Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library

PubMed Entry

Peak Intensity
339.52 1.4

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B^{1,4}X_{NeuAc}
341.21 0.8
350.19 4.2

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BY CZ
362.82 0.6
366.18 538.5

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ZY CZ BY BY CZ YZ ZY YZ
367.23 49.5

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C^{2,5}X_{Fuc} ^{0,4}A_{Man}Y
368.27 4.5

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CY
371.1 1.4

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C^{2,4}X_{NeuAc}
382.16 1.4

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C^{3,5}X_{Fuc} ^{1,4}A_{Gal} C^{1,5}X_{NeuAc} ^{0,3}A_{Man}Y
382.71 0.7

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C^{1,5}X_{NeuAc} ^{0,3}A_{Man}Y
384.23 2.0

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CY CY
407.23 2.5

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Z
409.16 1.7
418.22 5.6
419.19 1.5

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C
425.32 0.4

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Y
426.31 1.0

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^{1,5}A_{Gal} ^{1,3}A_{Man}Y C^{2,5}X_{Gal} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y C^{0,2}X_{Gal} Y^{1,3}X_{Man} ^{1,3}X_{Man}Y
427.17 3.1
436.1 0.5

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B^{0,2}X_{NeuAc}
438.21 12.4

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ZZ
439.28 1.5

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B^{2,5}X_{Fuc} Y^{3,5}X_{GlcNAc}
453.26 6.0

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B^{1,3}X_{Fuc} B^{2,4}X_{Fuc} ^{1,5}X_{Man}
454.21 109.8

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B
455.21 12.0

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^{0,3}A_{Man}Y ^{1,4}A_{Man} C^{0,3}X_{Fuc}
460.34 0.7
475.14 0.5
495.27 5.1
496.29 2.6

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Z^{2,5}X_{Gal} Z^{2,5}X_{GlcNAc} ^{2,5}X_{GlcNAc}Z
497.18 2.6

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Z^{2,5}X_{Gal} Z^{2,5}X_{GlcNAc} ^{2,5}X_{GlcNAc}Z
511.42 0.5

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Z^{3,5}X_{GlcNAc}
512.23 150.2

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BY CZ BY CZ
513.25 32.3

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^{0,4}A_{Man}
513.93 0.8

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^{2,4}A_{GlcNAc} C^{1,5}X_{Man}
527.36 1.0

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B^{1,4}X_{Man} Y^{1,3}X_{Gal} Y^{2,4}X_{Gal} ^{1,3}X_{Man}Y Y^{2,4}X_{GlcNAc} ^{2,4}X_{GlcNAc}Y
528.22 172.1

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BY CZ
529.22 15.4
530.19 2.0

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CY CY
533.29 1.2
535.38 1.0
546.19 2.4

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CY
548.91 0.8

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ZY YZ ZY YZ
558.1 1.1

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YY YY
567.78 0.6

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^{3,5}A_{Man}Z
568.7 2.7

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^{3,5}A_{Man}Z
569.37 10.6

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ZY YZ
570.2 0.7

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Z^{0,2}X_{Gal} ^{2,5}X_{Gal}Z ^{1,3}A_{Man}Z ^{2,4}A_{Man}Z B^{2,5}X_{Gal}
581.22 1.5

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CY
582.12 1.7

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B^{0,2}X_{NeuAc}
583.22 4.6

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BZ
586.3 1.0

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B^{1,5}X_{GlcNAc} ^{3,5}A_{Man}Y Y^{2,5}X_{Gal}
587.32 20.1

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YY
588.31 6.7

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C^{2,5}X_{Gal} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y
598.14 0.7

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B^{2,5}X_{NeuAc} B^{0,2}X_{NeuAc} ^{2,5}X_{GlcNAc}Z
599.64 0.7

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^{0,2}X_{GlcNAc}Y ^{1,3}X_{Man}Z Z^{1,3}X_{Gal} Z^{2,4}X_{Gal}
600.26 5.3

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C^{0,2}X_{NeuAc} B^{1,5}X_{NeuAc} ^{1,4}A_{Man}Z B^{1,4}X_{Man} Y^{2,5}X_{NeuAc} ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Man}
616.27 5.6

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C^{2,5}X_{NeuAc} C^{0,2}X_{NeuAc} ^{2,5}A_{Man}Y
618.27 1.5

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C^{1,5}X_{NeuAc} ^{1,4}A_{Man}Y
621.91 3.7

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ZY YZ ZY YZ
629.79 5.9

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ZY YZ
633.3 3.2
639.28 21.3

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BZ
640.13 2.9
641.12 3.1

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Z^{1,4}X_{Man} ^{1,4}X_{Man}Z
650.28 3.6

