Negative ion CID fragmentation of O-linked oligosaccharides aldoses-charge induced and charge remote fragmentation

PubMed Entry

GlyToucan Accession Number: G52120NK

Peak Intensity
191.8 408.0

Annotations:

YY
193.9 2123.0

Annotations:

ZZ
200.3 498.0
201.9 952.0

Annotations:

BY CZ
203.8 2462.0

Annotations:

YZ ZY
209.7 285.0
211.6 438.0

Annotations:

YY
214.7 1228.0
231.6 1328.0

Annotations:

B^{0,3}X_{NeuAc} Z^{2,5}X_{GlcNAc} ^{1,5}X_{Gal}Z Z^{1,5}X_{GlcNAc} ^{2,5}X_{Gal}Z Z^{2,5}X_{Gal}
242.9 656.0
244.6 2718.0
257.9 1751.0
261.1 1049.0

Annotations:

B^{0,3}X_{NeuAc} B^{0,3}X_{NeuAc}
262.8 571.0

Annotations:

^{3,5}A_{GlcNAc} ^{0,2}A_{GlcNAc}Z Y^{2,4}X_{GlcNAc} ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Gal} Y^{2,4}X_{Gal}
270.1 1314.0

Annotations:

^{0,3}A_{GlcNAc} ^{1,4}X_{NeuAc}Z
271.1 492.0
271.9 3590.0
287.8 4516.0
289.9 297772.0

Annotations:

B
290.9 37054.0

Annotations:

^{1,4}A_{GlcNAc}
291.9 3771.0

Annotations:

C^{1,4}X_{Gal} ^{1,4}A_{GlcNAc}Y
293.1 503.0

Annotations:

YY YY
303.9 3773.0

Annotations:

B^{1,3}X_{Gal} B^{2,4}X_{Gal}
315.7 414.0
319.0 476.0

Annotations:

^{0,2}X_{NeuAc}Z Z^{0,2}X_{NeuAc}
338.1 300.0
339.8 461.0
347.1 1408.0

Annotations:

Z^{2,4}X_{GlcNAc}
363.9 1186.0

Annotations:

BY CZ
366.0 1762.0

Annotations:

YZ ZY
383.0 1099.0
383.9 1732.0

Annotations:

YY
385.9 3004.0
386.8 1657.0

Annotations:

^{2,5}X_{GlcNAc}
389.0 4867.0

Annotations:

ZZ
401.2 3392.0

Annotations:

^{1,5}X_{NeuAc}Z Z^{1,5}X_{NeuAc} ^{3,5}X_{GlcNAc}
406.7 1009.0

Annotations:

YZ ZY
407.1 1194.0

Annotations:

YZ ZY
408.0 3571.0

Annotations:

^{2,5}X_{NeuAc}Z Z^{2,5}X_{NeuAc} ^{1,3}X_{NeuAc}Z Z^{1,3}X_{NeuAc} B^{1,3}X_{NeuAc} B^{1,3}X_{NeuAc}
408.4 2203.0

Annotations:

B^{1,3}X_{NeuAc} B^{1,3}X_{NeuAc} ^{2,5}X_{NeuAc}Z Z^{2,5}X_{NeuAc} ^{2,4}X_{GlcNAc}
409.1 7136.0

Annotations:

^{2,4}X_{GlcNAc} ^{0,2}X_{NeuAc}Y Y^{0,2}X_{NeuAc}
416.0 332.0
421.8 905.0
433.9 1094.0

Annotations:

B^{0,2}X_{NeuAc}
438.5 921.0

Annotations:

Y Y
439.2 1605.0
439.9 1875.0
446.4 807.0
448.2 535.0
456.0 510.0

Annotations:

^{1,5}X_{NeuAc}Y Y^{1,4}X_{GlcNAc}
464.8 568.0

Annotations:

Z^{2,5}X_{GlcNAc} ^{2,5}X_{Gal}Z Z^{2,5}X_{Gal}
467.1 893.0

Annotations:

Y^{0,2}X_{GlcNAc} ^{0,2}X_{Gal}Y Y^{0,2}X_{Gal}
469.1 587.0

Annotations:

^{2,4}X_{NeuAc}Y Y^{2,4}X_{NeuAc}
470.1 6907.0

Annotations:

C C
474.3 642.0

Annotations:

^{1,4}X_{Gal} ^{1,4}X_{Gal}
479.9 395.0

Annotations:

B^{3,5}X_{NeuAc}
504.1 1589.0
508.7 846.0

Annotations:

Z^{2,4}X_{GlcNAc} ^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z Z^{1,3}X_{Gal} Z^{2,4}X_{Gal}
510.5 841.0

Annotations:

Z Z
512.5 421.0

Annotations:

^{2,4}A_{GlcNAc}
514.0 666.0
517.9 544.0
519.5 354.0

Annotations:

Y Y
525.0 384.0
527.9 396.0
529.2 1031.0
532.7 461.0
534.4 901.0
548.3 293.0
549.1 728.0
551.1 572.0

Annotations:

ZZ ZZ
552.1 423.0
554.6 3141.0

Annotations:

B^{2,4}X_{NeuAc} ^{0,2}X_{NeuAc} ^{0,2}X_{NeuAc}
555.2 2789.0

Annotations:

^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc} ^{0,4}X_{NeuAc}Y
567.0 2416.0
567.4 889.0
569.1 1.0

