: Y |
|
369.14 | 161.4 |
370.05 | 1.3 |
371.03 | 0.4 |
373.4 | 0.7 |
374.08 | 0.2 |
375.15 | 5.8 |
Annotations: CY YY |
|
376.02 | 0.4 |
377.15 | 2.6 |
378.07 | 0.7 |
380.1 | 0.1 |
382.12 | 0.2 |
383.16 | 0.6 |
384.15 | 168.7 |
Annotations: C |
|
384.89 | 1.2 |
385.92 | 0.3 |
386.76 | 123.3 |
387.72 | 388.8 |
388.31 | 0.4 |
389.11 | 0.1 |
Annotations: ZZ |
|
390.21 | 0.6 |
392.26 | 2.1 |
393.52 | 2.4 |
394.85 | 9.9 |
395.76 | 2434.2 |
396.75 | 146.8 |
398.16 | 0.9 |
399.07 | 1.2 |
400.15 | 0.8 |
401.03 | 0.7 |
402.14 | 1.7 |
402.98 | 9.5 |
404.18 | 7.1 |
405.29 | 5.8 |
406.04 | 2.2 |
407.19 | 379.4 |
Annotations: YZ ZY |
|
408.27 | 65.9 |
409.18 | 2.4 |
410.17 | 0.5 |
411.07 | 0.9 |
Annotations: ^{2,5}A_{Man}Z |
|
411.92 | 0.7 |
413.16 | 1.7 |
414.21 | 3.1 |
415.04 | 0.6 |
417.27 | 0.9 |
421.31 | 5.8 |
422.15 | 0.5 |
422.75 | 30.5 |
423.78 | 0.3 |
424.44 | 55.9 |
425.23 | 1654.9 |
Annotations: YY |
|
426.27 | 256.4 |
Annotations: ^{1,3}A_{Man} ^{2,4}A_{Man} |
|
427.0 | 233.0 |
Annotations: ^{0,2}A_{Man}Z |
|
428.0 | 28.8 |
429.02 | 5.6 |
Annotations: ^{2,5}A_{Man}Y |
|
430.32 | 5.8 |
Annotations: ZZ |
|
431.45 | 1.9 |
432.12 | 0.6 |
434.08 | 1.8 |
435.18 | 4.2 |
436.22 | 2.9 |
437.2 | 0.7 |
438.2 | 35.7 |
Annotations: ZZ |
|
438.97 | 0.9 |
Annotations: Z |
|
439.57 | 166.9 |
Annotations: Z |
|
440.15 | 2.9 |
441.22 | 1.9 |
Annotations: ^{1,5}A_{Man}Z |
|
442.11 | 2.3 |
442.98 | 1.1 |
443.84 | 0.8 |
445.23 | 0.9 |
Annotations: ^{0,2}A_{Man}Y |
|
446.13 | 0.8 |
447.32 | 772.5 |
Annotations: B |
|
448.15 | 26.7 |
Annotations: Y |
|
449.07 | 0.6 |
450.24 | 10.7 |
451.13 | 7.0 |
452.13 | 4.8 |
453.03 | 0.2 |
454.26 | 0.6 |
455.2 | 0.7 |
456.33 | 272.2 |
Annotations: C |
|
456.91 | 14.3 |
457.95 | 0.9 |
458.51 | 3.5 |
Annotations: ZZ |
|
459.58 | 6.6 |
Annotations: ^{1,5}A_{Man}Y |
|
460.27 | 0.6 |
461.27 | 1.2 |
462.16 | 0.6 |
463.17 | 0.6 |
464.32 | 0.5 |
465.03 | 0.3 |
466.12 | 13.7 |
467.11 | 5.3 |
467.85 | 2499.0 |
Annotations: YZ ZY |
|
468.8 | 671.4 |
Annotations: BZ |
|
469.45 | 33.1 |
Annotations: BZ |
|
470.44 | 56.9 |
471.38 | 4.6 |
471.99 | 1.1 |
472.95 | 1.5 |
474.22 | 1.7 |
474.87 | 0.4 |
475.47 | 40.4 |
476.78 | 7536.8 |
Annotations: YY |
|
477.56 | 719.8 |
478.58 | 2.4 |
479.24 | 7.1 |
479.81 | 58.3 |
480.32 | 0.6 |
481.03 | 0.6 |
481.87 | 1.3 |
482.79 | 30.3 |
483.38 | 15.9 |
484.19 | 1.1 |