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^{2,5}X_{Gal}Z
654.47 0.8

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CY
655.09 2.9
655.79 7.9

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BZ
656.55 4.7

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BZ BZ
657.24 2581.6

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B
658.28 622.0
659.28 44.6

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B^{1,5}X_{GlcNAc} Y^{1,4}X_{Man} ^{1,4}X_{Man}Y ^{2,5}X_{Gal}Y
660.1 0.6

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^{2,5}X_{Gal}Y ^{2,4}A_{GlcNAc}
673.24 2.3

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Z^{1,3}X_{Man} ^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z
674.34 22.1

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CZ BY CY
675.27 10.2

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C
680.37 1.4

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^{0,2}X_{GlcNAc}Y Y^{2,5}X_{GlcNAc} ^{0,3}X_{NeuAc}Y
688.28 1.3

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B^{1,4}X_{NeuAc} ^{2,5}X_{GlcNAc}Y ^{3,5}X_{NeuAc}Y Y^{0,3}X_{NeuAc} C^{1,5}X_{Man}
689.26 1.5

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Y^{1,3}X_{Man} ^{1,3}X_{Man}Y
690.32 113.6

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C^{1,4}X_{GlcNAc}
691.33 29.7
692.18 0.5

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CY
695.34 1.9

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Y^{3,5}X_{GlcNAc} C^{0,2}X_{GlcNAc}
702.28 2.1

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ZY YZ
708.35 8.0

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^{1,5}X_{Fuc}Z Z^{1,5}X_{Man} ^{2,5}A_{Man}Z ^{2,5}A_{Man}Z
710.72 9.3

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^{2,4}X_{GlcNAc}Y C^{0,3}X_{GlcNAc} C^{1,4}X_{Man}
711.39 2.9

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YY
712.18 1.3

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YY
712.72 1.1
713.54 3.8

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ZZ ZZ
715.34 2.1

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B^{2,5}X_{Fuc} B^{0,2}X_{GlcNAc} ^{0,2}X_{Fuc}Z Z^{0,4}X_{NeuAc}
720.21 0.9

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^{0,2}A_{GlcNAc} C^{2,4}X_{NeuAc}
729.12 0.6

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^{1,4}A_{Man}Z B^{0,3}X_{Fuc}
730.06 0.7

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Z^{1,4}X_{Man} ^{0,3}X_{Fuc}Z ^{3,5}A_{Man}Z
731.34 70.5

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ZY YZ ZY YZ
732.32 14.6

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YY
733.33 7.7

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C^{2,5}X_{Fuc} Y^{2,4}X_{NeuAc}
734.15 1.1

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Y^{2,4}X_{NeuAc} ^{0,4}A_{Man}Y
740.35 3.9
741.01 2.2
745.26 1.2

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B^{3,5}X_{Fuc} B^{2,4}X_{GlcNAc} Z^{1,3}X_{Man} ^{0,4}X_{Fuc}Z ^{1,3}X_{NeuAc}Z
748.07 2.2

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^{1,5}X_{NeuAc}Y Y^{1,4}X_{GlcNAc} ^{3,5}A_{Man}Y
749.32 135.7

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YY YY
750.36 33.8
751.31 1.8
755.24 1.4

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^{2,5}X_{NeuAc}Y
762.11 6.0

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^{0,3}X_{NeuAc}Y C^{0,2}X_{NeuAc} Y^{1,3}X_{NeuAc}
766.75 0.9

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ZZ
775.22 1.5

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Z
778.46 1.3

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C^{2,5}X_{NeuAc}
783.78 2.3

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^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Gal} Y^{2,4}X_{Gal} Y^{2,4}X_{GlcNAc}
784.3 12.4

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Y
785.47 4.7
786.54 1.7
789.2 1.6

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^{1,5}X_{Fuc}Z Z^{1,5}X_{GlcNAc}
793.76 2.7

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C^{1,3}X_{NeuAc}
796.28 1.1

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^{0,2}X_{Fuc}Z B^{2,5}X_{GlcNAc}
801.66 4.2

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BZ
802.36 17.4
803.32 1189.9

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B
804.32 345.6

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ZY YZ ZY YZ
805.35 49.0

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^{0,2}X_{Fuc}Y C^{2,5}X_{GlcNAc}
806.27 1.6
812.62 18.7

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C^{0,3}X_{GlcNAc} ^{1,4}X_{Fuc}Y ^{1,4}X_{Man}
813.41 0.9

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YY YY
814.43 1.5

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^{0,2}X_{GlcNAc}Z Z^{0,2}X_{GlcNAc}
815.11 1.0
816.72 2.0

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Z^{0,2}X_{GlcNAc}
817.78 1.2
818.44 11.6

