Efficient Chemoenzymatic Synthesis of an N-glycan Isomer Library

PubMed Entry

Peak Intensity
274.19 431.1
275.23 36.7
291.04 38.3
292.07 711.7

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B
293.19 50.6

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^{1,4}A_{GlcNAc}
295.07 1.1

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^{0,4}A_{Man} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y
302.09 7.2

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^{3,5}A_{Man}
305.22 1.2
311.25 1.2
330.15 4.7

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Y^{1,4}X_{Man} ^{1,4}X_{Man}Y
331.01 1.0
335.98 1.2

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Z^{1,3}X_{Man} ^{1,3}X_{Man}Z
348.27 138.9

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BZ BZ BZ
356.25 0.6
364.12 2.1
364.95 125.0
365.46 10.5
366.15 8667.8

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B
367.13 674.0
368.06 4.9
368.57 0.4

Annotations:

C^{1,5}X_{Man} C^{2,4}X_{NeuAc}
370.12 1.7
380.34 9.2

Annotations:

^{1,5}X_{GlcNAc}Z Z^{1,5}X_{Man} Z^{1,5}X_{GlcNAc} ^{1,5}X_{Man}Z
382.13 0.8

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B^{1,4}X_{Man} ^{1,4}A_{Gal}
384.0 51.6

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C
385.17 5.0
388.14 2.7

Annotations:

B^{1,3}X_{NeuAc}
396.11 0.7

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^{1,5}A_{Man} ^{2,5}A_{Gal}
398.12 6.7

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^{2,5}A_{Man}Y
400.09 1.6
405.23 0.7

Annotations:

^{0,2}A_{Man}Y C^{1,3}X_{Man}
407.15 7.3

Annotations:

Z
408.18 1.5

Annotations:

^{1,3}A_{Man}Z ^{0,4}A_{Man}Z ^{1,3}A_{Man}Z ^{2,4}A_{Man}Z B^{0,2}X_{Gal} B^{0,2}X_{Gal}
417.2 0.9

Annotations:

BZ
419.03 1.9

Annotations:

C
420.1 3.0
421.04 2.2
422.21 9.5

Annotations:

^{3,5}A_{Man}Z ^{0,3}X_{GlcNAc}Z Z^{0,3}X_{GlcNAc}
424.11 0.7

Annotations:

B^{2,5}X_{Gal} B^{2,5}X_{Gal}
425.19 30.3

Annotations:

Y
428.06 12.7

Annotations:

C^{1,3}X_{NeuAc}
431.04 9.9

Annotations:

^{3,5}X_{GlcNAc}Z Z^{3,5}X_{GlcNAc}
433.12 0.5
436.27 81.9

Annotations:

B^{0,2}X_{NeuAc}
440.22 0.3

Annotations:

^{1,3}A_{Man} ^{2,4}A_{Man} ^{3,5}A_{Man}Y B^{1,5}X_{GlcNAc}
447.24 0.7

Annotations:

BY CZ ZY YZ
448.09 2.1
448.95 0.8
451.23 3.2
452.02 1.5

Annotations:

B^{2,5}X_{NeuAc}
453.41 23.9

Annotations:

^{1,5}X_{Man}
454.17 401.9

Annotations:

B
455.02 66.0

Annotations:

^{1,4}A_{Man}
456.45 1.0

Annotations:

CY YY
457.92 1.7
468.23 3.7

Annotations:

B^{1,3}X_{Gal} B^{2,4}X_{Gal} B^{0,4}X_{Gal} B^{1,3}X_{Gal} B^{2,4}X_{Gal} B^{0,2}X_{GlcNAc}
469.27 1.0
472.25 2.3

Annotations:

C
478.0 0.7
481.21 1.1

Annotations:

Z^{1,5}X_{Gal} Z^{1,5}X_{Man} ^{1,5}X_{Gal}Z ^{1,5}X_{Man}Z
489.02 1.1

Annotations:

Z^{0,2}X_{Gal} Z^{0,2}X_{GlcNAc} ^{0,2}X_{GlcNAc}Z ^{0,2}X_{Gal}Z
492.23 25.3

Annotations:

C^{1,4}X_{Man} C^{0,3}X_{GlcNAc} Y^{1,4}X_{GlcNAc} ^{1,4}X_{GlcNAc}Y
492.97 1.7
495.34 122.6
505.8 1.2

Annotations:

^{2,5}X_{Gal}Y Y^{2,5}X_{Gal} Y^{2,5}X_{GlcNAc} ^{2,5}X_{GlcNAc}Y
507.13 0.8

Annotations:

C^{1,3}X_{Man} ^{0,2}A_{Man}Y C^{2,4}X_{GlcNAc}
510.29 23.1

Annotations:

BZ
513.18 1.2

Annotations:

Y^{1,4}X_{Man} ^{0,3}X_{Gal}Y ^{1,4}X_{Gal}Y Y^{1,4}X_{Gal} ^{1,4}X_{Man}Y Y^{0,3}X_{GlcNAc} ^{0,3}X_{GlcNAc}Y
514.09 1.2

Annotations:

^{2,4}A_{GlcNAc} C^{1,5}X_{Man} ^{1,5}A_{Man}Y
524.13 0.4
525.15 1.2
526.41 0.6
527.19 37.1

Annotations:

B^{1,4}X_{Man}
528.22 2343.0

Annotations:

B
529.17 300.6
530.28 2.0
534.13 0.5

Annotations:

^{2,5}A_{Man}Z
541.14 2.5
541.97 1.1

Annotations:

B^{1,4}X_{NeuAc} B^{1,5}X_{GlcNAc} ^{0,2}A_{Man}Z B^{1,3}X_{Man} B^{1,5}X_{Gal}
546.17 243.6

Annotations:

C
546.67 201.2

Annotations:

C
547.28 13.9
548.07 0.7
550.19 0.9
550.78 1.3

Annotations:

ZZ
557.72 14.9

Annotations:

Y
559.14 0.4
561.81 1.4
566.34 1.0

Annotations:

C^{2,5}X_{Gal}
569.39 253.5

Annotations:

ZY YZ
570.36 1.7

Annotations:

^{1,3}A_{Man}Z ^{2,4}A_{Man}Z
573.96 1.2

Annotations:

^{0,2}A_{GlcNAc} C^{2,4}X_{NeuAc}
577.12 3.1
577.98 1.8

Annotations:

B^{2,5}X_{GlcNAc} Z^{2,5}X_{Gal} ^{2,5}X_{Gal}Z
579.54 1.0

Annotations:

^{0,2}A_{Man}Z B^{1,3}X_{Gal} B^{2,4}X_{Gal}
580.11 1.9

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^{2,5}A_{Man}Y
581.1 1.0

Annotations:

CY
583.29 5.4

Annotations:

BZ
583.88 0.8

Annotations:

BZ
585.2 5.1

Annotations:

^{1,4}X_{Gal}Z B^{0,3}X_{GlcNAc} ^{1,4}A_{GlcNAc} ^{1,4}X_{Man}Z Z^{1,4}X_{Gal} ^{1,4}X_{GlcNAc}Z Z^{1,4}X_{GlcNAc} ^{0,3}X_{Gal}Z
587.28 198.0

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YY
588.2 10.5

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^{0,2}A_{Man}Y ^{0,4}A_{Man} ^{1,3}A_{Man}Y ^{2,4}A_{Man}Y C^{1,3}X_{Gal} C^{2,4}X_{Gal}
592.77 2.2

Annotations:

BY CZ
594.93 0.3

Annotations:

C^{1,5}X_{GlcNAc} ^{1,5}A_{Man}Y
598.69 2.8

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B^{0,2}X_{NeuAc} ^{2,5}X_{GlcNAc}Z Z^{2,5}X_{GlcNAc} Z^{0,3}X_{NeuAc}
600.36 3.4

Annotations:

BZ
601.24 59.5

Annotations:

CY
602.3 19.9

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^{3,5}A_{Man}
603.12 2.3
608.06 1.2