485.09 | 1.8 |
485.82 | 7.8 |
486.4 | 3.1 |
486.97 | 105.0 |
Annotations: BY CZ |
|
487.93 | 62.4 |
488.64 | 0.9 |
489.16 | 0.6 |
490.25 | 3.7 |
492.11 | 4.0 |
492.9 | 1.0 |
494.28 | 18.7 |
494.99 | 6.8 |
495.96 | 0.7 |
496.7 | 3.1 |
497.31 | 0.3 |
498.26 | 8.9 |
499.04 | 2.1 |
500.11 | 6.8 |
501.18 | 3.0 |
501.95 | 2.6 |
502.48 | 1.6 |
502.99 | 0.3 |
503.71 | 1.1 |
504.77 | 43.0 |
Annotations: CY |
|
505.61 | 7.7 |
Annotations: CY |
|
507.35 | 1.9 |
508.4 | 1.0 |
509.17 | 18.9 |
510.22 | 135.8 |
Annotations: BZ BZ |
|
511.17 | 28.5 |
512.17 | 867.9 |
513.27 | 259.6 |
513.96 | 1.4 |
514.97 | 4.5 |
516.19 | 3.1 |
517.23 | 2.0 |
518.42 | 23.0 |
519.51 | 1.5 |
520.23 | 827.6 |
Annotations: Z |
|
520.74 | 4.2 |
521.3 | 1.3 |
521.95 | 1.6 |
522.95 | 0.2 |
524.27 | 1.3 |
525.58 | 4.3 |
526.38 | 65.9 |
527.23 | 131.5 |
528.19 | 15331.4 |
Annotations: BY CZ BY CZ |
|
529.18 | 2210.0 |
Annotations: Y |
|
530.23 | 239.8 |
531.16 | 1.3 |
532.04 | 12.1 |
533.08 | 12.6 |
534.21 | 22.5 |
535.28 | 64.4 |
536.35 | 2.0 |
536.94 | 0.8 |
537.61 | 47.0 |
538.24 | 21.6 |
539.08 | 19.9 |
539.77 | 47.5 |
540.99 | 518.6 |
Annotations: Z |
|
542.18 | 2.8 |
543.24 | 0.6 |
544.35 | 0.3 |
545.07 | 0.3 |
546.14 | 81.3 |
Annotations: CY CY |
|
547.76 | 46.9 |
548.89 | 3717.2 |
Annotations: Z |
|
549.8 | 1730.0 |
Annotations: Y |
|
550.44 | 18.8 |
551.24 | 35.4 |
552.01 | 1.1 |
553.36 | 72.3 |
Annotations: Z |
|
554.09 | 4.4 |
554.91 | 0.3 |
556.18 | 1.0 |
556.82 | 321.5 |
557.78 | 7131.9 |
Annotations: Y |
|
558.3 | 383.7 |
559.61 | 38.3 |
560.21 | 2.0 |
561.15 | 0.5 |
561.74 | 2.4 |
562.73 | 10.5 |
563.6 | 7.2 |
566.09 | 1.3 |
566.68 | 13.5 |
567.4 | 0.8 |
568.3 | 97.4 |
569.28 | 693.5 |
570.23 | 229.6 |
571.29 | 419.0 |
Annotations: Y |
|
572.23 | 91.5 |
573.28 | 1.5 |
573.99 | 1.7 |
574.89 | 1.4 |
575.6 | 0.9 |
576.3 | 1.1 |
576.87 | 5.8 |
578.28 | 2.6 |
579.37 | 1.6 |
580.11 | 10.1 |
581.29 | 0.7 |
582.05 | 0.4 |
582.98 | 2.4 |
583.98 | 10.8 |
585.04 | 10.9 |
586.1 | 138.9 |
587.22 | 4384.0 |
588.19 | 647.0 |
588.88 | 58.9 |
589.74 | 3.4 |
590.43 | 2.1 |
591.39 | 1.8 |
592.43 | 2.4 |
594.03 | 4.0 |
595.16 | 6.4 |
596.22 | 8.7 |
597.31 | 2.0 |
598.17 | 2.7 |
599.32 | 3.7 |
599.88 | 0.5 |
601.03 | 14.3 |
602.3 | 4.0 |
603.44 | 21.1 |
604.56 | 5.9 |
605.3 | 2.1 |
605.84 | 0.7 |
606.5 | 4.6 |
607.34 | 5.3 |
608.14 | 5.1 |