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BZ BZ
819.28 83.9

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B
820.35 31.1

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^{1,4}X_{GlcNAc} C^{3,5}X_{GlcNAc} Y^{1,4}X_{GlcNAc} ^{0,3}X_{Fuc}Y
821.53 30.1

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C
823.13 3.4
824.43 1.3

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Z^{2,5}X_{GlcNAc}
835.82 0.4
836.36 22.5

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CY CY
837.44 9.7

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C
838.38 0.4
842.28 1.6

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^{2,5}X_{Gal}Y Y^{2,5}X_{Gal}
848.24 1.4

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Z
852.43 8.1
853.5 1.1
856.14 0.8

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^{2,4}X_{GlcNAc} Y^{2,4}X_{GlcNAc} Y^{2,5}X_{NeuAc} ^{2,5}X_{NeuAc}Y
856.68 16.9

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Y^{2,5}X_{NeuAc} ^{2,5}X_{NeuAc}Y
857.37 2.9

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Y
860.42 4.3

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Z^{3,5}X_{GlcNAc}
861.3 2.1

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^{0,4}A_{Man}Z B^{0,2}X_{Fuc}
862.11 0.8

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^{3,5}X_{NeuAc}Z B^{1,5}X_{Gal} Y^{0,3}X_{GlcNAc} B^{1,5}X_{Gal} ^{2,5}A_{Man}Z Z^{3,5}X_{NeuAc}
866.03 0.9
870.35 3.8

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^{0,2}A_{Man}Z B^{2,5}X_{NeuAc} B^{2,5}X_{NeuAc}
871.07 0.9

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B^{2,5}X_{NeuAc} B^{2,5}X_{NeuAc} C^{1,5}X_{Gal} ^{2,5}A_{Man}Y ^{3,5}X_{NeuAc}Y C^{1,5}X_{Gal} Y^{3,5}X_{NeuAc} ^{1,5}X_{GlcNAc}
875.48 2.5

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ZZ
876.44 7.2

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ZZ ZY YZ ZY YZ
877.41 11.9

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B^{2,5}X_{Fuc} B^{2,5}X_{Gal} B^{2,5}X_{Gal} ^{1,5}A_{Man}Z B^{0,3}X_{NeuAc} B^{0,3}X_{NeuAc}
878.41 12.0

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C^{0,2}X_{Gal} C^{0,2}X_{Gal} Y^{3,5}X_{GlcNAc}
879.48 4.8

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^{0,4}A_{Man}Y ^{0,2}A_{Man}Y ^{1,3}A_{Man} ^{2,4}A_{Man} C^{0,2}X_{Fuc} C^{2,5}X_{NeuAc} C^{2,5}X_{NeuAc}
885.27 6.6

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ZY YZ
885.96 8.2

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YY YY
886.56 3.8

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C^{2,5}X_{Gal} ^{1,5}A_{Man}Y C^{2,5}X_{Gal} C^{0,3}X_{NeuAc} C^{0,3}X_{NeuAc}
887.4 3.3
890.68 0.9

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^{1,5}X_{Fuc}Z Z^{1,5}X_{Fuc} ^{1,5}X_{Gal}Z Z^{1,5}X_{Gal}
891.54 0.7

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BZ
892.26 4.0

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Z^{1,4}X_{NeuAc} ^{1,4}X_{NeuAc}Z ^{2,4}X_{GlcNAc}Y Y^{2,4}X_{GlcNAc}
893.36 214.4

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ZY YZ
894.39 80.6

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YY
895.36 59.8

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C^{2,5}X_{Fuc}
896.26 6.7
896.98 0.4
907.44 1.6

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B^{3,5}X_{Fuc}
910.37 3.5
911.37 301.3

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YY
912.37 72.3

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Z^{1,4}X_{Gal} Z^{0,3}X_{Fuc} ^{1,4}X_{Gal}Z ^{0,3}X_{Fuc}Z
913.37 4.9

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B^{0,4}X_{NeuAc} B^{0,4}X_{NeuAc} Y^{1,4}X_{Fuc} ^{1,4}X_{Fuc}Y ^{0,3}X_{GlcNAc}
916.66 2.2

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ZZ
919.45 1.2

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Z^{1,3}X_{Fuc} Z^{2,4}X_{Fuc} ^{1,3}X_{Fuc}Z ^{2,4}X_{Fuc}Z
921.44 0.8

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^{1,5}X_{GlcNAc}Z B^{0,2}X_{Fuc} Z^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}Z Z^{1,5}X_{GlcNAc} B^{0,4}X_{Fuc} B^{1,3}X_{NeuAc} Y^{0,3}X_{Fuc} ^{1,4}X_{Gal}Y Y^{1,4}X_{Gal} ^{0,3}X_{Fuc}Y ^{3,5}X_{GlcNAc}
929.57 21.7