Annotations:

Y^{0,3}X_{NeuAc} B^{1,4}X_{GlcNAc}
611.04 4.2
612.03 15.6
612.85 0.8

Annotations:

B^{1,3}X_{NeuAc} ^{3,5}X_{GlcNAc}Z Z^{3,5}X_{GlcNAc}
615.53 6.4

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Y^{1,5}X_{Man} ^{1,5}X_{Man}Y C^{1,5}X_{Man} Y^{3,5}X_{NeuAc}
621.19 2.0

Annotations:

BZ ZZ
623.46 0.8
624.01 7.6
624.96 1.9
627.11 2.1
629.16 5.0

Annotations:

B^{1,4}X_{Man} B^{0,3}X_{GlcNAc} ^{1,5}A_{GlcNAc} ^{2,4}X_{GlcNAc}Y Y^{2,4}X_{GlcNAc}
629.82 40.2

Annotations:

Z
631.29 0.9

Annotations:

C^{1,3}X_{NeuAc}
634.79 1.6
637.17 0.7

Annotations:

B^{3,5}X_{GlcNAc} Z^{1,4}X_{NeuAc}
638.21 1.3

Annotations:

C^{1,4}X_{Man} C^{0,3}X_{GlcNAc}
639.36 62.7
640.2 19.1
642.97 2.2

Annotations:

Y^{0,4}X_{NeuAc}
644.67 3.7

Annotations:

B^{3,5}X_{NeuAc} B^{0,2}X_{NeuAc} ^{2,5}A_{Man}Y
648.9 1.6
650.28 5.1

Annotations:

ZY YZ
650.8 7.7

Annotations:

B^{0,2}X_{Gal} ^{1,5}A_{Man}Z
651.86 1.5

Annotations:

B^{2,5}X_{NeuAc}
654.19 16.5

Annotations:

C^{1,5}X_{NeuAc}
655.24 94.6
656.31 53.4
657.24 13666.1

Annotations:

B
658.28 1860.8

Annotations:

B^{2,5}X_{Gal}
659.23 17.3

Annotations:

YY
668.55 3.5

Annotations:

C^{0,3}X_{NeuAc}
673.29 9.0

Annotations:

BY CZ BY CZ
674.16 3.8

Annotations:

BY CZ BY CZ
675.06 2.9

Annotations:

C
680.29 28.9

Annotations:

^{0,2}X_{GlcNAc}Y Y^{0,2}X_{Gal} ^{0,2}X_{GlcNAc} ^{0,2}X_{Gal}Y B^{1,3}X_{Gal} B^{2,4}X_{Gal}
685.98 4.8

Annotations:

^{0,3}X_{GlcNAc}Z Z^{1,4}X_{Gal} ^{0,3}X_{Gal}Z ^{1,4}X_{Gal}Z
687.28 4.3

Annotations:

B^{1,5}X_{GlcNAc} B^{1,5}X_{Gal} Z^{3,5}X_{NeuAc}
688.18 11.5

Annotations:

B^{1,5}X_{GlcNAc} B^{1,5}X_{Gal} Z^{3,5}X_{NeuAc} ^{2,5}X_{GlcNAc}Y Y^{2,5}X_{Gal} ^{2,5}X_{Gal}Y ^{2,5}X_{GlcNAc}
688.93 31.1

Annotations:

Y^{0,3}X_{NeuAc} Y^{1,3}X_{Man} ^{1,3}X_{Man}Y
690.35 919.4

Annotations:

BY CZ
691.31 244.4
693.03 1.5
694.49 0.8

Annotations:

Z
695.1 2.6

Annotations:

B^{0,2}X_{Gal} B^{0,4}X_{NeuAc} ^{0,3}X_{GlcNAc}Y Y^{1,4}X_{Gal} ^{0,3}X_{Gal}Y ^{1,4}X_{Gal}Y ^{0,3}X_{GlcNAc}
697.17 1.3

Annotations:

C^{1,5}X_{GlcNAc} C^{1,5}X_{Gal} Y^{3,5}X_{NeuAc} B^{1,4}X_{NeuAc}
698.19 1.0
703.12 4.3

Annotations:

Y
707.2 1.3
708.15 44.3

Annotations:

CY
709.28 2.1

Annotations:

B^{0,3}X_{Gal} B^{1,4}X_{Gal} B^{1,4}X_{GlcNAc}
710.92 214.0

Annotations:

BY CZ
713.43 149.3

Annotations:

ZZ ZZ
714.96 0.3

Annotations:

B^{0,2}X_{GlcNAc} Z^{0,4}X_{NeuAc}
715.86 0.7
716.37 0.3
718.42 8.5

Annotations:

B^{1,5}X_{Man} B^{2,4}X_{NeuAc} C^{1,4}X_{GlcNAc} C^{0,3}X_{Gal} C^{1,4}X_{Gal}
719.69 2.6

Annotations:

CY
724.0 3.5

Annotations:

C^{0,2}X_{GlcNAc} Y^{0,4}X_{NeuAc}
725.0 12.9

Annotations:

B^{0,4}X_{Gal} B^{1,3}X_{Gal} B^{2,4}X_{Gal} Z^{2,4}X_{NeuAc}
728.21 4.7
729.46 41.7
730.24 1.8

Annotations:

B^{0,3}X_{GlcNAc}
731.33 1185.9

Annotations:

Z
732.07 68.9

Annotations:

C^{2,5}X_{GlcNAc}
732.9 5.1

Annotations:

B^{1,3}X_{NeuAc}
734.11 1.4

Annotations:

^{0,2}A_{Man} C^{0,4}X_{Gal} C^{1,3}X_{Gal} C^{2,4}X_{Gal} Y^{2,4}X_{NeuAc}
735.87 1.6

Annotations:

C^{1,5}X_{Man} C^{2,4}X_{NeuAc}
738.5 2.8

Annotations:

B^{3,5}X_{GlcNAc}
740.27 21.3

Annotations:

Y
740.79 7.8

Annotations:

^{1,5}A_{Man}
741.6 0.3

Annotations:

C^{1,3}X_{NeuAc}
744.6 2.6
745.59 45.0

Annotations:

B^{2,4}X_{GlcNAc} ^{1,5}X_{Gal}Z B^{0,2}X_{NeuAc}
746.31 188.4

Annotations:

B^{1,5}X_{NeuAc}
747.26 16.3

Annotations:

C^{3,5}X_{GlcNAc} ^{1,4}A_{Man}
748.19 21.0
749.37 1452.8

Annotations:

YY YY
750.17 135.1
750.75 1.8
753.3 2.0

Annotations:

Z^{1,3}X_{NeuAc} B^{2,5}X_{NeuAc}
754.28 2.1

Annotations:

B
763.35 213.8

Annotations:

C
764.32 73.3
767.0 3.3

Annotations:

Z^{1,5}X_{NeuAc} ^{0,3}X_{Gal}Z ^{1,4}X_{Gal}Z
769.23 2.9

Annotations:

B^{3,5}X_{NeuAc} ^{2,5}X_{Gal}Y ^{2,5}X_{Gal}
771.06 1.5
772.22 4.2
773.43 1.3
775.03 5.1

Annotations:

Z
775.56 4.8

Annotations:

Z
778.2 1.0

Annotations:

C^{3,5}X_{NeuAc}
779.01 0.5
784.23 7.8

Annotations:

Y
786.29 3.6
790.62 4.0

Annotations:

Y^{0,3}X_{NeuAc}
792.6 1.6

Annotations:

^{0,2}A_{Man}Z B^{1,3}X_{Man}
795.61 4.1
797.0 1.1
798.26 1.5

Annotations:

C^{1,5}X_{Gal} ^{1,5}X_{GlcNAc} Y^{3,5}X_{NeuAc}
799.81 1.0
801.15 2.4
803.15 4.5

Annotations:

^{1,4}X_{GlcNAc}Z Z^{1,4}X_{Man} Z^{1,4}X_{GlcNAc} ^{1,4}X_{Man}Z
804.13 34.4

Annotations:

B^{2,5}X_{Gal}
804.95 72.2

Annotations:

C^{0,2}X_{Gal} C^{0,4}X_{NeuAc}
806.04 6.4

Annotations:

B^{2,4}X_{NeuAc} ^{1,5}A_{Man}Z
809.72 1.3
812.29 578.6

Annotations:

Z
813.41 8.0

Annotations:

C^{2,5}X_{Gal}
816.01 0.8
817.37 2.0
818.26 2.7
819.29 531.5

Annotations:

B
820.39 72.4

Annotations:

^{1,4}X_{GlcNAc} C^{0,3}X_{Gal} C^{1,4}X_{Gal}
821.22 57.7

Annotations:

Y
821.8 311.6

Annotations:

Y
822.47 4.2
823.24 1.8
824.44 0.5

Annotations:

^{1,5}A_{Man}Y
825.16 1.8
827.44 2.2
831.39 4.7
837.02 13.3

Annotations:

C
839.25 2.1
844.8 14.1

Annotations:

^{0,3}X_{GlcNAc}Z Z^{0,3}X_{GlcNAc}
849.48 2.3
850.28 1.6
851.61 0.4

Annotations:

Y^{1,3}X_{Man} ^{1,3}X_{Man}Y
852.4 450.2

Annotations:

BY CZ
856.38 97.6

Annotations:

B
857.04 5.2

Annotations:

^{1,5}X_{NeuAc}
858.37 0.9
860.44 18.8

Annotations:

^{3,5}X_{GlcNAc}Z Z^{3,5}X_{GlcNAc}
861.27 39.2
863.35 3.0

Annotations:

Y^{1,3}X_{NeuAc}
865.22 1.4

Annotations:

C
866.01 48.9
867.29 3.1
868.98 3.8
870.39 51.8

Annotations:

CY
871.43 0.4

Annotations:

^{0,3}X_{NeuAc}
873.4 2.2
874.13 1.2

Annotations:

^{2,4}X_{GlcNAc}Z Z^{2,4}X_{GlcNAc}
874.81 4.1

Annotations:

^{2,4}X_{GlcNAc}Z Z^{2,4}X_{GlcNAc}
875.73 2.8

Annotations:

BZ ZZ
876.75 16.7

Annotations:

Z
879.73 0.8

Annotations:

^{3,5}X_{NeuAc} ^{2,4}A_{Man} ^{1,3}A_{Man}
882.84 0.7
884.43 2.3
885.27 2.5
886.27 28.6

Annotations:

Y
886.79 4.1
887.82 0.5
889.11 1.6
891.28 9.0
892.65 29.0

Annotations:

^{2,4}X_{GlcNAc}Y Y^{2,4}X_{GlcNAc}
893.35 2119.1

Annotations:

BY CZ ZY YZ
894.42 183.8
895.48 2.2
900.91 1.5
902.87 0.8
904.12 2.3
909.95 28.1
910.73 24.0
911.31 3461.9

Annotations:

CY YY
912.37 606.9
913.36 11.8
914.47 3.2

Annotations:

^{2,5}X_{Gal}
917.72 2.8
919.35 0.7
920.11 1.7
920.86 3.2

Annotations:

^{1,5}X_{GlcNAc}Z B^{1,5}X_{Man} Z^{1,5}X_{GlcNAc}
921.8 3.7

Annotations:

^{1,5}X_{GlcNAc}Z B^{1,5}X_{Man} Z^{1,5}X_{GlcNAc} ^{0,3}X_{Gal} ^{1,4}X_{Gal}
926.37 17.8
930.28 1.6

Annotations:

^{3,5}X_{Gal}
931.53 1.4
933.8 2.3
934.38 191.0

Annotations:

ZY YZ ZY YZ
935.42 0.7

Annotations:

B^{0,2}X_{GlcNAc}
937.41 0.7
938.68 3.5
941.26 12.6
944.15 0.8
946.86 1.0
948.32 24.5
949.24 67.4
950.36 2.8
951.38 2.2