Annotations:

YZ ZY YZ ZY
570.2 7100.0
581.1 342.0
581.6 398.0
583.1 416.0

Annotations:

^{1,4}A_{GlcNAc}
584.1 3549.0
585.2 572.0
587.1 1.0

Annotations:

YY YY
588.1 4161.0
589.0 658.0
594.2 478.0
595.2 517.0
598.2 708.0
603.0 389.0
605.5 983.0

Annotations:

^{0,4}X_{NeuAc} ^{0,4}X_{NeuAc}
611.0 1884.0

Annotations:

B^{1,3}X_{NeuAc} Z^{0,2}X_{Gal} ^{0,2}X_{Gal}Z
623.3 688.0
624.1 287.0
629.0 1969.0

Annotations:

C^{1,3}X_{NeuAc} Y^{0,2}X_{Gal} ^{0,2}X_{Gal}Y
631.3 569.0

Annotations:

^{1,3}X_{NeuAc}Y
633.0 559.0
633.4 4745.0
633.9 2258.0
634.9 5521.0
636.3 913.0
637.2 2267.0
638.9 416.0

Annotations:

^{0,2}X_{NeuAc}Z Z^{0,2}X_{NeuAc}
642.1 338.0
643.5 8256.0

Annotations:

^{1,3}X_{NeuAc} ^{1,3}X_{NeuAc}
644.0 1498.0
645.2 4358.0

Annotations:

Y^{2,5}X_{Gal} ^{2,5}X_{Gal}Y
646.6 743.0
647.5 6620.0
649.1 294.0
650.3 408.0
652.2 4598.0
652.8 6781.0
654.1 1118.0
655.1 9246.0

Annotations:

B
656.1 30624.0
657.3 6680.0

Annotations:

Z
658.7 686.0
659.4 477.0

Annotations:

^{1,5}X_{NeuAc}Y Y^{1,5}X_{NeuAc} Y^{1,4}X_{Gal} ^{1,4}X_{Gal}Y
660.4 289.0
673.2 6438.0

Annotations:

C
675.0 1050.0

Annotations:

Y
677.5 403.0
678.1 873.0
688.9 813.0

Annotations:

Y^{1,3}X_{Gal} Y^{2,4}X_{Gal} ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y
692.0 2401.0
696.0 3532.0
697.9 420.0
726.9 531.0
727.5 450.0
731.0 1101.0

Annotations:

YZ ZY
732.0 2885.0
741.4 1452.0
745.1 1621.0

Annotations:

^{1,4}X_{NeuAc}Z Z^{1,4}X_{NeuAc}
746.1 2717.0
747.3 1244.0

Annotations:

^{1,4}X_{GlcNAc}
748.0 1108.0
749.1 1.0

Annotations:

YY
750.1 40351.0
751.1 7062.0
752.3 5386.0
756.1 3299.0
782.1 663.0
783.1 951.0
791.2 3525.0
800.1 289.0
801.1 501.0

Annotations:

^{0,2}X_{NeuAc}Z Z^{0,2}X_{NeuAc}
802.1 1187.0
816.1 480.0

Annotations:

Z^{1,3}X_{NeuAc} ^{1,3}X_{NeuAc}Z
817.8 620.0
819.1 2537.0

Annotations:

^{0,2}X_{NeuAc}Y Y^{0,2}X_{NeuAc}
836.1 2147.0
839.1 289.0
842.2 2853.0
844.1 3374.0
845.7 786.0
847.6 875.0

Annotations:

^{3,5}X_{NeuAc}Z Z^{3,5}X_{NeuAc}
848.3 1322.0
858.3 2148.0
860.2 15131.0

Annotations:

Z Z
861.3 5209.0
863.4 597.0
873.0 1087.0
876.5 290.0
878.2 20036.0

Annotations:

Y Y
879.3 13072.0
880.1 1442.0
881.1 663.0
907.4 747.0

Annotations:

^{1,4}X_{NeuAc}Z Z^{1,4}X_{NeuAc}
921.2 2188.0

Annotations:

^{2,4}X_{NeuAc}Z Z^{2,4}X_{NeuAc}
943.0 408.0
945.3 496.0
956.2 672.0
962.2 1.0
963.1 9851.0
964.3 1631.0
965.2 720.0
965.6 1566.0
968.2 4941.0
980.2 12673.0

Annotations:

^{1,3}X_{Gal} ^{2,4}X_{Gal} ^{1,3}X_{Gal} ^{2,4}X_{Gal}
981.3 7898.0
982.2 917.0
986.1 642.0
992.2 485.0
993.1 281.0
996.4 1303.0

Annotations:

^{1,3}X_{NeuAc}Y Y^{1,3}X_{NeuAc}
999.1 783.0
1004.2 4123.0
1020.2 3261.0
1022.2 40344.0

Annotations:

Z Z
1023.2 20558.0
1024.3 7718.0
1025.3 5167.0
1036.1 2348.0
1038.3 5969.0
1039.2 3278.0
1040.3 682321.0

Annotations:

Y Y
1041.2 331819.0
1042.2 106291.0
1043.2 13211.0
1044.1 7879.0
1083.6 1181.0
1097.4 283.0
1229.2 2206.0
1246.5 782.0

There are 5 similar spectra:

Id Structure Score

118

0.98

362

0.98

117

0.87

169

0.65

503

0.57
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