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CZ BY BY CZ
930.15 4.4

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^{3,5}X_{Fuc}Y C^{0,2}X_{Fuc} Y^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}Y Y^{3,5}X_{Fuc}
932.3 0.9

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C^{2,4}X_{NeuAc} C^{2,4}X_{NeuAc}
932.85 0.9
933.99 2.8

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ZY YZ
934.57 7.5

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ZY YZ
935.81 4.6

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Z^{0,3}X_{NeuAc} ^{0,3}X_{NeuAc}Z
936.51 0.7

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B^{0,3}X_{Fuc} Y^{0,4}X_{Fuc} ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{NeuAc} Y^{1,3}X_{Gal} Y^{2,4}X_{Gal} ^{0,4}X_{Fuc}Y ^{1,3}X_{NeuAc}Y
938.27 3.3

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CY CY
938.95 0.3

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Y^{1,5}X_{GlcNAc} ^{1,5}X_{GlcNAc}Y C^{0,4}X_{Fuc} C^{1,3}X_{NeuAc}
947.56 0.6
948.36 25.5

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ZZ ZZ
949.06 9.1

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ZZ ZZ
949.72 2.4

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Z Z
951.21 2.3

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B^{0,4}X_{Fuc} B^{1,3}X_{NeuAc} B^{1,3}X_{NeuAc}
952.46 11.7

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YY
957.18 1.0
957.77 10.0

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ZY YZ ZY YZ
958.31 20.3

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ZY YZ ZY YZ
958.87 9.0

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Y Y
961.83 0.5
965.41 64.3

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B
966.59 42.5

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YY YY
967.38 40.7
968.07 9.3
970.58 1.2

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Z^{0,4}X_{NeuAc} ^{0,4}X_{NeuAc}Z
981.38 6.9

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BY CZ
982.26 7.9

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C
983.58 2.0

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C
986.89 0.6

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Z^{2,5}X_{Fuc} ^{2,5}X_{Fuc}Z B^{3,5}X_{NeuAc} B^{3,5}X_{NeuAc}
998.47 6.1
999.57 1.8

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CY
1002.08 4.5

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BY CZ
1002.65 5.2

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^{1,5}X_{NeuAc}Y Y^{1,5}X_{NeuAc} Y^{0,3}X_{Fuc} ^{0,3}X_{Fuc}Y
1003.84 3.6
1011.39 2.8
1016.18 0.9

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B^{1,5}X_{Fuc} ^{3,5}X_{NeuAc}Z Z^{3,5}X_{NeuAc}
1017.48 1.0

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B^{1,4}X_{NeuAc} B^{1,4}X_{NeuAc} Y^{0,4}X_{Fuc} Y^{1,3}X_{NeuAc} ^{0,4}X_{Fuc}Y ^{1,3}X_{NeuAc}Y
1021.5 3.5
1022.59 16.5

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Z^{3,5}X_{GlcNAc} B^{0,2}X_{Fuc}
1023.51 6.9

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C^{0,4}X_{NeuAc} C^{0,4}X_{NeuAc}
1024.35 0.6

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C^{0,4}X_{NeuAc} C^{0,4}X_{NeuAc} B^{2,4}X_{NeuAc} B^{2,4}X_{NeuAc} Y^{1,4}X_{Gal} ^{1,4}X_{Man}Y Y^{0,3}X_{GlcNAc}
1025.5 1.7

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^{0,4}A_{Man}
1029.15 0.8
1030.98 40.7

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Z Z
1031.81 19.2

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C^{0,2}X_{Fuc}
1032.37 1.3
1037.62 0.9

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B^{0,3}X_{Fuc}
1038.55 2.3

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C^{1,4}X_{Fuc}
1039.96 272.4

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Y Y
1040.74 70.2

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Y^{3,5}X_{GlcNAc}
1041.65 8.4
1042.39 2.9
1044.0 1.2
1045.79 2.6

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B^{3,5}X_{Fuc} ^{1,4}X_{NeuAc}Z Z^{1,4}X_{NeuAc}
1047.74 1.1
1054.52 0.9

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Y^{2,4}X_{Gal} Y^{1,3}X_{Gal} ^{1,3}X_{Man}Y Y^{2,4}X_{GlcNAc} ^{2,4}X_{GlcNAc}Y C^{3,5}X_{Fuc} ^{1,4}X_{NeuAc}Y Y^{1,4}X_{NeuAc}
1055.44 183.7

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^{0,3}A_{Man}
1056.42 58.8
1057.42 90.8
1058.5 30.3
1059.67 4.9
1062.36 1.7

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ZZ
1063.13 1.5
1066.42 3.8
1068.71 1.5
1071.64 2.7