608.73 | 1.6 |
610.33 | 31.8 |
611.31 | 26.3 |
612.28 | 38.3 |
613.1 | 118.9 |
614.13 | 15.2 |
615.17 | 12.3 |
616.61 | 1.9 |
618.41 | 1.1 |
620.01 | 2.3 |
621.02 | 92.9 |
621.82 | 220.1 |
622.46 | 75.7 |
623.35 | 3.2 |
628.47 | 42.8 |
629.47 | 3.7 |
630.24 | 22.4 |
632.05 | 1.4 |
Annotations: ^{2,5}A_{Man} |
|
632.74 | 0.7 |
637.09 | 1.1 |
638.19 | 49.9 |
639.31 | 71.4 |
648.85 | 0.3 |
650.76 | 63.1 |
651.42 | 25.3 |
652.01 | 0.5 |
652.66 | 0.4 |
654.16 | 1.2 |
656.39 | 37.4 |
662.35 | 13.7 |
Annotations: ^{1,5}A_{Man} |
|
670.66 | 0.5 |
672.4 | 135.1 |
Annotations: BZ |
|
673.03 | 6.5 |
673.55 | 0.6 |
674.26 | 4963.7 |
675.3 | 833.5 |
676.24 | 3.3 |
679.01 | 2.5 |
679.62 | 2.8 |
680.28 | 1.0 |
687.94 | 69.3 |
689.02 | 414.2 |
689.63 | 0.6 |
690.24 | 24420.4 |
Annotations: B |
|
691.28 | 5193.5 |
692.27 | 268.8 |
692.91 | 84.9 |
694.41 | 0.2 |
695.53 | 0.6 |
696.37 | 4.7 |
707.55 | 4.7 |
708.31 | 231.4 |
Annotations: C |
|
709.33 | 126.4 |
710.34 | 9.7 |
711.32 | 3.9 |
712.31 | 0.1 |
713.24 | 57.2 |
Annotations: BZ ZZ |
|
714.38 | 26.7 |
715.38 | 142.3 |
Annotations: ZY YZ |
|
716.23 | 57.1 |
716.88 | 1.6 |
729.28 | 1.6 |
729.92 | 72.3 |
730.45 | 1.8 |
731.28 | 4697.3 |
Annotations: BY CZ YZ ZY |
|
732.34 | 1198.5 |
733.31 | 2845.6 |
Annotations: YY |
|
734.3 | 393.8 |
734.85 | 0.6 |
735.43 | 0.2 |
737.9 | 0.1 |
746.63 | 46.9 |
747.56 | 222.6 |
748.57 | 667.2 |
749.28 | 19982.4 |
Annotations: CY YY |
|
750.28 | 4326.8 |
751.09 | 184.9 |
752.11 | 5.9 |
760.33 | 0.5 |
763.22 | 1.8 |
769.09 | 0.7 |
771.34 | 0.4 |
772.4 | 26.6 |
773.38 | 20.5 |
774.29 | 58.0 |
775.24 | 50.7 |
775.81 | 0.3 |
777.22 | 0.1 |
781.34 | 0.4 |
782.24 | 1.0 |
787.22 | 0.5 |
788.22 | 1.0 |
789.48 | 5.6 |
790.32 | 948.5 |
791.28 | 62.3 |
791.87 | 0.6 |
794.9 | 1.8 |
797.35 | 0.4 |
800.43 | 0.5 |
803.2 | 0.2 |
810.41 | 0.2 |
815.48 | 1.4 |
816.15 | 3.5 |
817.6 | 10.1 |
818.27 | 93.6 |
822.21 | 0.5 |
825.69 | 15.8 |
831.05 | 0.1 |
833.74 | 1.2 |
834.54 | 157.3 |
835.56 | 173.3 |
836.3 | 12869.8 |
837.32 | 3623.1 |
838.2 | 291.3 |
838.73 | 0.6 |
839.81 | 28.8 |
841.46 | 0.1 |
842.27 | 0.6 |
844.21 | 0.3 |
849.45 | 0.9 |
851.67 | 1.8 |
852.49 | 3.6 |
853.52 | 0.9 |
854.32 | 234.2 |
855.41 | 5.4 |
856.22 | 3.0 |
857.32 | 25.7 |
859.17 | 1.4 |
Annotations: ZZ |
|
863.43 | 0.3 |
871.34 | 1.4 |
872.85 | 10.4 |
873.73 | 15.9 |