Annotations:

B^{2,5}X_{GlcNAc}
952.43 10.0

Annotations:

YY YY
953.45 0.9

Annotations:

C^{0,2}X_{GlcNAc}
957.55 2.4
958.27 4.7
966.96 0.8
968.35 2.0
974.73 14.9
977.55 0.2
981.33 4.5

Annotations:

BY CZ
982.48 0.9
984.91 0.9
997.65 12.1

Annotations:

^{2,5}A_{Man}Y
998.23 5.0
999.41 3.1

Annotations:

CY
1000.32 0.8
1014.0 7.1
1020.62 5.1
1021.91 18.2

Annotations:

^{3,5}X_{Gal}Z Z^{3,5}X_{GlcNAc} ^{3,5}X_{GlcNAc}Z
1022.5 67.8

Annotations:

^{3,5}X_{Gal}Z Z^{3,5}X_{GlcNAc} ^{3,5}X_{GlcNAc}Z
1023.29 8.5
1024.4 6.2

Annotations:

Y^{1,4}X_{Man} ^{0,3}X_{Gal}Y ^{1,4}X_{Gal}Y Y^{1,4}X_{Gal} ^{1,4}X_{Man}Y Y^{0,3}X_{GlcNAc} ^{0,3}X_{GlcNAc}Y
1034.1 3.5
1036.36 4.4

Annotations:

Z^{1,3}X_{Man} ^{0,4}X_{Gal}Z ^{1,3}X_{Gal}Z ^{2,4}X_{Gal}Z Z^{1,3}X_{Gal} Z^{2,4}X_{Gal} ^{1,3}X_{Man}Z Z^{2,4}X_{GlcNAc} ^{2,4}X_{GlcNAc}Z
1037.51 34.4

Annotations:

BZ BZ
1040.47 23.3

Annotations:

^{3,5}X_{Gal}Y Y^{3,5}X_{GlcNAc} ^{3,5}X_{GlcNAc}Y
1050.36 1.3
1051.64 11.3
1053.43 2.6

Annotations:

B^{1,4}X_{Man}
1054.46 28.7

Annotations:

Y^{1,3}X_{Man} ^{0,4}X_{Gal}Y ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y Y^{1,3}X_{Gal} Y^{2,4}X_{Gal} ^{1,3}X_{Man}Y Y^{2,4}X_{GlcNAc} ^{2,4}X_{GlcNAc}Y
1055.39 4185.1

Annotations:

CZ BY CZ BY
1056.31 852.2
1057.36 17.0
1058.32 0.6
1061.18 0.7
1071.56 4.0

Annotations:

C^{1,4}X_{Man}
1072.47 4.5
1073.38 223.7

Annotations:

CY CY
1074.28 86.4
1075.29 12.6
1075.95 1.6
1077.51 4.1
1078.63 3.0

Annotations:

ZZ ZZ ZZ
1079.4 4.3
1080.28 1.2
1081.3 2.4
1091.32 12.8
1092.96 0.9
1095.36 85.2
1096.5 2237.2

Annotations:

Z
1097.38 175.9

Annotations:

^{1,5}A_{Man}Z B^{0,2}X_{Gal}
1098.33 2.3
1101.34 8.3

Annotations:

C^{1,5}X_{GlcNAc} C^{1,3}X_{Man} C^{1,5}X_{Gal} ^{0,2}A_{Man}Y
1102.64 1.1
1107.18 14.0
1112.69 111.3
1113.48 163.2

Annotations:

B^{2,5}X_{Gal}
1114.4 3557.2

Annotations:

Y
1115.48 878.5

Annotations:

^{1,5}A_{Man}Y C^{0,2}X_{Gal}
1116.49 1.3
1122.95 1.6
1132.99 6.1
1133.82 9.9
1138.31 1.7

Annotations:

B^{0,2}X_{GlcNAc} Z^{0,2}X_{Gal} ^{0,2}X_{Gal}Z
1140.89 23.6
1143.42 0.5

Annotations:

BY CZ
1146.17 1.1
1159.43 2.6

Annotations:

^{2,5}A_{Man}Y
1162.22 2.1
1164.89 1.7
1169.17 1.1
1181.47 1.2
1183.12 13.5
1184.37 84.1

Annotations:

BY CZ
1185.53 35.3
1199.49 1.4

Annotations:

BZ
1201.57 0.3
1202.47 42.9

Annotations:

CY
1203.49 69.0
1206.56 0.5
1208.47 1.9
1209.49 13.0

Annotations:

^{0,3}X_{GlcNAc}Z Z^{0,3}X_{GlcNAc}
1215.36 2.2

Annotations:

B^{1,4}X_{GlcNAc}
1217.55 12.9

Annotations:

BY CZ
1220.48 3.9
1222.4 1.4
1235.33 2.9

Annotations:

CY
1238.41 2.4
1239.51 14.0

Annotations:

Z^{2,4}X_{GlcNAc} ^{2,4}X_{GlcNAc}Z
1240.45 39.2

Annotations:

BZ ZZ
1241.54 5.0
1242.51 2.1

Annotations:

B^{2,5}X_{GlcNAc}
1251.08 9.2
1252.56 1.0
1255.9 3.5
1256.54 6.4

Annotations:

B^{1,4}X_{Man} B^{0,3}X_{GlcNAc}
1257.51 321.7

Annotations:

^{2,4}X_{GlcNAc}Y Y^{2,4}X_{GlcNAc}
1258.47 6051.2

Annotations:

Z
1259.44 2308.8
1260.36 61.9

Annotations:

C^{2,5}X_{GlcNAc}
1261.4 2.1
1262.07 1.5
1271.75 4.1
1272.97 1.9
1273.83 4.8
1274.73 25.6

Annotations:

C^{1,4}X_{Man} C^{0,3}X_{GlcNAc}
1275.28 1563.5
1276.42 22566.3

Annotations:

Y
1277.47 8864.5
1278.35 136.6
1279.49 4.3
1280.94 1.4
1289.15 1.4

Annotations:

B^{1,5}X_{NeuAc}
1297.64 0.9
1298.5 3.3
1299.44 8.2

Annotations:

ZY YZ
1301.33 1.3
1316.49 0.5

Annotations:

B^{2,5}X_{Gal}
1317.35 26.5

Annotations:

YY
1324.19 8.9
1327.75 4.2

Annotations:

Z^{1,5}X_{Gal} ^{1,5}X_{Gal}Z
1328.48 4.8

Annotations:

BZ BZ
1329.23 1.3
1330.48 2.6

Annotations:

Z^{1,5}X_{NeuAc} ^{1,4}X_{GlcNAc}Z B^{1,4}X_{Gal}
1339.09 2.5
1343.64 0.9

Annotations:

Z^{1,3}X_{NeuAc}
1344.26 1.2

Annotations:

Z^{2,5}X_{NeuAc}
1345.56 12.5

Annotations:

Y^{1,5}X_{Gal} ^{1,5}X_{Gal}Y
1346.53 329.2

Annotations:

BY CZ BY CZ
1347.44 87.2
1348.34 0.9

Annotations:

Y^{1,5}X_{NeuAc} ^{1,4}X_{GlcNAc}Y C^{1,4}X_{Gal} ^{1,4}X_{GlcNAc}
1349.2 1.2
1351.28 1.1

Annotations:

C^{3,5}X_{NeuAc}
1362.56 1.0

Annotations:

Y^{2,5}X_{NeuAc}
1363.7 10.9
1364.37 191.2

Annotations:

CY CY
1365.5 17.9
1366.57 5.0
1368.58 2.1
1386.61 5.8
1387.64 134.8

Annotations:

Z
1388.52 22.8

Annotations:

B^{0,2}X_{Gal} B^{0,4}X_{NeuAc}
1389.44 2.6

Annotations:

^{0,3}X_{GlcNAc}Y Y^{1,4}X_{Gal} ^{0,3}X_{Gal}Y ^{1,4}X_{Gal}Y ^{0,3}X_{GlcNAc}
1399.96 1.8
1403.81 78.5
1404.5 14.0

Annotations:

B^{2,5}X_{Gal}
1405.48 246.3

Annotations:

Y
1406.61 313.7

Annotations:

C^{0,2}X_{Gal} C^{0,4}X_{NeuAc}
1407.37 27.6

Annotations:

B^{2,4}X_{NeuAc}
1413.2 3.7
1419.33 1.8

Annotations:

^{2,4}X_{GlcNAc}Y Y^{1,3}X_{Gal} Y^{2,4}X_{Gal} ^{0,4}X_{Gal}Y ^{1,3}X_{Gal}Y ^{2,4}X_{Gal}Y ^{2,4}X_{GlcNAc}
1420.55 557.1

Annotations:

BY CZ
1421.5 113.3
1422.4 3.4

Annotations:

C^{2,5}X_{Gal}
1437.81 31.2
1438.45 12.2

Annotations:

CY
1439.67 25.4
1441.03 0.5
1442.21 0.8
1444.3 2.9
1453.7 1.7
1460.93 45.4
1461.63 150.7

Annotations:

Z
1462.4 214.3
1466.7 1.4

Annotations:

^{0,2}A_{Man} C^{0,4}X_{Gal} C^{1,3}X_{Gal} C^{2,4}X_{Gal} Y^{2,4}X_{NeuAc}
1475.41 65.5

Annotations:

B^{3,5}X_{GlcNAc}
1477.96 5.3

Annotations:

C^{0,3}X_{GlcNAc} ^{1,4}X_{Man}
1478.63 4.3
1479.58 556.2

Annotations:

Y
1480.63 55.0

Annotations:

^{1,5}A_{Man}
1507.81 2.9

Annotations:

^{1,3}X_{Man} ^{1,5}X_{Gal}Y ^{1,5}X_{Gal} C^{2,4}X_{GlcNAc}
1508.54 217.0

Annotations:

B
1509.52 4.6
1510.67 1.4

Annotations:

C^{1,5}X_{NeuAc}
1526.59 3.1

Annotations:

C
1527.59 0.9
1531.61 2.7

Annotations:

BZ
1533.7 1.8

Annotations:

Z^{1,5}X_{NeuAc} ^{0,3}X_{Gal}Z ^{1,4}X_{Gal}Z
1547.83 19.9

Annotations:

Z^{2,5}X_{NeuAc}
1548.81 185.1
1549.51 648.2

Annotations:

Z
1550.57 710.8
1551.49 31.7

Annotations:

Y^{1,5}X_{NeuAc} ^{0,3}X_{Gal}Y ^{1,4}X_{Gal}Y ^{1,4}X_{Gal}
1565.36 5.8

Annotations:

Y^{2,5}X_{NeuAc}
1566.04 47.5

Annotations:

Y^{2,5}X_{NeuAc}
1566.65 482.2
1567.52 2840.8

Annotations:

Y
1568.59 1474.7
1569.63 8.0
1570.67 0.8
1622.68 17.2
1623.65 282.0

Annotations:

Z
1624.67 12.5
1640.6 8.9
1641.54 493.6

Annotations:

Y
1642.51 537.6
1643.28 41.5
1644.56 58.6
1669.73 2.0

Annotations:

C^{0,4}X_{Gal} C^{1,3}X_{Gal} C^{2,4}X_{Gal} Y^{2,4}X_{NeuAc}
1711.11 34.2

Annotations:

B
1711.67 55.7

Annotations:

B
1712.64 83.5
1713.51 2.6

Annotations:

^{1,5}X_{NeuAc}
1729.48 440.5

Annotations:

C
1730.58 135.5
1731.6 2.8
1733.01 0.5
1734.75 1.4
1749.57 0.8
1750.37 1.1
1799.73 1.0

There are 3 similar spectra:

Id Structure Score

2718

0.79

2700

0.74

2727

0.51
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