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C^{1,4}X_{Man}
1073.37 18.8
1074.11 2.5
1074.86 9.8

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B
1075.69 14.7

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^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}
1076.43 3.0
1078.5 3.4

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ZZ ZZ
1080.53 8.2

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ZY YZ
1081.38 2.4

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^{1,3}X_{NeuAc}Z Z^{1,3}X_{NeuAc}
1083.03 0.5

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^{2,5}X_{NeuAc} ^{2,5}X_{NeuAc} ^{0,2}A_{Man}Z B^{1,3}X_{Man}
1084.53 3.8
1086.42 2.1
1088.45 1.9
1093.49 1.8
1094.55 21.5
1095.51 19.2
1096.49 87.3

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ZY YZ ZY YZ
1097.42 36.8

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^{1,5}A_{Man}Z ^{3,5}X_{NeuAc} ^{3,5}X_{NeuAc}
1098.49 8.0

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YY
1099.44 2.4
1101.85 1.4

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C^{1,3}X_{Man} ^{0,2}A_{Man}Y
1102.88 2.4
1103.61 28.4

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Z
1104.53 16.6
1105.32 1.6
1106.18 1.1
1109.91 2.5
1110.44 11.3
1111.42 8.6
1111.94 0.9

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Y
1112.56 61.7

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Y
1113.39 41.4
1114.47 156.6

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YY YY
1115.48 47.7

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^{1,5}A_{Man}Y
1116.33 9.7
1122.71 0.4

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^{0,2}X_{Gal}Z
1127.45 7.8

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BY CZ
1128.47 4.3
1138.64 0.5

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Z^{0,2}X_{Gal} ^{2,5}X_{Gal}Z
1142.9 0.5

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BY CZ
1143.59 1.5

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BY CZ
1145.29 1.7

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CY
1145.93 2.9
1146.88 2.0
1150.41 0.8
1158.98 1.0
1162.34 3.9
1164.92 0.6
1166.47 3.3

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BZ
1167.25 2.3
1168.29 11.0

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Z^{1,5}X_{NeuAc} ^{1,4}X_{Man}Z Z^{1,4}X_{Gal} ^{1,4}X_{GlcNAc}Z
1169.48 2.5
1183.75 0.6
1184.71 1.8

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BY CZ
1185.53 2.6
1186.32 1.6

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Y^{1,5}X_{NeuAc} ^{1,4}X_{Man}Y Y^{1,4}X_{Gal} ^{1,4}X_{GlcNAc}Y
1187.37 1.2
1201.49 106.7
1202.5 71.9

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CY
1203.5 10.7
1204.63 2.2
1217.5 4.9

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C^{1,4}X_{Man}
1219.49 8.6
1220.41 4.7
1221.32 0.6
1224.34 0.7

Annotations:

ZZ ZZ
1226.64 1.6

Annotations:

B^{0,2}X_{GlcNAc}
1239.65 0.6

Annotations:

^{2,4}X_{GlcNAc}Z
1241.54 2.1
1242.54 46.7

Annotations:

ZY YZ ZY YZ
1243.51 22.3

Annotations:

^{1,5}A_{Man}Z
1244.62 5.0

Annotations:

C^{0,2}X_{GlcNAc}
1249.57 1.5
1254.35 0.8
1254.92 0.5
1256.58 7.5

Annotations:

B^{1,4}X_{Man}
1257.61 14.0

Annotations:

^{2,4}X_{GlcNAc}Y
1258.51 182.0

Annotations:

ZY YZ
1259.52 96.2
1260.52 126.9

Annotations:

YY YY
1261.58 77.2

Annotations:

^{1,5}A_{Man}Y
1262.52 8.1
1269.28 1.1
1272.33 1.0

Annotations:

Z^{1,4}X_{NeuAc}
1273.98 1.7

Annotations:

C^{1,4}X_{Man}
1275.07 10.6
1275.84 2.5
1276.54 374.5

Annotations:

YY
1277.52 187.3
1278.55 31.7
1280.58 1.5
1289.51 1.5

Annotations:

BY CZ
1290.28 0.7

Annotations:

Y^{1,4}X_{NeuAc}
1299.6 5.8
1300.67 0.8

Annotations:

^{2,5}X_{Gal}Z
1304.49 1.4

Annotations:

C^{1,3}X_{Man} ^{1,5}X_{GlcNAc}Y C^{2,4}X_{GlcNAc} Y^{2,4}X_{NeuAc}
1306.0 1.6
1307.61 3.3

Annotations:

CY
1312.56 1.0

Annotations:

BZ
1313.51 4.9
1314.35 3.5

Annotations:

^{1,5}X_{NeuAc}Z Z^{1,4}X_{Man} Z^{1,4}X_{GlcNAc} ^{1,4}X_{Gal}Z
1328.53 6.9

Annotations:

BZ
1329.5 4.1
1330.55 47.5

Annotations:

BY CZ
1331.55 16.0
1332.38 5.2

Annotations:

^{1,5}X_{NeuAc}Y Y^{1,4}X_{Man} Y^{1,4}X_{GlcNAc} ^{1,4}X_{Gal}Y
1345.72 8.4
1346.55 159.9

Annotations:

BY CZ
1347.58 97.9
1348.57 44.2

Annotations:

CY
1349.72 10.7
1350.89 3.3
1354.83 0.6
1362.25 2.2

Annotations:

Y^{2,5}X_{NeuAc} ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Man}
1363.86 6.6
1364.6 13.4

Annotations:

CY
1365.59 12.4
1366.52 2.8
1367.19 1.5
1369.87 0.3

Annotations:

ZZ
1370.52 1.0
1372.5 1.0

Annotations:

B^{0,2}X_{GlcNAc}
1382.41 1.2
1386.53 3.5

Annotations:

ZZ
1387.57 104.7

Annotations:

Z
1388.59 45.8

Annotations:

B^{2,5}X_{GlcNAc}
1389.54 14.4

Annotations:

Y^{3,5}X_{GlcNAc}
1402.03 1.2

Annotations:

B^{0,3}X_{GlcNAc} B^{1,4}X_{Man}
1403.7 7.4

Annotations:

Y^{2,4}X_{GlcNAc}
1404.6 213.2

Annotations:

ZY YZ
1405.59 311.6

Annotations:

Y
1406.62 149.0

Annotations:

C^{2,5}X_{GlcNAc}
1407.58 24.6
1408.25 1.0
1420.73 27.1

Annotations:

C^{0,3}X_{GlcNAc} C^{1,4}X_{Man}
1421.75 43.9
1422.59 396.8

Annotations:

YY
1423.6 210.3
1424.55 40.7
1425.83 4.8
1426.76 1.0
1430.43 2.1
1432.01 0.3

Annotations:

^{0,4}X_{NeuAc}Y ^{0,2}A_{Man}Z Z^{1,5}X_{GlcNAc} B^{1,3}X_{Man} ^{0,2}A_{Man}Z B^{2,4}X_{GlcNAc} ^{2,4}X_{NeuAc}Z
1434.68 0.8

Annotations:

Z^{1,4}X_{NeuAc} ^{2,5}A_{Man}Y ^{2,5}A_{Man}Y
1438.69 5.9
1439.48 3.9
1441.9 0.7
1445.56 2.0

Annotations:

ZY YZ
1449.78 0.5
1459.07 4.6

Annotations:

Z^{1,4}X_{Man} ^{0,3}X_{Fuc}Z
1459.68 8.0

Annotations:

Z^{1,4}X_{Man} ^{0,3}X_{Fuc}Z
1460.54 5.6
1461.81 9.0

Annotations:

^{1,4}X_{Fuc}Y
1462.67 9.3
1463.25 0.5

Annotations:

YY
1464.35 0.5

Annotations:

^{1,5}A_{Man}Y ^{1,5}A_{Man}Y
1474.59 1.7

Annotations:

BZ BZ BZ
1475.67 13.7

Annotations:

^{3,5}X_{Fuc}Z
1476.66 6.9

Annotations:

^{1,5}X_{NeuAc}Z Z^{1,4}X_{GlcNAc}
1477.58 1.0

Annotations:

^{1,4}X_{Man} Y^{1,4}X_{Man} ^{0,3}X_{Fuc}Y
1479.55 21.6
1480.62 9.1
1481.5 0.8
1483.2 3.5
1484.24 1.2
1491.91 8.0

Annotations:

^{1,5}X_{Gal}Y ^{1,3}X_{Fuc}Y ^{2,4}X_{Fuc}Y Y^{1,5}X_{Gal}
1492.61 159.1

Annotations:

CZ BY CZ BY BY CZ
1493.64 111.2

Annotations:

^{3,5}X_{Fuc}Y
1494.59 15.4

Annotations:

^{1,5}X_{NeuAc}Y Y^{1,4}X_{GlcNAc}
1507.76 1.2

Annotations:

^{1,3}X_{Man} C^{2,4}X_{GlcNAc} Y^{1,3}X_{Man} ^{0,4}X_{Fuc}Y ^{1,3}X_{NeuAc}Y
1508.69 10.4

Annotations:

^{2,5}X_{NeuAc}Y
1509.68 4.1
1510.69 15.5

Annotations:

CY CY CY
1511.56 14.4
1512.46 2.0
1513.16 4.3
1514.85 0.6
1515.51 2.4
1527.17 0.7
1528.63 1.4
1531.65 4.5

Annotations:

ZZ
1532.68 7.2
1533.59 109.1

Annotations:

Z
1534.64 52.0

Annotations:

B^{0,2}X_{Gal} B^{0,2}X_{Gal}
1535.51 20.3

Annotations:

Y^{0,3}X_{GlcNAc} Y^{1,4}X_{Gal} ^{1,4}X_{Gal}Y
1548.33 12.7
1548.91 10.1
1549.64 364.6

Annotations:

Z
1550.67 309.4

Annotations:

B^{2,5}X_{Gal} B^{2,5}X_{Gal}
1551.63 416.5

Annotations:

Y
1552.67 278.9

Annotations:

C^{0,2}X_{Gal} C^{0,2}X_{Gal}
1553.69 67.8
1554.56 2.0
1564.45 4.3

Annotations:

B^{1,4}X_{Gal} B^{1,4}X_{Gal} B^{1,4}X_{GlcNAc}
1565.12 7.5

Annotations:

^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Gal} Y^{2,4}X_{Gal} Y^{2,4}X_{GlcNAc}
1566.16 23.5
1566.8 105.9
1567.6 1147.0

Annotations:

Y
1568.62 748.8

Annotations:

C^{2,5}X_{Gal} C^{2,5}X_{Gal}
1569.62 218.8
1570.74 1.3
1584.82 1.6
1585.78 1.5
1586.67 0.6
1607.2 1.9

Annotations:

ZY YZ ZY YZ
1607.74 6.8

Annotations:

ZY YZ ZY YZ
1608.72 4.6

Annotations:

^{1,5}A_{Man}Z ^{1,5}A_{Man}Z
1609.49 3.6

Annotations:

^{0,2}X_{Fuc}Y C^{2,5}X_{GlcNAc}
1611.77 1.1
1620.24 1.8
1621.05 0.9
1621.62 17.1

Annotations:

B^{3,5}X_{GlcNAc} Z^{1,4}X_{GlcNAc} ^{0,3}X_{Fuc}Z
1622.6 5.5
1623.79 17.5

Annotations:

C^{0,3}X_{GlcNAc} ^{1,4}X_{Fuc}Y ^{1,4}X_{Man}
1624.78 9.0
1625.62 12.6

Annotations:

YY YY
1626.75 11.9

Annotations:

^{1,5}A_{Man}Y ^{1,5}A_{Man}Y
1627.63 2.6
1637.82 1.9

Annotations:

^{3,5}X_{Fuc}Z
1638.5 3.3
1639.57 2.2

Annotations:

^{1,4}X_{GlcNAc} C^{3,5}X_{GlcNAc} Y^{1,4}X_{GlcNAc} ^{0,3}X_{Fuc}Y
1640.82 5.5
1641.79 9.7
1642.67 11.3
1643.48 3.6
1652.82 0.8
1654.55 8.9

Annotations:

CZ BY BY CZ
1655.75 4.2

Annotations:

^{3,5}X_{Fuc}Y
1660.25 3.5
1673.54 2.5
1677.66 9.8

Annotations:

BZ BZ
1678.69 11.2

Annotations:

Z^{3,5}X_{GlcNAc}
1679.63 3.2

Annotations:

Z^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}Z ^{1,4}X_{Gal}Z Z^{1,4}X_{Gal}
1693.64 2.9

Annotations:

^{2,5}X_{NeuAc}Z Z^{2,5}X_{NeuAc}
1694.46 11.2
1694.97 3.3
1695.67 520.5

Annotations:

Z
1696.66 331.2

Annotations:

Y^{3,5}X_{GlcNAc}
1697.69 115.5

Annotations:

Y^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}Y ^{1,4}X_{Gal}Y Y^{1,4}X_{Gal}
1698.58 6.3
1710.0 6.4

Annotations:

^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z Z^{1,3}X_{Gal} Z^{2,4}X_{Gal}
1710.71 0.9

Annotations:

^{2,4}X_{GlcNAc} Y^{2,4}X_{GlcNAc}
1711.47 21.1

Annotations:

Y^{2,5}X_{NeuAc} ^{2,5}X_{NeuAc}Y
1712.03 4.7

Annotations:

Y^{2,5}X_{NeuAc} ^{2,5}X_{NeuAc}Y
1712.78 189.7
1713.65 1885.0

Annotations:

Y
1714.65 1365.4
1715.68 490.0
1716.63 12.5
1717.27 3.4
1729.61 11.2
1730.69 7.1
1731.63 2.5
1733.72 1.5
1751.45 5.4

Annotations:

ZZ
1752.68 10.9

Annotations:

ZY YZ ZY YZ
1753.63 4.2

Annotations:

B^{2,5}X_{Gal} B^{2,5}X_{Gal} ^{1,5}A_{Man}Z
1754.44 2.4

Annotations:

B^{0,3}X_{NeuAc} B^{0,3}X_{NeuAc}
1754.98 1.1

Annotations:

B^{0,3}X_{NeuAc} B^{0,3}X_{NeuAc}
1770.02 11.4

Annotations:

ZY YZ
1770.77 22.9

Annotations:

YY YY
1771.8 16.5

Annotations:

C^{2,5}X_{Gal} ^{1,5}A_{Man}Y C^{2,5}X_{Gal}
1772.61 7.1

Annotations:

C^{0,3}X_{NeuAc} C^{0,3}X_{NeuAc}
1783.73 6.0

Annotations:

Z^{1,4}X_{NeuAc} ^{1,4}X_{NeuAc}Z
1784.73 4.2
1787.67 8.8

Annotations:

YY
1788.79 15.1

Annotations:

C^{3,5}X_{NeuAc} C^{3,5}X_{NeuAc}
1789.81 2.0
1798.79 1.4

Annotations:

Y^{1,5}X_{Fuc} ^{1,5}X_{Gal}Y Y^{1,5}X_{Gal} ^{1,5}X_{Fuc}Y
1799.73 4.1

Annotations:

BY CZ
1814.77 2.8
1816.99 0.9
1840.69 5.0

Annotations:

Z^{3,5}X_{Fuc} ^{3,5}X_{Fuc}Z
1841.81 6.6

Annotations:

B^{0,2}X_{Fuc} Z^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}Z
1842.71 8.0

Annotations:

Y^{1,4}X_{Gal} ^{0,3}X_{Fuc}Y ^{3,5}X_{GlcNAc} Y^{0,3}X_{Fuc} ^{1,4}X_{Gal}Y
1843.47 1.9

Annotations:

C^{0,4}X_{NeuAc} C^{0,4}X_{NeuAc}
1843.97 2.4

Annotations:

C^{0,4}X_{NeuAc} C^{0,4}X_{NeuAc}
1845.36 2.8

Annotations:

C^{1,5}X_{Fuc}
1856.6 1.2

Annotations:

Y^{1,3}X_{Fuc} Y^{2,4}X_{Fuc} ^{1,3}X_{Fuc}Y ^{2,4}X_{Fuc}Y ^{2,4}X_{GlcNAc}
1857.74 26.2

Annotations:

CZ BY BY CZ
1858.71 17.5

Annotations:

Y^{3,5}X_{Fuc} ^{3,5}X_{Fuc}Y
1859.75 14.0

Annotations:

C^{0,2}X_{Fuc} Y^{1,5}X_{NeuAc} ^{1,5}X_{NeuAc}Y
1860.86 3.3
1861.61 0.8
1874.72 2.8
1875.87 13.8

Annotations:

CY CY
1876.44 1.7
1877.57 1.9
1878.7 1.9
1898.84 7.9

Annotations:

Z Z
1899.84 11.6
1914.74 5.2

Annotations:

YZ ZY YZ ZY
1915.77 7.6
1916.73 33.5

Annotations:

Y Y
1917.74 24.6

Annotations:

^{1,5}A_{Man}
1918.61 0.6
1919.79 1.1

Annotations:

C^{0,4}X_{Fuc} C^{1,3}X_{NeuAc} C^{1,3}X_{NeuAc}
1932.76 35.8

Annotations:

YY YY
1933.74 23.5
1934.73 3.5
1935.95 2.6
1944.96 1.0

Annotations:

^{1,5}X_{Gal} ^{1,5}X_{Gal}
1945.66 4.6

Annotations:

B
1946.62 1.9
1947.16 2.4

Annotations:

C^{1,5}X_{NeuAc} C^{1,5}X_{NeuAc}
1947.72 4.4

Annotations:

C^{1,5}X_{NeuAc} C^{1,5}X_{NeuAc}
1961.39 3.1

Annotations:

C^{2,5}X_{NeuAc} C^{2,5}X_{NeuAc}
1970.76 1.2

Annotations:

Z^{1,4}X_{Fuc} ^{1,4}X_{Fuc}Z
1985.82 0.5
1986.66 9.0

Annotations:

^{1,5}X_{NeuAc}Z Z^{1,5}X_{NeuAc} Z^{0,3}X_{Fuc} ^{0,3}X_{Fuc}Z
1987.74 3.1
1988.51 1.9

Annotations:

Y^{1,4}X_{Fuc} ^{1,4}X_{Gal} ^{1,4}X_{Fuc}Y ^{1,4}X_{Gal}

There are 4 similar spectra:

Id Structure Score

2760

0.94

2736

0.92

2759

0.90

2710

0.90
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