874.5 | 1.1 |
875.31 | 17.7 |
Annotations: ZZ |
|
875.82 | 0.3 |
876.39 | 220.3 |
877.35 | 5590.4 |
Annotations: Z |
|
878.34 | 1638.5 |
879.37 | 120.4 |
889.26 | 0.3 |
890.51 | 0.2 |
891.44 | 45.9 |
892.23 | 168.3 |
893.34 | 11945.2 |
Annotations: B |
|
894.43 | 3584.8 |
895.3 | 32744.9 |
Annotations: Y |
|
896.32 | 6794.4 |
897.23 | 294.6 |
898.43 | 42.2 |
906.44 | 0.1 |
908.08 | 0.4 |
908.97 | 31.9 |
909.93 | 258.4 |
910.64 | 731.5 |
911.31 | 38278.6 |
Annotations: C |
|
912.34 | 8615.8 |
913.25 | 449.0 |
915.22 | 0.6 |
916.19 | 0.2 |
Annotations: ZZ |
|
917.38 | 1.5 |
920.13 | 0.5 |
931.31 | 4.1 |
933.27 | 5.8 |
934.42 | 179.5 |
Annotations: YZ ZY |
|
935.36 | 1.1 |
936.2 | 23.6 |
937.49 | 89.0 |
938.01 | 0.2 |
940.61 | 1.5 |
950.44 | 0.4 |
951.02 | 59.4 |
952.43 | 302.6 |
Annotations: YY |
|
953.38 | 107.9 |
954.41 | 2.1 |
954.99 | 0.1 |
956.25 | 33.2 |
958.2 | 0.5 |
963.47 | 0.3 |
964.4 | 0.6 |
990.37 | 0.3 |
991.27 | 0.4 |
997.31 | 0.2 |
998.18 | 1.3 |
999.34 | 0.1 |
1000.34 | 0.1 |
1003.47 | 33.1 |
1004.21 | 1.1 |
1005.4 | 2.3 |
1006.47 | 0.5 |
1015.53 | 0.2 |
1017.43 | 0.2 |
1019.45 | 0.4 |
1020.7 | 0.1 |
1021.37 | 7.2 |
1022.41 | 39.9 |
1029.45 | 0.2 |
1030.18 | 1.0 |
1031.28 | 2.4 |
1032.26 | 1.1 |
1033.36 | 0.3 |
1036.38 | 0.7 |
1037.56 | 6.8 |
1038.43 | 555.2 |
1039.36 | 13878.2 |
Annotations: Z |
|
1040.39 | 4127.6 |
1041.39 | 255.7 |
1045.24 | 0.5 |
1054.1 | 48.3 |
1054.77 | 50.0 |
1055.35 | 1207.4 |
1056.42 | 5527.7 |
1057.34 | 120241.6 |
Annotations: Y |
|
1058.35 | 42910.9 |
1059.38 | 2492.7 |
1059.99 | 170.8 |
1060.56 | 8.0 |
1061.36 | 0.3 |
1062.15 | 17.7 |
1066.55 | 1.7 |
1071.4 | 0.9 |
1072.46 | 49.6 |
1074.38 | 11.3 |
1075.43 | 14.0 |
1077.31 | 1.5 |
1078.49 | 0.5 |
1080.35 | 0.5 |
Annotations: Z |
|
1081.4 | 0.2 |
1082.41 | 0.3 |
1087.23 | 2.2 |
1091.88 | 0.6 |
1093.4 | 3.0 |
1095.83 | 1.0 |
1096.46 | 154.6 |
Annotations: Z |
|
1097.37 | 96.3 |
1098.47 | 2.1 |
Annotations: Y |
|
1099.44 | 17.9 |
1108.23 | 0.2 |
1113.48 | 32.3 |
1114.43 | 496.3 |
Annotations: Y |
|
1115.49 | 308.2 |
1116.42 | 41.4 |
1125.36 | 0.7 |
1126.64 | 0.7 |
1127.31 | 0.9 |
1129.27 | 0.5 |
1136.53 | 2.0 |
1151.14 | 0.2 |
1156.31 | 0.4 |
1178.54 | 0.2 |
1181.49 | 0.9 |
1222.42 | 0.1 |
1224.22 | 0.6 |
1237.5 | 0.2 |
1238.59 | 0.9 |
1239.57 | 0.3 |
1240.42 | 0.5 |
1241.38 | 0.7 |
There are not related spectra