Negative ion CID fragmentation of O-linked oligosaccharides aldoses-charge induced and charge remote fragmentation

PubMed Entry

GlyToucan Accession Number: G40269CS

Peak Intensity
189.9 1544.0
193.7 2217.0
194.7 601.0
199.8 1925.0
200.9 1188.0
201.7 3147.0
203.8 14584.0

Annotations:

Z
204.9 1074.0
208.8 963.0
209.8 2041.0
211.8 1159.0
218.8 704.0
219.6 7119.0
221.8 6247.0

Annotations:

Y
223.0 3412.0
223.7 1625.0
226.0 6976.0
228.7 1414.0
229.9 2906.0
231.1 705.0

Annotations:

B^{0,2}X_{NeuAc}
232.8 1506.0

Annotations:

B^{1,5}X_{NeuAc}
235.9 1102.0
243.9 2820.0
244.7 1356.0
245.8 3092.0
247.1 780.0

Annotations:

B^{2,5}X_{NeuAc}
248.4 1472.0
251.8 1953.0
259.7 586.0
260.7 651.0

Annotations:

B^{0,3}X_{NeuAc}
263.0 755.0
263.9 3607.0

Annotations:

^{0,2}X_{Gal}
267.2 424.0
267.9 575.0
269.7 3576.0
270.8 3452.0
271.9 15553.0
272.8 3110.0
273.8 1198.0
275.9 4495.0
283.9 1121.0
287.4 4765.0
287.9 30096.0
289.9 2096461.0

Annotations:

B
290.9 247009.0
291.9 16951.0
300.2 972.0
306.3 505.0
307.8 8058.0

Annotations:

C
320.0 2627.0
322.3 1542.0
324.0 651.0

Annotations:

^{1,3}X_{Gal} ^{2,4}X_{Gal}
326.2 586.0
327.8 563.0
329.9 490.0
334.0 2429.0
345.9 2186.0
347.9 2086.0
362.0 575.0
365.9 1451.0

Annotations:

Z
379.1 1285.0
379.9 19043.0

Annotations:

^{1,4}A_{Gal}
380.9 6220.0
383.0 2517.0
384.0 88539.0

Annotations:

Y
385.0 11889.0
386.0 6509.0
386.8 1861.0
387.9 1139.0
389.1 439.0
397.9 5807.0
404.0 5175.0
405.0 754.0
406.0 2577.0
406.9 3224.0
408.0 5818.0

Annotations:

B^{1,3}X_{NeuAc}
409.0 813.0
410.0 424.0

Annotations:

^{0,2}A_{Gal}
415.1 781.0
415.8 9001.0
416.9 3023.0
424.1 1823.0

Annotations:

^{1,5}A_{Gal}
426.8 998.0
434.0 2509.0
436.0 1645.0
451.1 818.0
454.0 13904.0

Annotations:

^{0,2}X_{NeuAc}
468.5 1924.0
470.0 43208.0

Annotations:

C
471.0 8411.0
472.5 5324.0
476.9 3722.0
478.0 1494.0
481.0 1318.0
490.0 718.0
493.1 2678.0
494.0 552.0
505.5 517.0
506.7 842.0
507.7 1367.0
513.2 568.0
514.1 999.0
517.8 1736.0
523.1 2147.0
524.0 417.0
527.0 757.0
531.2 2182.0
538.6 508.0
567.0 2093.0
570.7 612.0
593.0 501.0
595.0 2313.0
597.1 2972.0
613.0 7956.0
615.0 5098.0
616.2 1311.0
622.2 904.0
623.9 2287.0
631.1 18954.0

Annotations:

^{1,3}X_{NeuAc}
632.2 568.0
632.9 1901.0
640.2 693.0
641.0 1096.0
642.9 712.0
643.5 734.0
652.9 718.0
653.9 1128.0
655.1 35204.0
656.1 11138.0
657.1 91358.0
658.1 19837.0
659.2 2485.0
663.8 973.0
673.5 1862.0
686.4 428.0
687.0 443.0
689.3 698.0
690.9 734.0
691.7 534.0
697.1 1229.0
817.4 447.0
845.7 1967.0
851.2 1440.0
852.9 694.0

There are 7 similar spectra:

Id Structure Score

41

1.00

98

1.00

3653

0.99

3637

0.99

2814

0.99

2604

0.99

96

0.57
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